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46 articles for “reaction constant”
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Study of the Hammett equation for oxidation of 2 – Hydroxy – 1 - Naphthalidene Anil and para substituted chloroanils by potassium bromate in acid medium
Abstract: The kinetics of oxidation of the Schiff base and its substituted anils by potassium bromate in aquo-acetic acid medium has been studied in this work. The study of thermodynamic parameters is done, and the rate constants for the reaction are determined. The plot of log{ks/k0} against the substituent constant (ï³ ) is plotted for para and meta substitution and the reaction constant (ï²) is calculated. The plot of ï„H against …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 2, 2016 · pp. 1–4 Read article
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Non-destructive Application of Tracer Isotopes to Study the Kinetics of Iodide and Bromide Ion-isotopic Exchange Reactions in Anion Exchange Resins Indion-103 and Duolite A-611
Abstract: The present study is concerned with non-destructive application of radio-analytical technique for characterization of industrial grade ion exchange resins Indion-103 and Duolite A-611. The radioactive tracer isotopes 131I and 82Br were used to trace the kinetics of iodide and bromide ion-isotopic exchange reactions taking place in the two resins. It was observed that during bromide and iodide ion-isotopic exchange reactions, under identical experimental conditions of temperature remaining constant at 40 …
Published in Journal of Nuclear Engineering & Technology · Vol. 3, Issue 2, 2013 · pp. 14–24 Read article
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Analysis of Diethanolamide Reaction by using FTIR Technique
Abstract: The purpose of this work is to study the amidification reaction for production of diethanolamide from ethyl acetate and diethanolamine by using sulfuric acid catalyst. The amidation, which is the reaction between ethyl acetate and diethanolamine, was held in a glass batch reactor with mole ratio 1:1 using acid catalyst (H2SO4) 0.5% (w/w) and 200 rpm stirring. The reaction temperature is 160°C constant, and sampling was performed after every 30 …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 1, 2016 · pp. 7–10 Read article
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Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium
Abstract: The kinetics of ruthenium(III) catalyzed degradative oxidation of methylparaben by the copper complex, diperiodatocuprate(III) in alkaline medium is studied at 25ºC and at a ionic strength of 8.0 × 10−2 mol dm−3. In the presence of catalyst ruthenium(III), the reaction between methylparaben and diperiodatocuprate(III) in aqueous alkaline medium exhibits 1:1 stoichiometry. The oxidation products were identified by UV-visible, GC-MS and IR spectroscopy. The reaction exhibited unit order in case of …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 4–17 Read article
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BIOCHEMICAL AND KINETICS STUDIES ON PROTEASE ENZYME ISOLATED FROM AYURVEDIC HERBS ALONG WITH THEIR APPLICATION STUDIES
Abstract: The objective of the present work was to conduct comprehensive biochemical and kinetic analysis of a protease enzyme extracted from two Ayurvedic herbs, namely Shankhpushpi (Convolvulus prostratus) and Mulethi (Glycyrrhiza glabra). The primary focus was to characterize various biochemical aspects of the enzyme, encompassing substrate specificity, optimal pH and temperature conditions, stability, and activation energy. Furthermore, crucial kinetic parameters such as Michaelis-Menten constant (Km) and maximum reaction velocity (Vmax) were …
Published in Research and Reviews : A Journal of Biotechnology · Vol. 13, Issue 3, 2023 · pp. 21–37 Read article
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Kinetics of Ion-Isotopic Exchange Reactions using Nuclear Grade Resins Purolite NRW-4000 and Purolite NRW-60
Abstract: AbstractThe paper deals with an application of nondestructive radio isotopic tracer technique in performance evaluation of two nuclear grade anion exchange resins Purolite NRW-4000 and Purolite NRW-6000. The technique was used to study the kinetics of bromide and iodide ion-isotopic exchange reactions taking place between the external ionic solution and the resin surface for which 131I and 82Br were used as tracer isotopes. It was observe that at a constant …
Published in Journal of Nuclear Engineering & Technology · Vol. 4, Issue 1, 2014 Read article
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Compatative Catalytic Study of Oxidation of Thiourea by Chromium (VI) in Presence of Different Catalysts and Micelles
Abstract: The series of catalysts like acetate, oxalate, EDTA, the varies micelles viz, CTAB, SDS, TRITON X-100 was carried out in the kinetic study of oxidation of Thiourea by Cr(VI) as an oxidant in water medium. The effect of catalytic efficiency has been study for varies catalyst and micelles by volumetric method and UV spectroscopic methods. The product was confirmed by IR studies. UV study reveals shows that higher catalytic efficiency …
Published in International Journal of Advance in Molecular Engineering · Vol. 4, Issue 1, 2026 · pp. 9–21 Read article
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Role of Solid Acid Catalyst in Isopropylation Reaction
Abstract: Cumene synthesis was carried out by the reaction of benzene with isopropyl alcohol in the vapour phase over rare earth metal modified 13X zeolite. Zeolite modification was done by exchanging sodium ions of the zeolite with cerium ions to vary the acidity of the catalyst in the range of 0.25‑1.36 meq/g. The synthesis was carried out over a wide range of operating conditions. The synthesis conditions were optimized by studying …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 2, 2015 · pp. 19–26 Read article
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Removal of Thiophene from Model Fuel Using Titanium Catalyst
Abstract: Organosulfur compounds like thiophene (Th) and its alkyl derivatives are the major unwanted species present in crude oil fractions as they lead to the formation of sulfur oxides after combustion of the fuel and these oxides of sulfur cause severe environmental damage. Oxidative desulfurization (ODS) process is considered as one of the best alternative deep desulfurization technologies compared to hydrodesulfurization. In the ODS process, the sulfur compounds are oxidized to …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 1, 2016 · pp. 31–36 Read article
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Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
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Design and Validation of Polymer-Separated Lithium-Ion Battery Powered Mini-UPS for Networking Applications
Abstract: Due to the growing use of semiconductor-based electronic devices in networking applications, power interruptions can cause data loss, productivity loss, and system disruptions. To eliminate these outages, Mini Uninterruptible Power Supplies are expensive and have single-use batteries with shorter battery lives. These networking wires, cables, and other electrical components are polymer-insulated. Polymers with low dielectric constants have the potential to improve antenna interlayer dielectrics, communication cables, and other hardware for …
Published in Journal of Polymer & Composites · Vol. 13, Issue 1, 2025 · pp. 917–933 Read article
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Removal of CO2 using Aqueous Blends of Amines by Chemical Absorption Method: Modeling
Abstract: Carbon capture from point source emissions has been recognized as one of the several strategies necessary for mitigating unfettered release of greenhouse gases (GHG's) into the atmosphere to prevent global warming. To keep the GHG's at manageable level, large decrease of CO2 should take place through capture technologies like chemical absorption. Alkanolamines such as monoethanolamine (MEA), diethanolamine (DEA), and N-methyldiethanolamine (MDEA) have been used for gas treating at industries. There …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 1–5 Read article
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TiO2-ZrO2 Supported Nickel Oxide Catalysts for Hydrogenation of Levulinic Acid to -Valerolcatone
Abstract: The Titania-Zirconia (TZ) mixed oxide sample (50:50 wt.% percent) was prepared by a simple coprecipitation method and used as a support for the nickel catalyst. The various loadings of nickel content from 1 to 20 wt.% were synthesized for the production of γ-valerolactone (GVL) from levulinic acid (LA). Among all the tested samples, the 5 wt.% Ni/TZ sample exhibited the 98% conversion of LA and 96% selectivity to GVL and …
Published in Emerging Trends in Chemical Engineering · Vol. 9, Issue 3, 2022 · pp. 35–44 Read article
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Nondestructive Technique in Study of Purolite NRW-5010 and Duolite A-638 Anion Exchange Resins
Abstract: The present paper is one of the interesting applications of radioactive isotopes in nondestructive technique for performance evaluation of anion exchange resins Purolite NRW-5010 and Duolite A-638. The radioactive isotopes 131I and 82Br were used to trace the kinetics of ion-isotopic exchange reactions taking place between the resin surface and external ionic solution. It was observed that for bromide ion-isotopic exchange reaction at 35.0°C, when the concentration of bromide ions …
Published in Journal of Nuclear Engineering & Technology · Vol. 3, Issue 3, 2013 · pp. 1–11 Read article
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Isolation and Identification of Novel Bacillus tequilensis TB5 from Vegetable Waste and Analyze the Effect of Rudiment Compounds on Bio-Catalytic α-Amylase Production
Abstract: AbstractAmylase is one of the basic components for leather, baking, textiles and paper industries. It hydrolyzes starch into simple productive sugar which reduces the cost of the final desired product. In this work, amylase producing novel Bacillus tequilensis TB5 was isolated from vegetable waste and different chemical compounds were added at different concentration in production medium to analyze its effect on amylase enzyme production. We observed that addition of weight/volume …
Published in Research and Reviews: A Journal of Microbiology and Virology · Vol. 9, Issue 2, 2019 · pp. 39–50 Read article
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Synthesis and Dielectric Properties of CaCu3Ti4O12 Doped with La3+
Abstract: The effect La3+ doping on the structural and dielectric properties of CaCu3Ti4O12 (CCTO) is investigated, resulting in a compound of the type Ca1-xLaxCu3Ti4O12 (x = 0.00, 0.20 and 0.50). The compounds have been prepared by conventional solid state reaction. The Ca1-xLaxCu3Ti4O12 ceramics were characterized by X-ray diffraction, SEM techniques. The grain size and the grain boundary resistivity increased with the increase of doping percentages. Dielectric constant of the samples decreases …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 9, Issue 3, 2019 · pp. 22–26 Read article
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Metabolites in Modern Medicine: Decoding the Future of Health and Diseases
Abstract: The end products of many metabolic processes in cells are called metabolites. Each reaction contributes a specific metabolite. Metabolites act as fingerprints of on-going biological processes. Constant changes in cellular composition due to both environmental and internal factors. By analysing the types and presence of metabolites, scientists can effectively reconstruct the inner workings of a cell or organism. In the past, analysing metabolites was a slow and tedious process, often …
Published in Emerging Trends in Metabolites · Vol. 1, Issue 2, 2024 · pp. 1–13 Read article
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The Integrity of Eadic-Hofstee Plot Model to Predict the kinetic Parameters of Crude Oil Degradation using Vernonia amygdalina Stem
Abstract: The integrity of Eadic-Hofstee concept was tested for the determination of the functional coefficients and parameters of crude oil degradation kinetics. The techniques enhanced the relationship between the substrate divided by the specific rate of the substrate degradation against substrate concentration (TPH). The investigation reveals the values of the biokinetic parameters of maximum specific rate of substrate degradation (Vmax) and the equilibrium constant values of the substrate degradation (Ks). The …
Published in Journal of Petroleum Engineering & Technology · Vol. 14, Issue 2, 2024 · pp. 37–47 Read article
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Development and Performance Evaluation of Polymer-Modified Geopolymer Composites Incorporating GGBS
Abstract: This research investigates the development and performance of geopolymer-based composite materials formulated using Ground Granulated Blast Furnace Slag (GGBS) as a reactive mineral component within an aluminosilicate polymer matrix. The study aims to create an eco-efficient and structurally sound inorganic polymer composite comparable to M35-grade concrete, produced entirely under ambient curing conditions. A series of mixes with varying GGBS replacement ratios (0–100%) was prepared, maintaining a constant binder content of …
Published in Journal of Polymer & Composites · Vol. 14, Issue 2, 2026 · pp. 1145–1165 Read article
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Review and Opportunities for Thermal examination approaches Used to Investigate the Thermal Properties of Composite Compounds
Abstract: The use of thermal examination approach to assess the thermal quality of energy materials in “China” is concisely described. They are often used to calculate thermal stability, compatibility, and thermophysical constants, as well as to study thermal breakdown kinetics, causes, and interactions. Furthermore, a few studies focused on creativity or advancement, such as analyzing the mechanisms of topochemical reactions, assessing condensed-phase reaction kinetics by tracking the change in functional groups …
Published in Journal of Polymer & Composites · Vol. 12, Issue 6, 2024 · pp. 96–106 Read article