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620 articles for “Subtractive Synthesis”
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An Efficient Synthesis of Some Novel Benzo Coumarin Derivatives Under Solvent Conditions from 2-acetyl-benzo[f]chromen-3-one
Abstract: The synthesis of the target compounds began with the preparation of 2-[3-dimethylamino[acryloyl-3H-benzo[f]chromen-3-one. This intermediate was obtained through the reaction of 2-acetylbenzo[f]coumarin-3-one with N,N-dimethylformamide dimethyl acetal [DMFDMA[ under reflux conditions in xylene. The enaminone thus formed was subsequently reacted with 6-aminothiouracil in acetic acid, leading to the formation of 2-thioxo-2,3-dihydro-1H-pyrido[2,3-d]pyrimidin-4-one. This compound served as a pivotal intermediate for the synthesis of a series of pyridotriazolopyrimidinones. These derivatives were synthesized by reacting …
Published in International Journal of Cheminformatics · Vol. 2, Issue 2, 2024 · pp. 33–46 Read article
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Carbon Dioxide as a Fundamental Component in Sustainable Organic Synthesis
Abstract: A lot of people are interested in carbon dioxide (CO₂) as a cheap, plentiful, and safe source of carbon for making chemical processes more sustainable. Using it as a C1 building block in organic synthesis is a promising way to make products with added value while having less of an impact on the environment. This article examines current advancements in CO₂ fixation into organic compounds, emphasising the creation of effective …
Published in International Journal of Advance in Molecular Engineering · Vol. 3, Issue 2, 2025 · pp. 22–34 Read article
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Methodology for Evaluating Code Synthesis in Large Language Models: ChatGPT and Copilot: A Review
Abstract: The authors introduce a comprehensive framework to assess the code-generation capabilities of large language models, focusing on ChatGPT and Copilot through a benchmark suite of 25 program synthesis tasks. Their main goal was to show why making proper comparisons is important, they did not focus on choosing the newest models, since they keep changing frequently. The critique examines how the methodology addresses both functional and non-functional aspects of code. In …
Published in Recent Trends in Programming languages · Vol. 12, Issue 3, 2025 · pp. 01–07 Read article
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Synthesis, Production, and Mass Balance Analysis of Ten High-Volume Herbicides
Abstract: Herbicides play a crucial role in modern agriculture, enabling effective weed management and safeguarding crop yields amid rising global food demands and growing weed resistance, which can reduce productivity by up to 40%. This study provides a detailed examination of synthesis pathways, production methodologies, and mass balance dynamics for ten high-volume herbicides: Aclonifen, Ametryn, Amidosulfuron, Aminocyclopyrachlor, Aminopyralid, Atrazine, Azimsulfuron, Beflubutamid, Bensulfuron Methyl, and Bentazone, used to control broadleaf weeds, grasses, …
Published in Emerging Trends in Chemical Engineering · Vol. 12, Issue 3, 2025 · pp. 30–44 Read article
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Synthesis, Identification and Bio Evaluation of New Thiophene Derivatives
Abstract: Thiophene is considered one of the most effective cyclic sulfur compounds in organic and pharmaceutical chemistry due to its high stability in various chemical reactions. It plays a key role as an antifungal agent in treating skin allergies, as well as in the preparation of polymers, rubber, and other materials. Recent research has focused on incorporating sulfur compounds into the synthesis of organic compounds because of their high stability in …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 17, Issue 1, 2026 · pp. 32–44 Read article
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Nanoparticle Chemistry: The Synthesis, Properties and Applications of Polymer and Macromolecule-Based Nanoparticles and Their Composites
Abstract: Nanoparticles have arisen as a transformative branch of materials in chemistry, owing to their unique physicochemical and biological properties that vary from their bulk materials. Various synthesis techniques, including physical (e.g., laser ablation), chemical (e.g., sol-gel, co-precipitation) and biological (e.g., microbial or plant-mediated) approaches, offer control over particle size, shape and surface characteristics. These methods influence the optical, electronic, catalytic and mechanical properties of nanoparticles. Nanoparticles can exhibit high surface …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 1236–1247 Read article
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Synthesis, characterization, and antibacterial activity of silver nanoparticles with expired minocycline as reducing agent: proposed as a recycling technique.
Abstract: In this research, expired minocycline, a broad-spectrum tetracycline antibiotic, was employed as both a reducing and stabilizing agent for the eco-friendly synthesis of silver nanoparticles. This sustainable method avoids the use of toxic chemical reducing agents, providing a greener alternative for nanoparticle production. The synthesized silver nanoparticles were analyzed using several characterization techniques, such as UV-Vis’s spectroscopy, scanning electron microscopy, transmission electron microscopy, and Edex analysis, to assess their structural, …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 16, Issue 1, 2026 · pp. 30–43 Read article
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Copper Sulfide Semiconducting Nanoparticles for Antibacterial Applications: Synthesis Strategies, Mechanisms and Performance – A Review
Abstract: Copper sulfide nanoparticles (CuS NPs) have drawn growing attention as a next-generation antibacterial platform, owing to their tunable structural, optical, and catalytic properties. This review consolidates current evidence on CuS NP synthesis, mechanisms, and antibacterial performance, comparing chemical and green synthesis routes alongside the effects of morphology, doping, and surface modification. Mechanistically, CuS NPs act through several overlapping pathways, including reactive oxygen species generation, bacterial membrane disruption, ion release, and …
Published in Journal of Polymer & Composites · Vol. 14, Issue 4, 2026 · pp. 236–253 Read article
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A New Protocol for The Synthesis of 5-(azidomethyl)-4-phenyl-1H- 1,2,3-triazole From Baylis-Hillman Adducts Derived from Nitro Olefins.
Abstract: The Baylis-Hillman adducts derived from nitroolefins have been convenientlytransformed into 5-(azidomethyl)-4-phenyl-1h-1,2,3-triazole via simple reaction condition. These compounds have been demonstrated for the synthesis of azidomethyl is highly biological reactive compounds. This novel bromo derivative of the BH adduct was simply treated with mole percentage of sodium azide in reactive condition. As a result, these novel azidomethylcompounds were extremely encouraging and provided fresh chances for building libraries of several new molecules. …
Published in Emerging Trends in Chemical Engineering · Vol. 9, Issue 2, 2022 · pp. 42–46 Read article
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Synthesis Effect of Natural/Chemical Blend Nanoparticles on Impact Strength of Sustainable Composite Material
Abstract: Synthesis effect of mixing two types of nanoparticles in the same matrix polyester based sustainable composite was studied in this article. The nanoparticles blend includes sunflower seeds and calcium carbonate with amount 1–3 wt.%. Results showed that the samples containing sunflower seed nanoparticles have high impact strength compared to the samples with calcium carbonate, and increases with increasing reinforcement ratio compared with sample having calcium carbonate nanoparticles. Keywords: Sustainable composite, …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 1, 2017 · pp. 1–5 Read article
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Synthesis, Characterization and Drug Delivery Application of Poly (Acid Fuchsin) Based Triblock Copolymer
Abstract: Synthesis, characterization and its drug delivery application of Poly (acid fuchsin) (PAF) was done under inert atmosphere. The (M0/I0) was maintained at 100. In order to increase the molecular weight and processability, it was block copolymerized with ε-caprolactone (CL) and tetrahydrofuran (THF) separately. The conductivity value of PAF was found to be decreased after the chemical conjugation with poly(ε-caprolctone) (PCL) and poly(tetrahydrofuran) (PTHF) blocks. Thus obtained triblock copolymer was subjected …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 2, 2016 · pp. 33–43 Read article
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Synthesis and Study of Different Thioamides as Corrosion Inhibitors
Abstract: Many organic compounds having electron rich atoms in their structures, such as nitrogen, and sulphur are widely use in lubricating additives, in the oil industry to minimize corrosion. The presence of electron rich atoms in the molecules increases its ability to form coordinate covalent bonds with the metal atoms, involved in the corrosion environment. Compounds based on fatty amines, aromatic amines, imidazoline, diamidazoline, and fatty amides are now, uses as …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 3, 2016 · pp. 18–25 Read article
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In Situ Synthesized Cu(OH)2-Al2O3: A Novel and Highly Efficient Nano-Catalyst System for One pot Synthesis of N-Substituted Triazole at Room Temperature
Abstract: One pot room temperature synthesis of N- substituted Triazoles has been demonstrated using a novel catalyst system Cu(OH)2-Al2O3. The catalyst has been synthesized by a very simple one step chemical process. The catalyst is highly efficient and reusable with isolated yield as high as 87% even at the 4th reuse. The catalyst could also be used with water as a solvent with a little longer reaction time. Graphical Abstract: One …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 8–14 Read article
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An Efficient Synthesis of Annulated Novel Dihydropyridine Derivatives using Zeolite H-BEA and Zeolite BEA-SO3H
Abstract: Modified zeolite (zeolite BEA-SO3H) was synthesized with intent to improve the surface area and Si/Al ratio by loading chlorosulphonic acid onto zeolite H-BEA. Parent and modified zeolite were characterized by variety of characterization techniques such as, ICP, FT-IR, XRD, TGA, NH3-TPD,BET surface area, etc. The catalytic applications of parent and modified zeolite H-BEA were demonstrated through the synthesis of novel quinoline and benzoquinoline substituted dihydropyridines (DHPs) via one pot Hantzsch …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 1–12 Read article
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Synthesis, Characterization of Mesoporous Zeolite BEA and Its Application in Multicomponent Reactions
Abstract: Strongly acidic mesoporous zeolite beta (MZB or Beta/MCM-41composite) with bimodal pore structure and stepwise distributed acidity has been synthesized by novel route using zeolite BEA as silica-alumina source. The material was characterized by various techniques. Powder XRD showed the existence of well-structured microphase zeolite Beta and mesophase MCM-41 in the composite materials. The performance of the composite material as a catalyst was investigated for the synthesis of various biologically active …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 3, 2014 · pp. 25–45 Read article
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Direct and rapid synthesis of amides from carboxylic acids under solvent free condition using Clay based Heterogeneous recyclable catalyst
Abstract: Direct condensation of Carboxylic Acids and Amines has resulted in a highly simple and practical technique for the synthesis of amides. Fe-Al clay catalyst was used in the solvent-free, microwave-irradiated amide synthesis. Only a small amount of the catalyst was needed to produce products in very short of time with a good yield. The catalyst was easy to separate and could be recycled several times with negligible loss of catalytic …
Published in Journal of Catalyst & Catalysis · Vol. 10, Issue 2, 2023 · pp. 1–9 Read article
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Network Analysis and Synthesis Through Graph Theory as a Tool
Abstract: AbstractAs time went on, the systems to be dealt with increased enormously in size and complexity. Simultaneously, there has been an evolution in combinatory and graph theory, which led to producing a number of highly efficient graph theoretic algorithms devised with an eye on economy in time and computer storage requirements. Because of space limitations the current review cannot deal with the whole spectrum of relevant topics and will try …
Published in Journal of Microwave Engineering and Technologies · Vol. 6, Issue 3, 2019 · pp. 11–17 Read article
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Development and Synthesis of Graphene Based Gas Sensor
Abstract: AbstractGraphene has become a promising material for many different applications, such as nano electronic devices, physical, chemical and biochemical sensors, transparent conductive films, clean energy scavenging and storage devices and nano composite formulation. Recently gas sensing as a critical application intelligent system, is receiving increasing attention in both industry and academia. Sensing application using graphene sheets as transducer have experienced surge of activities in recent years, especially for gas sensing …
Published in Journal of Semiconductor Devices and Circuits · Vol. 7, Issue 2, 2020 · pp. 13–19 Read article
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Performance Study for Optical Half Subtractor Based on SOA
Abstract: AbstractThis article explores for an optical binary half subtractor design which is based on the semiconductor optical amplifiers nonlinear characteristics. For that, the difference output operation of data’s has been realized in the one branch with semiconductor optical amplifier realizing XOR operation and for borrow operation the AND logic operation of the data B with complaint of data A is realized in the other semiconductor optical amplifier branch. Accordingly the …
Published in Trends in Opto-electro & Optical Communication · Vol. 5, Issue 3, 2015 · pp. 50–57 Read article
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Synthesis and Characterization of Aminophenyl (p-hydroxyphenyl)Tellurium(IV) Dichlorides
Abstract: The synthesis and characterization of a number of aminophenyl(p-hydroxyphenyl)tellurium(IV) dichlorides with the general formula RR´TeCl₂—where R stands for the p-hydroxyphenyl group and R´ denotes substituted amino aromatic moieties like aniline, N-methylaniline, and N,N-dimethylaniline—are reported in this study. Because of their distinctive structural characteristics, adaptable bonding behavior, and prospective uses in organic synthesis, catalysis, and medicinal chemistry, organotellurium compounds have garnered a lot of interest. The coordination behavior and electrical characteristics …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 17, Issue 2, 2026 · pp. 01–06 Read article