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57 articles for “reaction kinetics”
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Tracer Application in Study of Reaction Kinetics using Duolite ARA-9366B and Duolite A-638
Abstract: Radiotracer isotopes 131I and 82Br were used to study the iodide and bromide ion-isotopic exchange reactions taking place in two anion exchange resins Duolite ARA-9366B (nuclear grade) and Duolite A-638 (non-nuclear grade) under different operational parameters like temperature and ionic concentration of exchanging medium. The results of present investigation indicate an existence of strong positive linear co-relationship between amount of ions exchanged and concentration of ionic solution; while existence of …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 34–44 Read article
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Activation Energy in Photochemical and Thermally Driven Reactions: Mechanistic Insights, Kinetic Modelling and Photocatalytic Applications
Abstract: Chemical reactions constitute fundamental processes in which reactants are transformed into products through the breaking and formation of chemical bonds. In photochemical systems, these transformations are initiated or influenced by the absorption of light, making energy transfer mechanisms particularly significant. A key parameter governing reaction kinetics is activation energy, defined as the minimum energy required for reactant molecules to undergo a successful transformation. This article focuses on the role of …
Published in International Journal of Photochemistry and Photochemical Research · Vol. 4, Issue 1, 2026 · pp. 21–26 Read article
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Nondestructive Technique in Study of Purolite NRW-5010 and Duolite A-638 Anion Exchange Resins
Abstract: The present paper is one of the interesting applications of radioactive isotopes in nondestructive technique for performance evaluation of anion exchange resins Purolite NRW-5010 and Duolite A-638. The radioactive isotopes 131I and 82Br were used to trace the kinetics of ion-isotopic exchange reactions taking place between the resin surface and external ionic solution. It was observed that for bromide ion-isotopic exchange reaction at 35.0°C, when the concentration of bromide ions …
Published in Journal of Nuclear Engineering & Technology · Vol. 3, Issue 3, 2013 · pp. 1–11 Read article
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Solid-State Reactions: Mechanistic Insights, Kinetic Behavior and Emerging Applications in Advanced Materials
Abstract: Solid-state reactions are fundamental to the synthesis and transformation of inorganic materials, playing a crucial role in the development of ceramics, semiconductors, catalysts, and energy storage systems. Unlike reactions in liquid or gaseous phases, they are limited by restricted atomic mobility and typically require elevated temperatures to enhance diffusion and overcome activation energy barriers. These reactions proceed through interfacial contact between solid reactants, followed by nucleation of product phases and …
Published in International Journal of Crystalline Materials · Vol. 3, Issue 1, 2026 · pp. 10–14 Read article
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Kinetics of Ion-Isotopic Exchange Reactions using Nuclear Grade Resins Purolite NRW-4000 and Purolite NRW-60
Abstract: AbstractThe paper deals with an application of nondestructive radio isotopic tracer technique in performance evaluation of two nuclear grade anion exchange resins Purolite NRW-4000 and Purolite NRW-6000. The technique was used to study the kinetics of bromide and iodide ion-isotopic exchange reactions taking place between the external ionic solution and the resin surface for which 131I and 82Br were used as tracer isotopes. It was observe that at a constant …
Published in Journal of Nuclear Engineering & Technology · Vol. 4, Issue 1, 2014 · pp. 1–12 Read article
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Non-destructive Application of Tracer Isotopes to Study the Kinetics of Iodide and Bromide Ion-isotopic Exchange Reactions in Anion Exchange Resins Indion-103 and Duolite A-611
Abstract: The present study is concerned with non-destructive application of radio-analytical technique for characterization of industrial grade ion exchange resins Indion-103 and Duolite A-611. The radioactive tracer isotopes 131I and 82Br were used to trace the kinetics of iodide and bromide ion-isotopic exchange reactions taking place in the two resins. It was observed that during bromide and iodide ion-isotopic exchange reactions, under identical experimental conditions of temperature remaining constant at 40 …
Published in Journal of Nuclear Engineering & Technology · Vol. 3, Issue 2, 2013 · pp. 14–24 Read article
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Review and Opportunities for Thermal examination approaches Used to Investigate the Thermal Properties of Composite Compounds
Abstract: The use of thermal examination approach to assess the thermal quality of energy materials in “China” is concisely described. They are often used to calculate thermal stability, compatibility, and thermophysical constants, as well as to study thermal breakdown kinetics, causes, and interactions. Furthermore, a few studies focused on creativity or advancement, such as analyzing the mechanisms of topochemical reactions, assessing condensed-phase reaction kinetics by tracking the change in functional groups …
Published in Journal of Polymer & Composites · Vol. 12, Issue 6, 2024 · pp. 96–106 Read article
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Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
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Compatative Catalytic Study of Oxidation of Thiourea by Chromium (VI) in Presence of Different Catalysts and Micelles
Abstract: The series of catalysts like acetate, oxalate, EDTA, the varies micelles viz, CTAB, SDS, TRITON X-100 was carried out in the kinetic study of oxidation of Thiourea by Cr(VI) as an oxidant in water medium. The effect of catalytic efficiency has been study for varies catalyst and micelles by volumetric method and UV spectroscopic methods. The product was confirmed by IR studies. UV study reveals shows that higher catalytic efficiency …
Published in International Journal of Advance in Molecular Engineering · Vol. 4, Issue 1, 2026 · pp. 9–21 Read article
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Future Challenges of Photocatalytic Water Splitting: Sustainability
Abstract: Photocatalytic water splitting has emerged as a promising technology for sustainable hydrogen production through the direct utilization of solar energy. This process mimics natural photosynthesis, using semiconductor materials to absorb light and drive the decomposition of water into hydrogen and oxygen. The method provides a sustainable and eco-friendly solution to the global energy challenge by enabling the reduction of carbon emissions. Among various solar-to-chemical energy conversion approaches, photocatalytic water splitting …
Published in International Journal of Photochemistry and Photochemical Research · Vol. 3, Issue 2, 2025 · pp. 43–48 Read article
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MODELING AND SIMULATION OF ESTERIFICATION PROCESS IN REACTIVE DISTILLATION COLUMN USING ASPEN PLUS
Abstract: Abstract: Reactive distillation is a process that combined a chemical reaction and physical separation in a single unit operation. A results is carrying out simulation by using Aspen plus, it is shown in reactive distillation column. In this case, reaction takes place in liquid phase. While solving this type of problem, we have to use thermodynamics property. The boiling point of water is low and iso-amyl acetate having high boiling …
Published in Emerging Trends in Chemical Engineering · Vol. 5, Issue 1, 2018 · pp. 5–9 Read article
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AI-Driven IoT Ecosystems for Real-Time Thermo-Chemical Decision Making
Abstract: The efficient management of thermo-chemical processes is a critical challenge in modern industry, where maintaining precision, operational safety, and energy efficiency directly influences productivity and sustainability. The convergence of the Internet of Things (IoT) and Artificial Intelligence (AI) has transformed conventional industrial systems into intelligent, data-driven environments capable of continuous monitoring, predictive analysis, and autonomous decision-making. By integrating interconnected sensors, edge computing, cloud platforms, and advanced machine learning algorithms, industries …
Published in International Journal of Photochemistry and Photochemical Research · Vol. 4, Issue 2, 2026 · pp. 10–15 Read article
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Removal of CO2 using Aqueous Blends of Amines by Chemical Absorption Method: Modeling
Abstract: Carbon capture from point source emissions has been recognized as one of the several strategies necessary for mitigating unfettered release of greenhouse gases (GHG's) into the atmosphere to prevent global warming. To keep the GHG's at manageable level, large decrease of CO2 should take place through capture technologies like chemical absorption. Alkanolamines such as monoethanolamine (MEA), diethanolamine (DEA), and N-methyldiethanolamine (MDEA) have been used for gas treating at industries. There …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 1–5 Read article
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Synthesis of Biodiesel fuel additive from Glycerol using Cationic ion exchange resin- A review
Abstract: With the alarming increasing of oil consumption and the number of automotives being instilled, there has been immense research taking place to find a sustainable fuel to replace the current fossil fuels and also not render the current automotives obsolete. The current favorable solution to this is Biodiesel which can be generated either from oil seeds or waste vegetable oils. The selectivity of this process is 90% and the byproduct …
Published in Journal of Catalyst & Catalysis · Vol. 6, Issue 3, 2019 · pp. 1–8 Read article
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Modelling and Evaluation of Kinetics of Methane Chlorination using Matlab Techniques
Abstract: The chlorination of methane follows series-consecutive reaction mechanism to yield the chloromethanes products. The equation of reaction comprised of four consecutive step chemical reaction equations. The kinetics model for chlorination of methane into monochloromethane, dichloromethane, trichloromethane and tetrachloromethane was developed from the chemical reaction equations. In the elementary rate equation, the concentration of chlorine was assumed to be in excess, reducing the model to first order kinetics. The developed model …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 2, 2020 · pp. 31–36 Read article
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Kinetic Analysis of Structural Acrylic Curing by DSC: Polymerization and Phase Transition Optimization
Abstract: Differential Scanning Calorimetry (DSC) was used to analyse the thermal properties and curing behaviour of a structural acrylic adhesive at heating rates of 5, 10, and 15 °C/min. The study focused on the curing kinetics, glass transition temperature (Tg), specific rate (k), and activation energy (Ea) of the polymerization reaction. The material is tested according to ASTM 3418 standards. Results showed that increasing the heating rate shifted the endothermic curing …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 726–733 Read article
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Role of Solid Acid Catalyst in Isopropylation Reaction
Abstract: Cumene synthesis was carried out by the reaction of benzene with isopropyl alcohol in the vapour phase over rare earth metal modified 13X zeolite. Zeolite modification was done by exchanging sodium ions of the zeolite with cerium ions to vary the acidity of the catalyst in the range of 0.25‑1.36 meq/g. The synthesis was carried out over a wide range of operating conditions. The synthesis conditions were optimized by studying …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 2, 2015 · pp. 19–26 Read article
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Review on Effected Factors of Type of Products
Abstract: This survey covers effect of some factors in type of products in any reaction. A catalyst speeds up a chemical reaction, without being consumed by the reaction. Catalysts that used in any reaction, as it affects the nature of the product, its quantity, purity, color, degree of stability, the physical and chemical properties, the resulting isomers, the essential and secondary resulted of each reaction, and even the reaction conditions. It …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 3, 2020 · pp. 33–40 Read article
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Mechanistic and Catalytic Behavior of Os(VIII) for the Chlorpheniramine Maleate and Bromamine-B Redox System: A Kinetics Based Approach
Abstract: Chlorpheniramine maleate (CPM) is an important antihistamine agent. To the best of our knowledge there is no report in the literature about the oxidation of CPM with halogen + 1 oxidant from the stand point of its kinetics and mechanistic chemistry. Hence, a systematic kinetics and mechanistic study on the oxidation of CPM with bromamine-B (BAB) in the presence of NaOH and Os(VIII) catalyst has been carried out at 303 …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 18–31 Read article
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Solar Energy Materials Synthesis and Characterization
Abstract: The studies on the structural, microstructure and composition of the MoSe2 films are discussed in this research work. It deals with the optical properties of pulse plated films of MoSe2. Very little information has been given in the literature concerning the deposition current efficiency using pulse plating. In agreement with pulse plating theory, according to reference, the limiting overall plating rate of materials generally does not exceed the values for …
Published in Journal of Refrigeration, Air conditioning, Heating and ventilation · Vol. 6, Issue 3, 2019 · pp. 24–37 Read article