Search
51 articles for “Catalyzed”
-
Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
-
Kinetic Studies of Pristine and Nanonickel Catalyzed Ammonia Borane
Abstract: The high hydrogen content chemical hydride, Ammonia Borane (NH3BH3, AB) is considered in its pure and catalyzed form for decomposition kinetics. The thermodynamics and slow kinetics are the major issues in addition to potential damage the material likely to cause to the fuel cell. The ability of AB for faster dehydrogenation at lower temperatures with Nickel in its nanoform is explored. The release kinetics, activation energy is computed using Kissinger …
Published in Journal of Alternate Energy Sources & Technologies · Vol. 6, Issue 1, 2015 · pp. 7–13 Read article
-
Green Synthesis of Biologically Active 2, 4, 5- Trisubstituted Imidazoles Catalyzed by Large Pore Zeolite H-BEA through Lophine MCRs
Abstract: 2, 4, 5-triphenyl-1(H)-imidazoles (popularly known as Lophine derivatives) are well known heterocyclic compounds and find significant diversified applications, not only in the area of medicinal chemistry as biologically active drug-like molecules, but also in the other advanced research areas, such as fluorescence labelling, biological imaging and chromospheres for non-linear optic system. In the present endeavour, a green synthesis of Lophine derivatives via multi-component reaction is carried out using benzil/benzoin, substituted …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 20–36 Read article
-
Sulfated Zirconia Catalyzed Biodiesel Production from Acid Oil Containing High Free Fatty Acids
Abstract: Biodiesel fuel has shown great promise as an alternative to petro-diesel fuel. Biodiesel production is widely conducted through esterification and transesterification reaction, catalyzed by homogeneous or heterogeneous catalysts. In the present endeavour, sulphated zirconia has been prepared using microwave method and characterized by using XRD, FT-IR, BET surface area, SEM and acidity measurement. The utility of synthesized catalyst is demonstrated in catalytic biodiesel production from acid oil feed stock. The …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 2, 2017 · pp. 35–45 Read article
-
Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium
Abstract: The kinetics of ruthenium(III) catalyzed degradative oxidation of methylparaben by the copper complex, diperiodatocuprate(III) in alkaline medium is studied at 25ºC and at a ionic strength of 8.0 × 10−2 mol dm−3. In the presence of catalyst ruthenium(III), the reaction between methylparaben and diperiodatocuprate(III) in aqueous alkaline medium exhibits 1:1 stoichiometry. The oxidation products were identified by UV-visible, GC-MS and IR spectroscopy. The reaction exhibited unit order in case of …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 4–17 Read article
-
Assessing the State of Readiness in Medium and Large-Scale Industries for Introducing Innovative HR Practices to Catalyze Operational Excellence and Becoming a Cost-Quality Leader
Abstract: Innovative HR practices help company in catalyzing operational excellence and cost quality leader. Through innovative HR practices company can convert its intangible innovative HR practices in to tangible results. Before 5 to 10 years company considered HR department as a nonhju7-productive department; but now a day’s scenario has been changed; now a company considers HR department as the most crucial part of the company. The primary objective of this research …
Published in Journal of Production Research & Management · Vol. 6, Issue 2, 2016 · pp. 54–63 Read article
-
Productions and Characterization of Biodiesel by Base Catalyzed Transesterification Reaction from Dairy Waste Scum of DEI Dairy, Agra
Abstract: With the increase in prices and rapid depletion of petroleum-based fuels, the investigation is being done to look over an alternative fuel source. Presently, the biodiesel is mainly produced from vegetable sources such as jatropa oil, karanja oil, rapeseed, soybean, and others that could overlap with nutritional requirement of the society if produced at large scale. Also, the production cost of biodiesel from vegetable and animal sources is very high …
Published in Research and Reviews : Journal of Dairy Science and Technology Read article
-
Evaluation of the Emission and Engine Operability of Biodiesel and Biodiesel Blends Produced from Alkali-Catalyzed Esterification and Transesterification of Jatropha Oil Feedstock
Abstract: This study reports on the engine performance analysis of biodiesel and blends produced from jatropha-based bio-oil feedstock via combined esterification and transesterification process, the physiochemical of the bio-oil, and subsequent biodiesel produced. Jatropha bio-oil was characterized to determine its fuel properties. A liquid phase transesterification reaction at 60 min reaction time, 50°C temperature, using a methanol-oil molar ratio of 40:1 and 0.35 g of sodium hydroxide (NaOH) catalyst was carried …
Published in Journal of Petroleum Engineering & Technology · Vol. 15, Issue 1, 2025 · pp. 9–21 Read article
-
Pt (II) Schiff Base Complex Catalyzed Oxidation of Internal and Terminal Alkenes
Abstract: Pt (II) complexes of Schiff base ligands were found highly efficient towards the catalytic oxidation of internal alkenes and terminal alkenes in dimethylformamide (DMF) solvent under normal pressure of molecular oxygen. In some catalytic reactions, H2O2 was also used as co-oxidant. No diminished catalytic activity was observed even after six to eight repeated catalytic runs. Effect of temperature and extra ligand etc. on the rate of oxidation, nature and percentage …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 3, 2015 · pp. 7–15 Read article
-
Ru(III)-Catalyzed Oxidative Cleavage of Ritodrine Hydrochloride: A Kinetic and Mechanistic Study
Abstract: A systematic kinetic and mechanistic study of the oxidation of ritodrine hydrochloride (RTH) with chloramine-T (CAT) in both HClO4 and NaOH media has been carried out at 303 K. In acid medium, the reaction rate is very sluggish to be measured kinetically. Ruthenium (III) chloride ([Ru(III)]) was found to be an efficient catalyst. The reaction rate exhibits a first-order dependence on [CAT]0 in both media. It shows a fractional-order on …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 29–40 Read article
-
Biocatalytic Process by Biodiesel Production to the help of Environment
Abstract: The synthesis of fatty acid esters using vegetable oils seems to be a crucial process that yields good diesel fuel substitutes and useful oleochemical intermediates. Biodiesel is made from fatty acid methyl esters, which are a mixture of mono-alkyl esters produced from vegetable oils including sunflower oil, soyabean oil, rapeseed oil, peanut oil, cotton seed oil, and animal fats like pig fats and lard. Biodiesel can also be made from …
Published in Journal of Catalyst & Catalysis · Vol. 8, Issue 3, 2021 · pp. 29–33 Read article
-
Strategic Enhancement of Composite Strength Explored Through Comprehensive Integration of Flax Fiber and Cenosphere in Epoxy Resin Matrices
Abstract: The Current research delves into the mechanical attributes of composite specimens, integrating flax fiber and cenosphere fillers within an epoxy resin matrix catalyzed by K-6 hardener. Executing a meticulous approach involving a vacuum bagging method and a specific formulation of 10 wt.% cenosphere, 50% epoxy resin, and 40% flax fibers, the study rigorously scrutinized tensile and flexural strengths. Notably, the first specimen exhibited a peak tensile strength of 94.329 MPa, …
Published in Journal of Polymer & Composites · Vol. 11, Issue 13, 2023 · pp. 199–217 Read article
-
Use of Modified and Unmodified Calcium Oxide from Bio-resources as Heterogeneous Transesterification Catalyst for Biodiesel Synthesis: A Review
Abstract: Metal oxides have been widely used to catalyze various types of organic reaction, whatever supported or nonsupport metal oxide catalysts (supported with metal, mixed oxides and acids such as sulphoric acid). Calcium oxide is one of the most metal oxides used as heterogeneous catalysts; due to its favorable properties such as high activity, availability, low cost, and easily separated, as well as environmental friendly. Calcium oxide whether laboratory, prepared from …
Published in Emerging Trends in Chemical Engineering · Vol. 9, Issue 3, 2022 · pp. 30–34 Read article
-
The Comparative Catalytic Activities of Tungstate and Molybdate Ions on Oxygen Transfer Reactions Used in Production of Some Petrochemicals
Abstract: The comparative catalytic activities and kinetics of formation of glycerine from oxidation of allyl alcohol by hydrogen peroxide in the presence of sodium tungstate and sodium molybdate as catalyst have been studied. The reaction is zero order with respect to hydrogen peroxide concentration and the reaction is first order with respect to allyl alcohol and catalyst (sodium tungstate or sodium molybdate) concentrations. Tungstate catalyzed formation of glycerine from allyl alcohol …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 1, 2017 · pp. 24–29 Read article
-
Catalytic Applications of Copper Species in Organic Transformations: A Review
Abstract: Copper a naturally occurring element is present in the earth's crust, in oceans, lakes, and rivers, from minute trace element levels through to rich mine deposits. It is essential to life – plants, fish, animals and humans all need copper to function properly. Homogeneous copper catalyzed reactions are widely used for the construction of important organic molecules, including pharmaceuticals, commodity chemicals, and polymers. The development of copper catalysis has been …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 21–34 Read article
-
Driving Industrial Transformation: Catalytic Engineering for Chemicals, Energy, Materials, Food, Healthcare, and Environmental Protection
Abstract: Catalytic engineering encompasses diverse fields including heterogeneous catalysis, molecular catalysis, and biocatalysis, all of which have profound industrial impacts across various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection. In heterogeneous catalysis, solid catalysts play a pivotal role in facilitating chemical reactions at industrial scales. These catalysts are used in processes ranging from petrochemical refining to environmental remediation, enabling the efficient production of fuels, polymers, and other …
Published in Journal of Catalyst & Catalysis · Vol. 10, Issue 2, 2023 · pp. 26–32 Read article
-
Production of Biofuel (Biodiesel and Bioethanol):An economical and environmentally feasible way to the society
Abstract: In recent years, bio fuels growers have achieved significant enhancement in crop output and processing efficiencies and today the volume of bio fuels produced in a specific planted area is several times higher than it used to be as latest methodology and technical work to increase production of biofuel. In the sense of methodology, bio fuels are sub-divided into two large categories: substitute for diesel (biodiesel) and substitute for petroleum …
Published in Journal of Energy, Environment & Carbon Credits · Vol. 11, Issue 2, 2021 · pp. 1–10 Read article
-
Zeolite-Y Encapsulated Copper (II) and Cobalt (II) Species as Hybrid Nano-catalysts: Structural and Catalytic Aspects
Abstract: Special properties inherent to zeolites in facilitating the construction of novel upramolecular assemblies by encapsulation of guest molecules (metal complexes) into their large cages can be utilized to use these assembled materials as novel catalysts. These modified solids have the advantages of both behaving as the homogeneous and the heterogeneous catalytic system. In the present work, copper (II) and cobalt (II) complexes of 2-amino ethanoic acid (2-AEA) encapsulated in the …
Published in Journal of Catalyst & Catalysis Read article
-
Precision in Progress: The Crucial Nexus of Instrumentation and Measurement in Biotechnology Advancements
Abstract: This comprehensive review examines the critical importance of instrumentation and measurement technologies in enabling advances across diverse domains of modern biotechnology. Detailed examples are provided demonstrating how analytical tools empower quantitative biology, drive discoveries, catalyze innovations, and provide solutions to global challenges. The historical evolution of bioanalytical techniques is traced, highlighting milestones that unleashed new capabilities. Current trends and future outlook are explored, underscoring the ongoing pivotal need for precision …
Published in International Journal of Molecular Biotechnological Research · Vol. 1, Issue 2, 2023 · pp. 11–19 Read article
-
Pharmacophore mapping, 3D QSAR, docking, and ADME prediction studies of novel Benzothiazinone derivatives
Abstract: Background Tuberculosis is a major public health concern worldwide which is caused by Mycobacterium tuberculosis. DprE1 (Decaprenyl Phosphoryl Ribose 2’- Epimerase) is the most challenging target for development of novel anti- tubercular agents because it is a small protein and located into cytoplasmic membrane. So, novel anti-TB drugs did not bound effectively with it. DprE1 catalyzes the oxidation of the 2’ hydroxyl group of DPR (Decaprenyl Phosphoryl D- Ribose) …
Published in International Journal of Antibiotics · Vol. 1, Issue 1, 2024 · pp. 59–82 Read article