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57 articles for “reaction kinetics”
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Ru(III)-Catalyzed Oxidative Cleavage of Ritodrine Hydrochloride: A Kinetic and Mechanistic Study
Abstract: A systematic kinetic and mechanistic study of the oxidation of ritodrine hydrochloride (RTH) with chloramine-T (CAT) in both HClO4 and NaOH media has been carried out at 303 K. In acid medium, the reaction rate is very sluggish to be measured kinetically. Ruthenium (III) chloride ([Ru(III)]) was found to be an efficient catalyst. The reaction rate exhibits a first-order dependence on [CAT]0 in both media. It shows a fractional-order on …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 29–40 Read article
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Utilization of Bentonite Clay Coupled with Potash for the Synthesis of Octadec-9-Enoic Acid Methyl Esters of Pongamia Pinnatatriglycerides
Abstract: Due to the ever increasing human population worldwide, especially in the developing countries across the world; renewable energy sources are in the primary focus of the scientists and researchers. In addition, the depletion of the reserves of the fossil fuels along with the increased consumption of the available reserves has led to wide spread global unrest. Complementing the above, there are significant environmental problems namely global warming due to increased …
Published in Journal of Polymer & Composites · Vol. 10, Issue 2, 2022 · pp. 72–78 Read article
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Combustion Analysis of Ethanol in An HCCI Engine
Abstract: Improving fuel economy and reducing emissions are two major challenges being faced by the automotive industry. Alternative fuels and new combustion concepts are emerging to combat both pollution and fuel crises. Of late, the concept of Homogeneous Charge Compression Ignition, has been receiving increased attention due to its potential for simultaneously reducing fuel consumption, NOx and Particulate Emissions. In particular, in HCCI engine research, where combustion is regarded to be …
Published in Trends in Mechanical Engineering & Technology · Vol. 3, Issue 2, 2013 · pp. 1–9 Read article
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Water Chestnut Stem-Derived Biochar Supported AgNPs/AC-CTS-PVA Composite Gel for Wastewater Treatment and Potent Antibacterial Performance
Abstract: In the present study, green and efficient Ag-NPs functionalized activated carbon/chitosan-polyvinyl alcohol (AgNPs/AC-CTS-PVA) composite gel was successfully synthesized using water chestnut stem-derived biochar for wastewater treatment and antibacterial applications. The composite was characterized by FTIR, XRD, SEM-EDX, and TGA analyses, confirming the successful incorporation of crystalline Ag nanoparticles within the polymeric matrix and improved thermal stability. The material was tested regarding the removal of the dye of methylene blue (MB) …
Published in Journal of Polymer & Composites · Vol. 14, Issue 2, 2026 · pp. 1129–1144 Read article
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Improving Photocatalytic and Antibacterial Properties of Zein/Polyvinyl Alcohol Polymer Composite Film by Dispersing TiO2 Nano Particles
Abstract: Zein/polyvinyl alcohol/nano-TiO2 composite film was effectively blended using a solution casting method. Mechanical, photocatalytic, and antibacterial properties of the composite film were evaluated. The breaking elongation of the composite film increased up to the maximum loading of 0.4% of nano-TiO2. The humidity and moisture content relationship was estimated with standard modified models of Halsey, Oswin, Chung Pfost, and Henderson. It was found that the Halsey model was the most suitable …
Published in Journal of Polymer & Composites · Vol. 8, Issue 2, 2020 · pp. 110–127 Read article
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Pt (II) Schiff Base Complex Catalyzed Oxidation of Internal and Terminal Alkenes
Abstract: Pt (II) complexes of Schiff base ligands were found highly efficient towards the catalytic oxidation of internal alkenes and terminal alkenes in dimethylformamide (DMF) solvent under normal pressure of molecular oxygen. In some catalytic reactions, H2O2 was also used as co-oxidant. No diminished catalytic activity was observed even after six to eight repeated catalytic runs. Effect of temperature and extra ligand etc. on the rate of oxidation, nature and percentage …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 3, 2015 · pp. 7–15 Read article
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The Comparative Catalytic Activities of Tungstate and Molybdate Ions on Oxygen Transfer Reactions Used in Production of Some Petrochemicals
Abstract: The comparative catalytic activities and kinetics of formation of glycerine from oxidation of allyl alcohol by hydrogen peroxide in the presence of sodium tungstate and sodium molybdate as catalyst have been studied. The reaction is zero order with respect to hydrogen peroxide concentration and the reaction is first order with respect to allyl alcohol and catalyst (sodium tungstate or sodium molybdate) concentrations. Tungstate catalyzed formation of glycerine from allyl alcohol …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 1, 2017 · pp. 24–29 Read article
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Melanoma Skin Cancer Detection Using Deep Learning
Abstract: Cancer as one of the major diseases rank in the World is still very challenging to diagnose and treat hence need for the technological advancements. Chemotherapy, radiation, as well as surgery therapies have several drawbacks including non-selective action, damage to healthy tissues, and multi-drug resistance. Smart nano-theranostics, an advanced integration of nanotechnology with diagnostic and therapeutic modalities, offers a next-generation approach for precision oncology. Thus, the development of multifunctional nanoparticles …
Published in Research and Reviews: Journal of Oncology and Hematology · Vol. 14, Issue 2, 2025 · pp. 1–9 Read article
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Catalyst, Mixed Catalyst and Additive Effects on the Oscillatory Behaviour of Pyrogallol based Chemical Oscillator
Abstract: The present work is aimed to investigate the effect of the metal ions used as single as well as mixed catalysts and Mo(VI) ion as additive on the oscillatory behaviour of the reaction system comprising of pyrogallol (1,2,3-trihydroxybenzene) as organic substrate and inorganic bromate as oxidant in aqueous sulphuric acid medium (1.5 mol Lï€1). The reactions were monitored both spectrophotometrically and potentiometrically. From kinetic study, the order of reactivity of …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 2, 2014 · pp. 11–19 Read article
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BIOCHEMICAL AND KINETICS STUDIES ON PROTEASE ENZYME ISOLATED FROM AYURVEDIC HERBS ALONG WITH THEIR APPLICATION STUDIES
Abstract: The objective of the present work was to conduct comprehensive biochemical and kinetic analysis of a protease enzyme extracted from two Ayurvedic herbs, namely Shankhpushpi (Convolvulus prostratus) and Mulethi (Glycyrrhiza glabra). The primary focus was to characterize various biochemical aspects of the enzyme, encompassing substrate specificity, optimal pH and temperature conditions, stability, and activation energy. Furthermore, crucial kinetic parameters such as Michaelis-Menten constant (Km) and maximum reaction velocity (Vmax) were …
Published in Research and Reviews : A Journal of Biotechnology · Vol. 13, Issue 3, 2023 · pp. 21–37 Read article
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Rheological Studies of a Cross-Linked Polymer Gel System
Abstract: The petroleum accumulations are found associated with water and it is rarely obtained without accompanying water production. Water production is a major technical, environmental, and economic challenge associated with oil and gas extraction. Rheological findings are of fundamental importance for the development, manufacture and processing of innumerable products. Polymeric gels exhibit a wide range of rheological properties and they are stable both mechanically and thermally in most cases thus are …
Published in Journal of Petroleum Engineering & Technology · Vol. 16, Issue 2, 2026 · pp. 13–26 Read article
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Role of Polymeric Composites in Controlled Drug Release Systems
Abstract: In the realm of controlled drug release systems, polymeric composites have attracted a lot of interest as they possess several diverse characteristics that enable exact control of the drug delivery rate. This lowers adverse effects and increases the efficacy of treatment. Usually composed of biocompatible polymers combined with functional fillers like nanoparticles, ceramics, or hydrogels, these composites help to get the desired drug release patterns. Stable, biodegradable, and bioactive materials …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 453–465 Read article
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Formation of Reaction Bubbles in FCC Riser Reactor
Abstract: For modeling FCC unit, art of defining undefined hydrocarbon misxtures in conjunction with application of two different specialized fields of Chemical Engineering–Chemical Reaction Engineering (CRE) and Computational Fluid Dynamics (CFD) are required. CRE needs elaboarte and appropriate definition of undefined mixture and their chemical kinetics, whereas CFD needs solution of more regorous differential equations to define fluctuating and turbulent flow. Most of the reported works in available literature seems to …
Published in Journal of Petroleum Engineering & Technology · Vol. 1, Issue 1-3, 2011 · pp. 16–27 Read article
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Isolation and Identification of Novel Bacillus tequilensis TB5 from Vegetable Waste and Analyze the Effect of Rudiment Compounds on Bio-Catalytic α-Amylase Production
Abstract: AbstractAmylase is one of the basic components for leather, baking, textiles and paper industries. It hydrolyzes starch into simple productive sugar which reduces the cost of the final desired product. In this work, amylase producing novel Bacillus tequilensis TB5 was isolated from vegetable waste and different chemical compounds were added at different concentration in production medium to analyze its effect on amylase enzyme production. We observed that addition of weight/volume …
Published in Research and Reviews: A Journal of Microbiology and Virology · Vol. 9, Issue 2, 2019 · pp. 39–50 Read article
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Adsorption of Pb2+ from Simulated Solution using Raw Kola nut Pod Adsorbent
Abstract: This study investigated the removal of the Pb (II) ion from an aqueous solution using kola nut pod as a natural adsorbent. The batch adsorption experiment was carried out, and the parametric effect on removal of heavy metals was also investigated. kinetic data such as pseudo-first, second, and intraparticle diffusion models during the adsorption process were also evaluated. The optimum dose of adsorbent for Pb (II) removal was 2.5 g …
Published in Nano Trends – A Journal of Nano Technology & Its Applications · Vol. 25, Issue 1, 2023 · pp. 38–49 Read article
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Copper (II) catalyzed oxidation of Hydrazine hydrate by Potassium ferricyanide
Abstract: The kinetics of Cu(II) catalysed oxidation of hydrazine by hexacyanoferrate(III) is studied in acid medium. The stoichiometry of the reaction is 1:1. The first order condition is [N2H5]>[Fe(CN)63- ] is maintained. The order of the reaction is unity with respect to Fe(CN)63-, fractional orders with respect to hydrazine and copper. The reaction is independent of variation of sulphuric acid and ionic strength. A suitable mechanism is proposed for the reaction. …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 3, 2012 · pp. 22–29 Read article
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Copper(II) Catalyzed Oxidation of Hydrazine Hydrate by Hexacyanoferrate(III)
Abstract: The kinetics of Cu(II) catalyzed oxidation of hydrazine by hexacyanoferrate(III) is studied in acid medium. The stoichiometry of the reaction is 1:1. The first order condition [N2H5] > [Fe(CN)63−] is maintained. The order of the reaction is unity with respect to Fe(CN)63−, fractional orders with respect to hydrazine and copper. The reaction is independent of variation of sulphuric acid and ionic strength. A suitable mechanism is proposed for the reaction
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 1-3, 2012 · pp. 22–29 Read article
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Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium
Abstract: The kinetics of ruthenium(III) catalyzed degradative oxidation of methylparaben by the copper complex, diperiodatocuprate(III) in alkaline medium is studied at 25ºC and at a ionic strength of 8.0 × 10−2 mol dm−3. In the presence of catalyst ruthenium(III), the reaction between methylparaben and diperiodatocuprate(III) in aqueous alkaline medium exhibits 1:1 stoichiometry. The oxidation products were identified by UV-visible, GC-MS and IR spectroscopy. The reaction exhibited unit order in case of …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 4–17 Read article
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Photochemical Materials for Light-responsive Optical Switching: AI-optimized Design of Dynamic Visual Effects
Abstract: This paper presents an in-depth investigation into the design and behavior of photochemical materials that generate optical illusions and dynamic visual effects through light-induced molecular transformations. The study focuses on advanced photoresponsive compounds such as azobenzene and spiropyran derivatives, emphasizing their reversible optical transitions governed by photoisomerization, phase transitions, and photochromism in solid-state and polymeric matrices. Spectroscopic and kinetic analyses are employed to evaluate the influence of light wavelength, material …
Published in International Journal of Photochemistry and Photochemical Research · Vol. 3, Issue 2, 2025 · pp. 13–27 Read article
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AI-Assisted Kinetic Modeling of PLA Hydrolysis Under Subcritical Water Conditions for Sustainable Polymer Recycling
Abstract: The accumulation of poly (lactic acid) (PLA) in terrestrial and marine ecosystems has intensified the demand for closed-loop, green recycling technologies. Subcritical water (SCW) hydrolysis offers a promising, catalyst-free pathway for the rapid depolymerization of PLA into its constituent monomer, lactic acid. However, the complex, highly non-linear kinetics governing macro-molecular degradation under variable hydrothermal conditions limit real-time process optimization and industrial scalability. This study develops a novel artificial intelligence (AI)-assisted …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 17, Issue 2, 2026 · pp. 65–74 Read article