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94 articles for “kinetic modeling”
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Comparative Analysis of Kinetic Models for Simulation of Biogas Production from Cow Dung and Fruit Waste via Anaerobic Digestion
Abstract: This study investigates the optimization of biogas and biofertilizer production from cow dung and fruit waste through anaerobic digestion, utilizing various microbial growth kinetic models. Simulations were conducted using the Monod, Moser, Contois, and Tessier models to predict biogas yield and assess model accuracy. Results indicated that the Tessier model provided the closest fit to experimental data, with a biogas yield of 0.45 m³/kg VS, while the Monod model overestimated …
Published in International Journal of Membranes · Vol. 2, Issue 1, 2025 · pp. 47–63 Read article
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AI-Assisted Kinetic Modeling of PLA Hydrolysis Under Subcritical Water Conditions for Sustainable Polymer Recycling
Abstract: The accumulation of poly (lactic acid) (PLA) in terrestrial and marine ecosystems has intensified the demand for closed-loop, green recycling technologies. Subcritical water (SCW) hydrolysis offers a promising, catalyst-free pathway for the rapid depolymerization of PLA into its constituent monomer, lactic acid. However, the complex, highly non-linear kinetics governing macro-molecular degradation under variable hydrothermal conditions limit real-time process optimization and industrial scalability. This study develops a novel artificial intelligence (AI)-assisted …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 17, Issue 2, 2026 · pp. 65–74 Read article
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Activation Energy in Photochemical and Thermally Driven Reactions: Mechanistic Insights, Kinetic Modelling and Photocatalytic Applications
Abstract: Chemical reactions constitute fundamental processes in which reactants are transformed into products through the breaking and formation of chemical bonds. In photochemical systems, these transformations are initiated or influenced by the absorption of light, making energy transfer mechanisms particularly significant. A key parameter governing reaction kinetics is activation energy, defined as the minimum energy required for reactant molecules to undergo a successful transformation. This article focuses on the role of …
Published in International Journal of Photochemistry and Photochemical Research · Vol. 4, Issue 1, 2026 · pp. 21–26 Read article
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Isotherm and Kinetic Studies of Methylene Blue Dye Adsorption Using Sulfuric Acid Activated Nigerian Montmorillonite Clay
Abstract: The Presence of methylene blue and other basic dyes in water causes various harmful effects for both human and aquatic species. In this study, montmorillonite clay in its raw and acid (0.5M H2SO4) activated states were investigated for the sorption of methylene blue dye. The structural changes due to acid treatment were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). The studied parameters that affect adsorption efficiency were …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 2, 2020 · pp. 37–47 Read article
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Modelling and Evaluation of Kinetics of Methane Chlorination using Matlab Techniques
Abstract: The chlorination of methane follows series-consecutive reaction mechanism to yield the chloromethanes products. The equation of reaction comprised of four consecutive step chemical reaction equations. The kinetics model for chlorination of methane into monochloromethane, dichloromethane, trichloromethane and tetrachloromethane was developed from the chemical reaction equations. In the elementary rate equation, the concentration of chlorine was assumed to be in excess, reducing the model to first order kinetics. The developed model …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 2, 2020 · pp. 31–36 Read article
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Evaluation of Agro-based Adsorbents for Oil Spill Remediation in Freshwater and Saltwater Environments: Kinetic and Adsorption Model Analysis
Abstract: Environmental pollution caused by oil spills poses significant risks to both human health and ecosystems, particularly in regions like Nigeria’s Niger Delta, where oil spills are frequent. Conventional methods for oil spill cleanup have limitations, which has prompted research into alternative, more effective techniques. This study investigates the use of agro-based materials, specifically plantain and banana species, combined with clay soil as adsorbents for oil removal in freshwater and saltwater …
Published in Journal of Petroleum Engineering & Technology · Vol. 15, Issue 2, 2025 · pp. 22–32 Read article
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Effective Removal of Widely Applicable Pesticides Using Iron Pillared Clay (Fe/Bt): Adsorption Behaviour and Kinetics
Abstract: The vast application of pesticides for agricultural purpose to enhance adequate plant growth is quite alarming, with its negative environmental influence increasing every day. The current study investigates the potential of iron pillared bentonite (Fe/Bt) for effective removal of three different widely applicable pesticides (Glyphosate, Bentazon and Diazinon) in aqueous solution. This adsorbent has been characterized ab initio by FT-IR spectroscopy. Adsorption parameters such as contact time, initial pesticide concentration …
Published in Journal of Catalyst & Catalysis · Vol. 10, Issue 1, 2023 · pp. 10–20 Read article
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The Integrity of Eadic-Hofstee Plot Model to Predict the kinetic Parameters of Crude Oil Degradation using Vernonia amygdalina Stem
Abstract: The integrity of Eadic-Hofstee concept was tested for the determination of the functional coefficients and parameters of crude oil degradation kinetics. The techniques enhanced the relationship between the substrate divided by the specific rate of the substrate degradation against substrate concentration (TPH). The investigation reveals the values of the biokinetic parameters of maximum specific rate of substrate degradation (Vmax) and the equilibrium constant values of the substrate degradation (Ks). The …
Published in Journal of Petroleum Engineering & Technology · Vol. 14, Issue 2, 2024 · pp. 37–47 Read article
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Organophilicization of Bentonite by HDTMA+ and TMPA+ Cations for Sorption of 2,4-Dichlorophenol (2,4-DCP) in Aqueous Solution
Abstract: Bentonite (Bt) was converted to organoclays by intercalation of cationic surfactants into its interlayer space. Two types of organoclays were synthesized from HDTMA and TMPA at 100% CEC, and the adsorbents were characterized by FTIR, XRD and SEM. The adsorption capacities of Bt and the organoclays for the removal of 2,4-dichlorophrnol (2,4-DCP) from aqueous solutions were tested under different conditions. Two adsorption isotherm models (Langmuir and Freundlich isotherms) were used …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 3, 2020 · pp. 22–32 Read article
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Electromechanical Modeling of Microscale Fluidic Systems with Electro Kinetic
Abstract: Due to their capacity to carry out complex fluid manipulations at the microscale, microfluidic systems have become more popular in a variety of applications. For a variety of industries, including biomedical diagnostics, chemical analysis, and environmental monitoring, achieving precise and effective fluid control is essential. The electromechanical modeling of microscale fluidic systems using electro kinetic actuation is the main topic of this research study. We propose a thorough framework for …
Published in International Journal of Electro-Mechanics and Material Behaviour · Vol. 1, Issue 1, 2023 · pp. 18–22 Read article
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Photo-Catalytic Degradation of Rhodamine-B by using UV/TiO2 and Nb2O5 Process: A Kinetic Study
Abstract: The photo-catalytic degradation of Rhodamine-B (RB) in aqueous solution with titanium dioxide (TiO2) and niobium pentaoxide (Nb2O5) as photocatalyst in slurry form has been carried out using UV-A light (254 nm). The effect of various parameters such as catalyst loading, pH and initial concentration of the RB dye on degradation have been determined. An attempt has been made to study the effect of process parameters through concentration of dye, amount …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 3, 2014 · pp. 12–24 Read article
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Evaluation on Bioremediation Kinetics of Petroleum- Contaminated Soils Using Plant-Based Amendments
Abstract: The effectiveness of bioremediation processes is strongly influenced by environmental conditions, reactor design parameters, microbial characteristics, and pollutant properties. This study investigates the combined effects of environmental-related factors, reactor design considerations, organism- related characteristics, and pollutant properties on the degradation of total petroleum hydrocarbons (TPH) in swampy and clay soils amended. Laboratory-scale remediation experiments were conducted over an 84-day period using amendment dosages ranging from 20 to 100 g. The …
Published in Emerging Trends in Chemical Engineering · Vol. 13, Issue 1, 2026 · pp. 24–30 Read article
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Removal of AB 10B from Water by Copper Oxide Nano- Particles through Adsorption: A Kinetics and Thermodynamic Study
Abstract: Copper oxide nanoparticle was synthesized by a simple method. Consequently, adsorbent was characterized by using FTIR, XRD, and SEM techniques. The study of optimized parameter contains pH, initial dye concentration, adsorbent dose and contact time. Langmuir, Freundlich and Tempkin models were pragmatic for evaluating adsorption equilibrium data of AB 10B as the adsorbent but experiment show the Langmuir model is best for it. The adsorption kinetic model study was done …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 37–48 Read article
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Hexavalent Chromium Resistance Test of Saccharomyces Cerevisiae and Modeling of its Bioaccumulation Process
Abstract: Now a day, the release of high chromium containing tannery waste water from tanning industries to the environment is the life threatening action of human activities and bioaccumulation becomes a better alternative in treating heavy metals(such as Cr(VI) )due to its cost effective, relatively high heavy metal removal capacity and recovery property. Cell suspensions of S.cerevisiae at its exponential growth phase were added to 250 ml plastic flasks of containing …
Published in Emerging Trends in Chemical Engineering · Vol. 8, Issue 1, 2021 · pp. 36–44 Read article
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The Impact of Bacteria and Biostimulants on Crude Oil Breakdown in Loamy Soil
Abstract: This study investigates the influence of bacteria and biostimulants—specifically Bryophyllum pinnatum leaves soaked in both water and ethanol—on the degradation of crude oil in loamy soil. A laboratory-scale bioremediation setup was employed using a batch reactor model and first-order degradation kinetics to assess total petroleum hydrocarbon (TPH) breakdown under controlled conditions. Various analytical tools and procedures, including gas chromatography (Agilent 6890) and microbial media such as nutrient agar and mineral …
Published in International Journal of Pollution: Prevention & Control · Vol. 3, Issue 2, 2025 · pp. 15–22 Read article
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Design, Mathematical Modeling, and Dynamic Optimization of a Speed Breaker-Based Vehicular Kinetic Energy Harvester
Abstract: Decentralized energy harvesting methods are becoming more popular due to rapid urbanization and the rising need for sustainable infrastructure. The road-embedded vehicle kinetic energy harvester (VKEH) design, mathematical modelling, and experimental validation are presented in this work. This paper presents the structural engineering, continuum mathematical modeling, and experimental validation of an optimized road-embedded vehicular kinetic energy harvester (VKEH). The mechanism utilizes a spring- loaded, low-friction rack-and-pinion transmission coupled with a …
Published in International Journal of Electrical Power and Machine Systems · Vol. 4, Issue 2, 2026 Read article
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Crystallization Kinetics and Morphological Shifts in Polylactic Acid/Nanocellulose Blends Under Isothermal Melt Conditions
Abstract: The great potential of polylactic acid as a sustainable biopolymer for packaging, biomedical materials, and additive manufacturing, polylactic acid's slow crystallization kinetics during melt processing causes it to be poorly crystallized, thermally weak, and mechanically underperforming. Crystallization models of PLA/nanocellulose blends have been limited to isothermal melt crystallization kinetics and the resulting morphological changes. The phenomena discussed in this work are systematically explored by melt compounding of polylactic acid with …
Published in Journal of Polymer & Composites · Vol. 14, Issue 4, 2026 Read article
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Mechanistic and Catalytic Behavior of Os(VIII) for the Chlorpheniramine Maleate and Bromamine-B Redox System: A Kinetics Based Approach
Abstract: Chlorpheniramine maleate (CPM) is an important antihistamine agent. To the best of our knowledge there is no report in the literature about the oxidation of CPM with halogen + 1 oxidant from the stand point of its kinetics and mechanistic chemistry. Hence, a systematic kinetics and mechanistic study on the oxidation of CPM with bromamine-B (BAB) in the presence of NaOH and Os(VIII) catalyst has been carried out at 303 …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 18–31 Read article
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Synthesis of Biodiesel fuel additive from Glycerol using Cationic ion exchange resin- A review
Abstract: With the alarming increasing of oil consumption and the number of automotives being instilled, there has been immense research taking place to find a sustainable fuel to replace the current fossil fuels and also not render the current automotives obsolete. The current favorable solution to this is Biodiesel which can be generated either from oil seeds or waste vegetable oils. The selectivity of this process is 90% and the byproduct …
Published in Journal of Catalyst & Catalysis · Vol. 6, Issue 3, 2019 · pp. 1–8 Read article
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Facile Fabrication and Characterization of Novel Sterculia Gum–graft-poly(n-isopropylacrylamide-co-acrylamide) Hydrogel for Efficient Removal of Cationic Dyes from Aqueous Solution
Abstract: Water is indispensable component of life. Contamination of water is a severe problem that affects human health, aquatic vegetation, and fauna. Aside from various effluents, a variety of cationic dyes generated by industrial effluents contributes significantly to water contamination. In this study, a sterculia gum graft-poly(n-isopropylacrylamide-co-acrylamide) hydrogel was made using a graft copolymerization technique with N,N′-methylene-bis-acrylamide as a crosslinker, ammonium persulphate as an initiator, and tetramethylethylenediamine as an accelerator to …
Published in Journal of Polymer & Composites · Vol. 10, Issue 2, 2022 · pp. 29–59 Read article