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42 articles for “crosslinking”
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Effect of Polymer Crosslinking on Drug Release Kinetics
Abstract: In order to improve treatment effectiveness and minimise adverse effects, polymer-based drug delivery systems are often used to produce regulated and sustained drug release. Polymer crosslinking, which alters the structural, mechanical, and degrading characteristics of the polymer matrix, is one of the key elements affecting drug release kinetics. The porosity, swelling behaviour, and rate of degradation of the polymer are all impacted by the crosslinking process, which may be accomplished …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 636–647 Read article
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The Impact of Crosslinking Polyvinyl Alcohol with Glutaraldehyde on Toughness: A Statistical Analysis Using the Turnkey HSD Method
Abstract: The widespread use of non-biodegradable polymers exacerbates problems with global warming and other environmental difficulties. These problems necessitate the development of biodegradable polymers as a solution. In this research, we analyze the utilization of crosslinked polymer by its processing of polyvinyl alcohol (P V A) crosslinked with glutaraldehyde (G L U T). After curing for 24 hours in 2 moles of sulfuric acid (H2SO4), the plasticized alcohol has been cross-linked …
Published in Journal of Polymer & Composites · Vol. 12, Issue 3, 2024 · pp. 213–219 Read article
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Dissipative Particle Dynamics Simulation Study on the Evolution of Photoinitiated Free Radical Polymerization Crosslinked Networks
Abstract: Gradient polymer materials overcome the limitations of conventional homogeneous polymers by integrating multiple distinct functionalities within a single continuous structure. Although photoinitiated free-radical polymerization offers excellent spatial and temporal control, the underlying microscopic mechanisms governing network evolution under non-uniform light fields remain poorly understood. In this study, a mesoscale dissipative particle dynamics (DPD) model was successfully developed to couple free-radical polymerization kinetics—including initiation, propagation, crosslinking, and termination—with exponential light attenuation …
Published in Journal of Polymer & Composites · Vol. 14, Issue 4, 2026 · pp. 142–158 Read article
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Nano-Silica Reinforced Crosslinked Biopolymer–PCM Composites for Improved Thermal Cycling Durability
Abstract: Crosslinked biopolymer–PCM composites reinforced with nano-silica were developed to enhance thermal cycling durability, leakage resistance, and structural stability for advanced thermal energy storage applications. A starch-based biopolymer was chemically crosslinked using citric acid to create a stable polymer network, while paraffin was employed as the phase-change medium and nano-silica (1–4 wt%) served as a multifunctional inorganic reinforcement. FTIR analysis confirmed successful esterification between citric acid and the polymer backbone, indicated …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 1–10 Read article
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Marine Algal Microfiber and Agro-Waste Reinforced Crosslinked Polymer Composites for Sustainable Coastal Materials
Abstract: Crosslinked bio-polymer composites reinforced with marine algal microfibers and agro-waste fillers were fabricated and systematically characterized for sustainable coastal applications. Mechanical testing revealed that tensile strength increased from 18.5 MPa for neat polymer to 25.1 MPa at 20 wt.% reinforcement (~35% improvement), while the flexural modulus improved from 0.72 GPa to 1.02 GPa (~42% increase). Impact strength, however, decreased from 3.8 kJ/m² for neat polymer to 2.9 kJ/m² at 30 …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 210–223 Read article
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Green Fabrication of Glutaraldehyde-Crosslinked Chitosan/PVA Biocomposite for Heavy Metal Removal from Wastewater
Abstract: Chitosan (CS) and Polyvinyl alcohol (PVA) are polymers that possess biodegradable, biocompatible, and non-toxic properties, making them suitable for wastewater treatment applications. The primary objective of this research is to chemically modify chitosan in a novel manner to enhance its ability to remove hexavalent chromium Cr(VI) from aqueous solutions. In this study, a composite material was synthesized by crosslinking PVA and CS with glutaraldehyde (GA), resulting in the formation of …
Published in Journal of Water Pollution & Purification Research · Vol. 12, Issue 3, 2025 · pp. 59–83 Read article
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Crosslinked Starch Polymer for Coating on Fruit/Vegetable for Preservation Derived from Waste De-Oiled Soybean Cake
Abstract: Cross-linked starch films have been prepared by reacting starch extracted from de-oiled soybean cake (waste material from oil industry) with bio-based acids citric acid and tartaric acid. The obtained films were characterized by spectroscopic, thermal and surface morphological techniques. Thermal analysis showed that thin film has good thermal stability. The micrographs obtained from scanning electron microscopy showed the film surface has smooth and uniform morphology. Biological properties like cytocompatibility, antimicrobial …
Published in Journal of Catalyst & Catalysis Read article
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Crosslinked Starch Polymer for Coating on Fruit/Vegetable for Preservation Derived from Waste De-Oiled Soybean Cake
Abstract: Cross-linked starch films have been prepared by reacting starch extracted from de-oiled soybean cake (waste material from oil industry) with bio-based acids citric acid and tartaric acid. The obtained films were characterized by spectroscopic, thermal and surface morphological techniques. Thermal analysis showed that thin film has good thermal stability. The micrographs obtained from scanning electron microscopy showed the film surface has smooth and uniform morphology. Biological properties like cytocompatibility, antimicrobial …
Published in Journal of Catalyst & Catalysis · Vol. 8, Issue 2, 2021 · pp. 17–29 Read article
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Polymer Chemistry and Nanocomposite Network Design of PEGDA-Based Hydrogels
Abstract: The chemical structure and crosslinking density of polyethylene glycol diacrylate (PEGDA) can be systematically tailored, making it a versatile polymeric network in biomedical engineering, drug delivery, tissue engineering, biosensing and advanced manufacturing. PEGDA is a polymerizable acrylate-functionalized hydrophilic PEG that can be polymerized to make three-dimensional networks via free-radical polymerization, specifically photoinitiated. The resulting network architecture depends on the PEGDA molecular weight, the concentration of precursors, the polymerization conditions, the …
Published in Journal of Polymer & Composites · Vol. 14, Issue 5, 2026 Read article
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Iota carrageenan, a Sustainable polymer transformed into a nanogel formulation, by using environment friendly method for antitumor action
Abstract: In the pharmaceutical field, the utilization of polymers, both in their natural form and through chemical modifications, holds immense importance. In this context, a novel and eco-friendly method for the synthesis of nano carrageenan-based polymers has been developed. The efficacy of carrageenan in this domain is attributed to its crosslinking and biological properties, which are largely influenced by its sulfate ion content. This study aims to formulate nanogels via a …
Published in Journal of Polymer & Composites · Vol. 13, Issue 1, 2025 · pp. 881–889 Read article
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Polysaccharide-Based Hydrogels for Sustained Drug Release in Pharmacology
Abstract: Polysaccharide-based hydrogels have showed great potential in medicine as materials for long-lasting, under control medication delivery systems. Natural polysaccharides include chitosan; alginate, agarose, and cellulose form these hydrogels. Among its many advantages are biocompatibility, biodegradability, and customising ability for various drug release rates. Reacting to pH, temperature, and ionic strength changes in the surroundings, polysaccharide-based hydrogels may swell. For usage requiring the release of therapeutic substances over an extended period …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 300–312 Read article
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Valorization of Fruit and Vegetable Wastes for CA Production: A Comprehensive Review with Emphasis on Aspergillus niger Bioprocessing and Future Prospects
Abstract: Citric Acid (CA) is a multifunctional organic acid with diverse industrial applications, recently gaining prominence in polymer and composite science as a green crosslinker, compatibilizer, and functional additive. Conventionally produced through submerged fermentation of refined sugars by Aspergillus niger, industrial CA production faces sustainability challenges due to reliance on food-grade substrates. This review highlights emerging strategies for CA biosynthesis from vegetable and fruit processing residues—including cucumber peels, broccoli stalks, spinach …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 807–822 Read article
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Hydrogel Membranes for Skin Moisturization and Hydration: A Comparative Study
Abstract: Hydrogel membranes have emerged as a revolutionary technology in skin care, particularly for moisturizing and hydration applications. These water-swellable polymers mimic the extracellular matrix, providing an ideal environment for skin nourishment and moisture retention. This review comprehensively explores the various types of hydrogel membranes, including natural, synthetic, and hybrid formulations, highlighting their physicochemical properties, mechanisms of action, and applications in skin care. We examine how factors such as crosslinking density, …
Published in Recent Trends in Cosmetics · Vol. 1, Issue 1, 2024 · pp. 13–22 Read article
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Comparative Thermal Stability of Structural Acrylic and Polyurethane Adhesives under High Heating Rate Conditions
Abstract: This study examines the thermal stability and degradation characteristics of structural acrylic and polyurethane adhesives through Differential Scanning Calorimetry (DSC) at an elevated heating rate of 15 °C/min. The purpose of this study is to assess the impact of rapid thermal excitation on the volatile loss of adhesives, their curing behaviour, and thermal decomposition profiles elements that are essential in high-speed manufacturing and thermally challenging settings. The findings indicated that …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 717–725 Read article
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Comparative study of the Antibacterial Properties of Modified Textile Materials with Different Metal Nanoparticles
Abstract: A number of metal particles have proven antibacterial properties. In this study, a comparative analysis was made of two types of metal particles: zinc oxide and titanium oxide nanoparticles respectively, which were deposited on cellulose material and were fixed by means of a cross-linked gelatin hydrogel. Three methods were applied under different reaction conditions for obtaining the biocomposite materials. The biomaterials were investigated by means of scanning electron microscopy, transmittance …
Published in Journal of Polymer & Composites · Vol. 12, Issue 3, 2024 · pp. 92–101 Read article
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Structure–Property Relationships in Poly (N isopropylacrylamide) Hydrogels: Toward Thermoresponsive Polymer Composites
Abstract: Poly(N-isopropylacrylamide) (PNIPAAm) hydrogels can shift from solid to gel and back again at body temperature. Due to their lack structural integrity, thermal stability, and mechanical strength, they are difficult to use. This study mixed PNIPAAm with biocompatible fillers like chitosan and silicon nanoparticles to create hydrogels with superior structure-property correlations. Free radical polymerization with ammonium persulfate/TEMED initiator and N,N′-methylenebisacrylamide crosslinker produced the composites. Scanning electron microscopy showed a denser, interconnected …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 884–895 Read article
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Review Article on Biomedical Lubricant Hydrogels as Cartilage Substitutes
Abstract: This article underscores the increasing popularity of hydrogel lubricants in the biomedical domain and presents a comprehensive exploration of their potential as substitutes for cartilage. This understanding forms the foundation for the development of hydrogel-based lubricants that are designed to emulate these natural functionalities. Providing detailed insights, this article navigates through cutting-edge bio-inspired architecture techniques tailored to create hydrogels for cartilage. The emphasis is on achieving superior strength through diverse …
Published in Research & Reviews : Journal of Physics · Vol. 13, Issue 1, 2024 · pp. 35–48 Read article
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Role of Polymeric Composites in Controlled Drug Release Systems
Abstract: In the realm of controlled drug release systems, polymeric composites have attracted a lot of interest as they possess several diverse characteristics that enable exact control of the drug delivery rate. This lowers adverse effects and increases the efficacy of treatment. Usually composed of biocompatible polymers combined with functional fillers like nanoparticles, ceramics, or hydrogels, these composites help to get the desired drug release patterns. Stable, biodegradable, and bioactive materials …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 453–465 Read article
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Bio-inspired Thermo-responsive and Self-Healing Polymer–PCM Hybrids for Next-Generation Smart Textile Applications
Abstract: The integration of phase change materials (PCMs) into flexible polymers represents a promising strategy for developing smart textiles with advanced thermal regulation and mechanical adaptability. However, the challenges of PCM leakage, poor mechanical strength, and durability under cyclic stress have limited their practical applications. In this study, we present a novel self-healing and elastic composite based on thermoplastic polyurethane (TPU) incorporating 30 wt% microencapsulated PCM (mPCM) and dynamic disulfide bonds …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 228–238 Read article
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Polymer Chemistry-Guided Development of Biomimetic Composite Scaffolds
Abstract: Polymer chemistry plays a fundamental role in advancing biomaterials for anatomical tissue engineering, particularly in the design of composite scaffolds that replicate the intrinsic characteristics of native tissues. The regeneration of damaged tissues, especially within anatomically complex structures such as bone, cartilage, and skin, necessitates biomaterials that closely emulate the hierarchical architecture and biological functions of native extracellular matrices (ECMs). The capacity to replicate both mechanical and biochemical cues of …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 7–13 Read article