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10 articles for “crosslinked network structure”
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Dissipative Particle Dynamics Simulation Study on the Evolution of Photoinitiated Free Radical Polymerization Crosslinked Networks
Abstract: Gradient polymer materials overcome the limitations of conventional homogeneous polymers by integrating multiple distinct functionalities within a single continuous structure. Although photoinitiated free-radical polymerization offers excellent spatial and temporal control, the underlying microscopic mechanisms governing network evolution under non-uniform light fields remain poorly understood. In this study, a mesoscale dissipative particle dynamics (DPD) model was successfully developed to couple free-radical polymerization kinetics—including initiation, propagation, crosslinking, and termination—with exponential light attenuation …
Published in Journal of Polymer & Composites · Vol. 14, Issue 4, 2026 · pp. 142–158 Read article
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Machine Learning Based Optimization of Polymer Structure Property Relationships in Composite Material Systems
Abstract: In modern engineering applications, polymer-based composite materials have garnered a lot of attention because of their lightweight nature, high strength-to-weight ratio, and changing physical features. In order to maximize the relationships between polymer structure and properties in composite materials, this study suggests a strategy based on reinforcement learning (RL). The research utilized the Polymer Composite Properties Dataset, which contains 12,700 records associated with polymer matrices, reinforcement fillers, interfacial bonding characteristics, …
Published in Journal of Polymer & Composites · Vol. 14, Issue 3, 2026 · pp. 242–255 Read article
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Nano-Silica Reinforced Crosslinked Biopolymer–PCM Composites for Improved Thermal Cycling Durability
Abstract: Crosslinked biopolymer–PCM composites reinforced with nano-silica were developed to enhance thermal cycling durability, leakage resistance, and structural stability for advanced thermal energy storage applications. A starch-based biopolymer was chemically crosslinked using citric acid to create a stable polymer network, while paraffin was employed as the phase-change medium and nano-silica (1–4 wt%) served as a multifunctional inorganic reinforcement. FTIR analysis confirmed successful esterification between citric acid and the polymer backbone, indicated …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 1–10 Read article
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Structure–Property Relationships in Poly (N isopropylacrylamide) Hydrogels: Toward Thermoresponsive Polymer Composites
Abstract: Poly(N-isopropylacrylamide) (PNIPAAm) hydrogels can shift from solid to gel and back again at body temperature. Due to their lack structural integrity, thermal stability, and mechanical strength, they are difficult to use. This study mixed PNIPAAm with biocompatible fillers like chitosan and silicon nanoparticles to create hydrogels with superior structure-property correlations. Free radical polymerization with ammonium persulfate/TEMED initiator and N,N′-methylenebisacrylamide crosslinker produced the composites. Scanning electron microscopy showed a denser, interconnected …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 884–895 Read article
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Synthesis and Characterization of pH-Sensitive Poly (N-isopropylacrylamide-co-acrylic Acid) Hydrogels for Controlled Release of Doxorubicin
Abstract: pH-responsive polymeric hydrogels have attracted significant attention as intelligent biomaterials for site-specific and controlled drug delivery in cancer therapy due to their ability to respond to the acidic tumor microenvironment. In the present study, poly (N-isopropylacrylamide-co-acrylic acid) [P(NIPAM-co-AAc)] hydrogels were synthesized via free radical copolymerization and systematically characterized to evaluate their suitability for controlled delivery of doxorubicin, a widely used chemotherapeutic agent. The copolymer hydrogels were prepared using N-isopropylacrylamide and …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 449–458 Read article
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Effect of Polymer Crosslinking on Drug Release Kinetics
Abstract: In order to improve treatment effectiveness and minimise adverse effects, polymer-based drug delivery systems are often used to produce regulated and sustained drug release. Polymer crosslinking, which alters the structural, mechanical, and degrading characteristics of the polymer matrix, is one of the key elements affecting drug release kinetics. The porosity, swelling behaviour, and rate of degradation of the polymer are all impacted by the crosslinking process, which may be accomplished …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 636–647 Read article
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Digitally Tunable Dual-Phase Polymer–PCM Composites for IoT-Based Adaptive Thermal Management in Smart Buildings
Abstract: This study presents the design and development of digitally tunable dual-phase polymer–phase change material (PCM) composites for advanced thermal management in smart building applications. The composite is based on a hybrid polymer matrix comprising thermoplastic polyurethane (TPU) and a crosslinked polyvinyl alcohol (PVA) gel, reinforced with paraffin microencapsulated PCM and hydrated salt PCM to achieve multi-stage thermal energy storage. The polymer composite architecture enables enhanced structural integrity, high encapsulation efficiency …
Published in Journal of Polymer & Composites · Vol. 14, Issue 3, 2026 · pp. 147–157 Read article
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Polymer–Gel Composite Phase Change Materials: A Functional Polymer Composite Approach for Solar-Thermal Energy Storage in Building Facades
Abstract: This study investigates polymer–composite phase change materials (PCMs) in the form of polymer–gel hybrids as multifunctional systems for solar–thermal energy storage in building façades. Paraffin- and PEG-based PCMs were embedded into polyurethane and acrylic gel matrices to create shape-stabilized polymer–composites with high PCM loading (70–80 wt%). Differential Scanning Calorimetry (DSC) confirmed distinct melting/freezing transitions at ~56°C (paraffin) and ~42°C (PEG), with enthalpy values of 120–150 J/g, closely matching theoretical predictions, …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 36–51 Read article
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IoT-Enabled Polymer–Gel PCM Composites for Intelligent Thermal Management in Solar Facade Applications
Abstract: The present study investigates the development of a multifunctional polymer–gel phase change composite designed for solar façade applications with integrated real-time thermal monitoring capability. A crosslinked polyvinyl alcohol–borax matrix was employed as a three-dimensional polymer scaffold to encapsulate paraffin-based phase change material, ensuring leakage-free operation and structural integrity under repeated thermal cycling. Graphite nanoplatelets were incorporated as thermally conductive nano-fillers to enhance heat transfer through the polymer composite via percolation-driven …
Published in Journal of Polymer & Composites · Vol. 14, Issue 3, 2026 · pp. 99–111 Read article
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Review Article on Biomedical Lubricant Hydrogels as Cartilage Substitutes
Abstract: This article underscores the increasing popularity of hydrogel lubricants in the biomedical domain and presents a comprehensive exploration of their potential as substitutes for cartilage. This understanding forms the foundation for the development of hydrogel-based lubricants that are designed to emulate these natural functionalities. Providing detailed insights, this article navigates through cutting-edge bio-inspired architecture techniques tailored to create hydrogels for cartilage. The emphasis is on achieving superior strength through diverse …
Published in Research & Reviews : Journal of Physics · Vol. 13, Issue 1, 2024 · pp. 35–48 Read article