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16 articles for “Homogeneous catalyst”
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Optimisation of Biodiesel synthesis process from various edible oils using KOH and NaOH as homogeneous catalysts
Abstract: In the present experimental study, an optimization of biodiesel production from different kinds of edible oils (Palm oil, Cotton-seed oil and Sunflower oil) using KOH & NaOH as homogenous catalyst has been investigated by one step transesterification method. The research study was conducted into two parts. In the first experimental study, different types of edible oils (Sunflower oil, Cottonseed oil and Palm oil) have been optimised using KOH and NaOH …
Published in Emerging Trends in Chemical Engineering · Vol. 11, Issue 2, 2024 · pp. 69–77 Read article
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Review on: Heterogeneous Solid Base Catalyst Production from Waste Animal Bone as Transesterification of Jatropha Oil
Abstract: Biodiesel is produce mainly by transesterification, reacting vegetable oils or animal fats with monohydric alcohol in presence of a catalyst. The transesterification reaction is affected by various parameters. One of this parameter is catalyst type. Generally, catalysts used in transesterification reaction can be divided into three categories: homogenous, heterogeneous and enzymes. Heterogeneous catalysts offer numerous advantages over homogeneous catalysts as it can easily be separated from reaction mixture and can …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 1, 2020 · pp. 13–23 Read article
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Preparation of Biodiesel from Karanja Oil using Homogeneous and Heterogeneous Catalyst
Abstract: In India, diesel consumption is increasing at an alarming rate which is increasing the import bill and the problems related to environment pollution. Biodiesel (BD) from non-edible oil like karanja is attractive feed stock for diesel engine. Due to high acid value of karanja oil (KO), a two-step process is necessary for BD production using homogeneous catalyst. In present study, BD was produced from KO by transesterification process using homogeneous …
Published in Journal of Alternate Energy Sources & Technologies · Vol. 7, Issue 3, 2016 · pp. 23–37 Read article
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Application of Ultrasound for Synthesis of Biodiesel
Abstract: The aim of study is to synthesize a biodiesel from soybean oil using ultrasonic process. At present, biodiesel is produced in batch reactors in which the required energy is provided by heating by mechanical mixing. Alternatively, ultrasonic processing is an effective way to attain required mixing providing the necessary activation energy. Ultrasonic is a very desirable tool for producing biodiesel from vegetable oil and animal fats, because it lowers the …
Published in Emerging Trends in Chemical Engineering · Vol. 2, Issue 1, 2015 · pp. 1–8 Read article
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A comprehensive review on Sustainable Pathways to Synthesize 2, 5-Furandicarboxylic Acid (FDCA) from 5-Hydroxymethylfurfural (HMF) via Oxidative Processes
Abstract: The increasing global concern over the environmental impact of traditional plastics derived from petroleum and natural gas has spurred a search for more sustainable alternatives. Bioplastics, which are derived from renewable sources and may be biodegradable, have garnered significant interest as eco-friendly materials. Among the promising building blocks for bioplastics, 2,5-Furandicarboxylic Acid (FDCA) has emerged due to its potential to enhance polymer properties. One key precursor for bioplastics, 5-Hydroxymethylfurfural (5-HMF), …
Published in Emerging Trends in Chemical Engineering · Vol. 11, Issue 2, 2024 · pp. 01–13 Read article
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Heterogeneous vs. Homogeneous Catalysis: Comparative Insights and Breakthroughs
Abstract: Catalysis, a pivotal process in chemical reactions, can be classified into two main types: heterogeneous and homogeneous catalysis. This comparative analysis delves into the distinctions, advantages, and breakthroughs in both domains. Heterogeneous catalysis, involving catalysts in a different phase than the reactants, is characterized by ease of separation and catalyst recovery, making it industrially favorable. Conversely, homogeneous catalysis, where catalysts and reactants share the same phase, offers superior selectivity and …
Published in Journal of Catalyst & Catalysis · Vol. 10, Issue 3, 2023 · pp. 1–7 Read article
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Catalysis by Iridium (III) in the Oxidation of Hydrocarbons and Cyclic Alcohols by in situ Prepared Sodium Ferrate
Abstract: Potassium ferrate can be used as an oxidant only after separating it in the solid form for which tedious and multi-step process involving hazardous chemicals is required. Problems of separation of potassium ferrate in the solid form and its storage can be minimized if in situ prepared sodium ferrate is used as an oxidant which easily oxidizes hydrocarbons and cyclic alcohols from the synthetic point of view. Surprisingly, addition of …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 1, 2016 · pp. 25–31 Read article
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Sulfated Zirconia Catalyzed Biodiesel Production from Acid Oil Containing High Free Fatty Acids
Abstract: Biodiesel fuel has shown great promise as an alternative to petro-diesel fuel. Biodiesel production is widely conducted through esterification and transesterification reaction, catalyzed by homogeneous or heterogeneous catalysts. In the present endeavour, sulphated zirconia has been prepared using microwave method and characterized by using XRD, FT-IR, BET surface area, SEM and acidity measurement. The utility of synthesized catalyst is demonstrated in catalytic biodiesel production from acid oil feed stock. The …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 2, 2017 · pp. 35–45 Read article
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Role of Quantum Chemistry in Catalysis: A Comprehensive Review
Abstract: Catalysis plays a crucial role in modern chemical manufacturing, energy conversion, and environmental protection by enabling chemical reactions to occur more rapidly, selectively, and with reduced energy consumption. A fundamental understanding of catalytic processes at the atomic and electronic levels is essential for the rational design and optimization of catalysts. Quantum chemistry has emerged as a powerful theoretical and computational framework that enables detailed investigation of electronic structure, reaction energetics, …
Published in Journal of Catalyst & Catalysis · Vol. 13, Issue 1, 2026 · pp. 01–16 Read article
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Zeolite-Y Encapsulated Copper (II) and Cobalt (II) Species as Hybrid Nano-catalysts: Structural and Catalytic Aspects
Abstract: Special properties inherent to zeolites in facilitating the construction of novel upramolecular assemblies by encapsulation of guest molecules (metal complexes) into their large cages can be utilized to use these assembled materials as novel catalysts. These modified solids have the advantages of both behaving as the homogeneous and the heterogeneous catalytic system. In the present work, copper (II) and cobalt (II) complexes of 2-amino ethanoic acid (2-AEA) encapsulated in the …
Published in Journal of Catalyst & Catalysis Read article
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Zeolite-Y Encapsulated Copper (II) and Cobalt (II) Species as Hybrid Nano-catalysts: Structural and Catalytic Aspects
Abstract: Special properties inherent to zeolites in facilitating the construction of novel supramolecular assemblies by encapsulation of guest molecules (metal complexes) into their large cages can be utilized to use these assembled materials as novel catalysts. These modified solids have the advantages of both behaving as the homogeneous and the heterogeneous catalytic system. In the present work, copper (II) and cobalt (II) complexes of 2-amino ethanoic acid (2-AEA) encapsulated in the …
Published in Journal of Catalyst & Catalysis · Vol. 8, Issue 1, 2021 · pp. 19–32 Read article
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Esterification in Reactive Distillation Column Using Software Packages: A Review
Abstract: Abstract: Reactive distillation is the combination of reaction and separation in a same column. This represents an exciting alternative to traditional liquid phase chemical reaction processing. In reactive distillation, separation of products from unconverted reactants allows for better conversion, because produce elimination put out of place equilibrium and forces the reaction towards completion. The energy requirement of the conventional column is very and requires large recycling costs. Reactive Distillation is …
Published in Emerging Trends in Chemical Engineering · Vol. 5, Issue 1, 2018 · pp. 23–27 Read article
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Mechanism Action of Catalysis
Abstract: Catalysis is a method for speeding up the rate of a reaction. It is of three types homogeneous, biocatalysis and heterogeneous catalysis which further involve acid base catalysis, that is based on Brønsted-Lowry concept which state that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a base and in enzymatic catalysis every enzyme is specific to …
Published in Journal of Catalyst & Catalysis · Vol. 8, Issue 3, 2021 · pp. 22–28 Read article
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Catalytic Applications of Copper Species in Organic Transformations: A Review
Abstract: Copper a naturally occurring element is present in the earth's crust, in oceans, lakes, and rivers, from minute trace element levels through to rich mine deposits. It is essential to life – plants, fish, animals and humans all need copper to function properly. Homogeneous copper catalyzed reactions are widely used for the construction of important organic molecules, including pharmaceuticals, commodity chemicals, and polymers. The development of copper catalysis has been …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 21–34 Read article
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Solar Light Photocatalytic Degradation of Methylene Blue and Methyl Orange Dyes by Ag-ZnO Nanocomposite
Abstract: A highly efficient silver-assisted ZnO nanocomposite was synthesized using the co-precipitation method, a technique that ensures a controlled and homogeneous formation of the composite material. The high purity of the synthesized nanocomposite was confirmed through detailed FTIR spectra analysis, which showed clear and distinct peaks corresponding to the functional groups present, indicating the absence of significant impurities. To evaluate the photocatalytic capabilities of the nanocomposite, a series of tests were …
Published in Journal of Polymer & Composites · Vol. 12, Issue 6, 2024 · pp. 160–171 Read article
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Optimization of Direct Ink Writing Process Parameters for Liquid Silicone Rubber/TiO2 Composite Ink
Abstract: The purpose of this research is to develop and optimize the Liquid Silicone Rubber (LSR)/Titanium Dioxide (TiO₂) composite inks in Direct Ink Writing (DIW)-based 3D printing systems. The primary research objective was to use enhancement of mechanical, rheological, and dielectric characteristics of LSR using TiO₂ reinforcement but still retain extrusion stability and dimensional consistency. TiO₂ content (0, 5, 10, and 15 wt%) and catalyst and glycerol ratios were regulated and …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 240–259 Read article