Journal of Modern Chemistry & Chemical Technology
Volume 5, Issue 1 (2014)
Published
Table of contents
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Removal of CO2 using Aqueous Blends of Amines by Chemical Absorption Method: Modeling
Abstract: Carbon capture from point source emissions has been recognized as one of the several strategies necessary for mitigating unfettered release of greenhouse gases (GHG's) into the atmosphere to prevent global warming. To keep the GHG's at manageable level, large decrease of CO2 should take place through capture technologies like chemical absorption. Alkanolamines such as monoethanolamine (MEA), diethanolamine (DEA), and N-methyldiethanolamine (MDEA) have been used for gas treating at industries. There …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 1–5 Read article
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Synthesis and Characterization of Composites of Beryllia and Lithium-titanate Produced by Solid State Route
Abstract: Beryllium oxide (BeO) is proposed to be used as a constituent for lithium titanate (Li2TiO3) based composite material for neutron multiplication and breeding in International Thermonuclear Experimental Reactor (ITER) for its high thermal conductivity, low neutron absorption cross-section and high neutron reflection cross section. In the present investigation, we report the synthesis of single phase BeO-Li2TiO3 composites with BeO to Li2TiO3 (produced through solid state route) in volume ratios of …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 17–27 Read article
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Thermogravimetric and crystallinity studies of ER/PS blends
Abstract: Thermoplastic elastomeric blends of polystyrene (PS) and exudated resin (ER) were prepared by solution casting technique. The decomposition behavior of these blends was studied by thermogravimetric analysis. The effect of blend ratio and cross linking on the thermal behavior of ER/PS blend system was studied. An enhancement in thermal stability was observed by the addition of ER into polystyrene. The activation energy of degradation was calculated by using Horowitz-Metzger equation. …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 28–33 Read article
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Tracer Application in Study of Reaction Kinetics using Duolite ARA-9366B and Duolite A-638
Abstract: Radiotracer isotopes 131I and 82Br were used to study the iodide and bromide ion-isotopic exchange reactions taking place in two anion exchange resins Duolite ARA-9366B (nuclear grade) and Duolite A-638 (non-nuclear grade) under different operational parameters like temperature and ionic concentration of exchanging medium. The results of present investigation indicate an existence of strong positive linear co-relationship between amount of ions exchanged and concentration of ionic solution; while existence of …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 34–44 Read article
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Spectral, thermal, electrochemical and biological studies of Co(II), Ni(II), Cu(II) and Zn(II) complexes derived from 4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine.
Abstract: The Schiff base4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine and its Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized and characterized by IR, NMR, electronic, ESR, fluorescence, thermal, magnetic moment and electrochemical studies. IR and thermal data support the presence of coordinated water in the metal complexes. The electronic spectral and magnetic moment measurements indicate octahedral geometry for Co(II), Ni(II) and Zn(II) complexes and square planar for Cu(II) complexes. Biological studies of the ligand and …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 6–16 Read article