Journal of Polymer & Composites Original Research
Tailoring Toughness of Pineapple Leaf Fiber-Reinforced Epoxy Composites Using Halloysite Nanotubes
Abstract
This comprehensive study investigates the effects of halloysite nanotubes (HNTs) on the impact strength and fracture toughness of pineapple leaf fabric-reinforced epoxy (PALF/Ep) composites with an emphasis on sustainable material development. ASTM D256 and ASTM D5045 standards were followed in the fabrication of the composites. HNT weight percentages were systematically changed from 0 to 3wt% through using solution mixing and manual lay-up techniques, and vacuum bagging was used to obtain the best fiber-matrix impregnation. Results from these experimental studies demonstrate significant improvements in mechanical performance. According to single-edge notched bend tests, fracture toughness increased from 2.91 ± 0.3 MPa·m1/2 in the unfilled PALF/Ep to a maximum of 4.92 ± 0.2 MPa·m1/2 at 2wt% HNT loading. Izod impact testing revealed that impact strength reached a maximum of 433.9 J/m at this loading, an impressive 95.2% improvement above the unfilled PALF/Ep of 222.3 J/m. Due to nanotube agglomeration, which promoted stress concentrations and poor dispersion, performance somewhat decreased at 3wt% HNT loading. However, HNTs work well as nanofillers, increasing the PALF/Ep composite's impact and fracture toughness. These results advance bio-based engineering solutions by supporting HNT-modified PALF/Ep for high-performance green composites in structural areas including wind turbine blades and automotive panels.
Keywords
References (59)
- Kamarudin SH, Mohd Basri MS, Rayung M, et al. A review on natural fiber reinforced polymer composites (NFRPC) for sustainable industrial applications. Polymers. 2022;14(17):3698.
- McKay I, Vargas J, Yang L, et al. A review of natural fibers and biopolymer composites: progress, limitations, and enhancement strategies. Materials. 2024;17(19):4878.
- Sethupathi M, Khumalo MV, Skosana SJ, et al. Recent developments of pineapple leaf fiber (PALF) utilization in the polymer composites—a review. Separations. 2024;11(8):245.
- Roy S. Comparative analysis of thermo-physical and mechanical properties of PALF/CF/epoxy resin with and without nano TiO2 Journal of the Mechanical Behavior of Biomedical Materials. 2023; 148:106201.
- Nurazzi NM, Sabaruddin FA, Harussani MM, et al. Mechanical performance and applications of cnts reinforced polymer composites—A review. Nanomaterials. 2021;11(9):2186.
- da Luz FS, Garcia Filho FDC, Del-Rio MTG, et al. Graphene-incorporated natural fiber polymer composites: A first overview. Polymers. 2020;12(7):1601.
- Thomas J, Thomas PS, Stephen R. Improved mechanical, thermal, and barrier properties of halloysite nanotubes and nanocellulose incorporated PVA-PEO films: For food packaging applications. Food Packaging and Shelf Life. 2024;46:101373.
- Suresha B, Hemanth G. Effect of halloysite nanotubes on morphology and mechanical properties of alkali treated pineapple fiber reinforced epoxy composites. Materials Today: Proceedings. 2021;46:9047-9053.
- Chee SS, Jawaid M, Alothman OY, et al. Effects of nanoclay on mechanical and dynamic mechanical properties of bamboo/kenaf reinforced epoxy hybrid composites. Polymers. 2021;13(3):395.
- Mayakannan S, Raj JB, Raja VL, et al. Effectiveness of silicon nanoparticles on the mechanical, wear, and physical characteristics of PALF/sisal fiber–based polymer hybrid nanocomposites. Biomass Conversion and Biorefinery. 2023;13(14):13291-13305.
- Mousavi SR, Estaji S, Paydayesh A, et al. A review of recent progress in improving the fracture toughness of epoxy‐based composites using carbonaceous nanofillers. Polymer Composites. 2022;43(4):1871-1886.
- Zeinedini A. Fracture toughness of graphene/polymer nanocomposites: well dispersion, agglomeration and toughening mechanisms. Theoretical and Applied Fracture Mechanics. 2024;131:104449.
- Shirodkar N, Cheng S, Seidel GD. Enhancement of Mode I fracture toughness properties of epoxy reinforced with graphene nanoplatelets and carbon nanotubes. Composites Part B: Engineering. 2021;224:109177.
- Raghavendra S, Sannegowda RR, Rudrappa AK, et al. Enhancement of tensile strength and fracture toughness characteristics of banana fiber reinforced epoxy composites with nano MgO fillers. Next Materials. 2024;5:100258.
- Dungani R, Sumardi I, Alamsyah EM, et al. A study on fracture toughness of nano-structured carbon black-filled epoxy composites. Polymer Bulletin. 2021;78(12):6867-85.
- Sun DX, Huang CH, Zhang ZX, et al. Synchronously enhancing fracture toughness and mechanical strength of polyester blend composites via constructing dual-network structures of one-dimensional carbon nanofillers. Polymer. 2025;324:128242.
- Kavosi J, Sarikaya S, Creasy TS, et al. Identification of the effect of nanofiller morphology on interlaminar fracture toughness of hybrid composites. Journal of Composite Materials. 2021;55(21):2899-2910.
- Tee ZY, Yeap SP, Hassan CS, et al. Nano and non-nano fillers in enhancing mechanical properties of epoxy resins: a brief review. Polymer-Plastics Technology and Materials. 2022;61(7):709-725.
- Al-Maharma AY, Sendur P. Review of the main factors controlling the fracture toughness and impact strength properties of natural composites. Materials Research Express. 2018;6(2):022001.
- Wang S, Zhao B, Cong F, et al. Study on the synergistic effect of carbon nanofillers on the interlaminar toughness of fiber metal laminates. Materials Today Communications. 2022;33:104218.
- Prasad V, Sekar K, Varghese S, et al. Evaluation of interlaminar fracture toughness and dynamic mechanical properties of nano TiO2 coated flax fiber epoxy composites. Polymer Testing. 2020 ;91:106784.
- Malik K, Ahmad F, Yunus NA, et al. The hybridization effects of glass and carbon fibers on the mechanical properties of kenaf mat/epoxy composites. Journal of Natural Fibers. 2022;19(17):15432-47.
- Razavi SMJ, Neisiany RE, Razavi M, et al. Efficient improvement in fracture toughness of laminated composite by interleaving functionalized nanofibers. Polymers. 2021;13(15):2509.
- Vallack N, Sampson WW. Materials systems for interleave toughening in polymer composites. Journal of Materials Science. 2022;57(11):6129-6156.
- Shrivastava R, Singh KK. Interlaminar fracture toughness characterization of laminated composites: a review. Polymer Reviews. 2020;60(3):542-93.
- Mahadevaswamy HS, Suresha B. Role of nano-CaCO3 on mechanical and thermal characteristics of pineapple fiber reinforced epoxy composites. Materials Today: Proceedings. 2020;22:572-579.
- Arul M, Sasikumar KSK, Sambathkumar M, et al. Enhancement of fracture toughness characteristics of woven jute fabric mat reinforced epoxy composites with SiC fillers. Journal of Natural Fibers. 2023;20(1):2144979.
- Olusanya JO, Mohan TP, Kanny K. Fracture toughness of hybrid natural fiber/nanoclay reinforced starch biocomposite material. Composites and Advanced Materials. 2023;32:26349833231188980.
- Li X, Wang Q, Cui X, et al. Study on the mechanical and toughness behavior of epoxy nano-composites with zero-dimensional and two-dimensional nano-fillers. Polymers. 2022;14(17):3618.1
- Biswas PK, Omole O, Peterson G, et al. Carbon and cellulose based nanofillers reinforcement to strengthen carbon fiber-epoxy composites: Processing, characterizations, and applications. Frontiers in Materials. 2023;9:1089996.
- Dejene BK. Advancing natural fiber-reinforced composites through incorporating ZnO nanofillers in the polymeric matrix: a review. Journal of Natural Fibers. 2024;21(1):2356015.
- Mahmud MZ, Rabbi SF, Islam MD, et al. Synthesis and applications of natural fiber‐reinforced epoxy composites: A comprehensive review. SPE Polymers. 2025;6(1):e10161.
- Amjad A, Anjang Ab Rahman A, et al. A review investigating the influence of nanofiller addition on the mechanical, thermal and water absorption properties of cellulosic fibre reinforced polymer composite. Journal of Industrial Textiles. 2022;51(1_suppl):65S-100S.
- Mousavi SR, Estaji S, Paydayesh A, et al. A review of recent progress in improving the fracture toughness of epoxy‐based composites using carbonaceous nanofillers. Polymer Composites. 2022;43(4):1871-1886.
- Cozza RC, Verma V. Evaluation of fracture toughness of epoxy polymer composite incorporating micro/nano silica, rubber and CNTs. Polímeros. 2020;30:e2020030.
- Bakhori SN, Hassan MZ, Bakhori NM, et al. Mechanical properties of PALF/kevlar-reinforced unsaturated polyester hybrid composite laminates. Polymers. 2022;14(12).
- D20 Committee. Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics. doi:10.1520/d0256-10
- D20 Committee. Test Methods for Plane-Strain Fracture Toughness and Strain Energy Release Rate of Plastic Materials. doi:10.1520/d5045-14
- Idumah CI, Hassan A, Ogbu J, et al. Recently emerging advancements in halloysite nanotubes polymer nanocomposites. Composite Interfaces. 2019;26(9):751-824.
- Krishnaiah P, Manickam S, Ratnam CT, et al. Mechanical, thermal and dynamic-mechanical studies of functionalized halloysite nanotubes reinforced polypropylene composites. Polymers and Polymer Composites. 2021;29(8):1212-1221.
- Rasana N, Murugan S, Rammanoj G, et al. The effect of different nanofillers on the morphology, mechanical, sorption and thermal properties of polypropylene based hybrid composites. Materials Today: Proceedings. 2020;24:1273-1281.
- Ashok KG, Kalaichelvan K, Damodaran A. Effect of nano fillers on mechanical properties of luffa fiber epoxy composites. Journal of Natural Fibers. 2022;19(4):1472-1489.
- Mohanavel V, Ravichandran M. Influence of nanofillers on the mechanical characteristics of natural fiber reinforced polymer composites. ECS Transactions. 2022;107(1):12513.
- Ge M, Li X, Su X, et al. Improvement of Mechanical and Acoustic Characteristics of Halloysite Nanotube-Reinforced Polyurethane Elastomer Composites and Their Applications. Polymers. 2024;16(21):3025.
- Stern T, Marom G. Fracture Mechanisms and Toughness in Polymer Nanocomposites: A Brief Review. Journal of Composites Science. 2024 Oct 1;8(10):395.
- Aguiar R, Miller RE, Petel OE. Microstructural evidence of the toughening mechanisms of polyurethane reinforced with halloysite nanotubes under high strain-rate tensile loading. Scientific Reports. 2021 Jun 23;11(1):13161.
- Churruca MJ, Moran JI, Rodriguez ES. Effect of Halloysite Nanotubes on Matrix Microcracking in Carbon Fiber/Epoxy Composites. Mechanics of Composite Materials. 2022 May;58(2):293-304.
- Franciszczak P, Taraghi I, Paszkiewicz S, et al. Effect of halloysite nanotube on mechanical properties, thermal stability and morphology of polypropylene and polypropylene/short kenaf fibers hybrid biocomposites. Materials. 2020;13(19):4459.
- Kosedag E. The effect of halloysite nanotubes reinforced epoxy filler on the crushing behavior of aluminum tubes. Journal of Applied Polymer Science. 2024;141(3):e54902.
- Chakraborty S, Chakraborty AK, Barbezat M, et al. Interfacial interaction and the fracture toughness (KIC) trends in epoxy nanocomposites filled with functionalized graphene‐based fillers. Polymer Composites. 2018;39(S4):E2356-E2369.
- Muralidhara B, Kumaresh Babu SP, Suresha B et al. Enhanced mechanical, thermal, and wear performance of halloysite nanotube infused carbon fiber epoxy composites. Scientific Reports. 2025;15(1):1-25.
- Hulugappa B, Achutha MV, Suresha B. Effect of fillers on mechanical properties and fracture toughness of glass fabric reinforced epoxy composites. Journal of Minerals and Materials Characterization and Engineering. 2016;4(01):1.
- Khalid MY, Kamal A, Otabil A, et al. Graphene/epoxy nanocomposites for improved fracture toughness: A focused review on toughening mechanism. Chemical Engineering Journal Advances. 2023;16:100537.
- Kosedag E. The effect of halloysite nanotubes reinforced epoxy filler on the crushing behavior of aluminum tubes. Journal of Applied Polymer Science. 2024;141(3):e54902.
- Ulus H, Kaybal HB, Eskizeybek V, et al. Halloysite nanotube reinforcement endows ameliorated fracture resistance of seawater aged basalt/epoxy composites. Journal of composite materials. 2020;54(20):2761-79.
- Zhang J, Zhang Z, Huang R, et al. Advances in Toughening Modification Methods for Epoxy Resins: A Comprehensive Review. Polymers. 2025;17(9):1288.
- Al-Maharma AY, Sendur P. Review of the main factors controlling the fracture toughness and impact strength properties of natural composites. Materials Research Express. 2018;6(2):022001.
- Guo Z, Ning N, Zhou G, et al. Toughening of Infusible Epoxy Resins by Core/Shell Nanoparticles Plus a Soluble Thermoplastic Polymer and Their Synergistic Mechanism at the Mesoscopic Morphological Level. ACS Applied Polymer Materials. 2025 Mar 3;7(5):3085-92.
- Wenbin JIA, Lei FANG, Jian SHI, et al. Optimal design of fracture toughness for CNT-epoxy composites. Acta Aeronautica et Astronautica Sinica. 2024;45(7).