Journal of Polymer & Composites Original Research
Durability Assessment of Geopolymer and OPC Concretes under Chloride and Sulphate Chemical Attack
Abstract
The main problems with durable concrete constructions are attacks by sulphates and chlorides on concrete. The primary objective of this study is to evaluate how the strength properties of concrete are affected by the incorporation of fly ash when exposed to environmental conditions involving sulphate and chloride solutions. In this research, geopolymer concrete (GPC) is utilized as a replacement for conventional ordinary Portland cement (OPC). The concrete composition is prepared with geopolymer varies. Samples are demolded and then submerged in water for a full 28 days to cure. Following this, the samples are placed in different solutions of 10% sodium chloride (NaCl) and 10% sodium sulphate (Na2SO4) for hardening times at 28, 56, and 90 days respectively. A degree of damage, variation in compressive strength, and weight change were used to assess the impacts of sulphate and chloride on the concretes. After 90 days, the exposure of fly ash to concrete significantly improved its compressive strength at 33.11% as compared to the strength of 10% NaCl solution, water and OPC, respectively. In contrast to the OPC, the 10% NaCl solution decreased the compressive strength of fly ash-containing GPC after 90 days of exposure. In comparison to other models, the maximum ultrasonic pulse velocity of GPC-7 was attained at 4430 m/s. The minimal charge cleared in the GPC-7 fast chloride permeability test is 1045 coulombs. According to this study, adding fly ash to concrete as an additional cementitious material may help lessen the harmful impacts of sulphate and chloride salts. The study's findings suggest that adding ground fly ash to concrete as an additional cementitious element strengthens the material's durability to harsh environments.
Keywords
References (48)
- Reddy DV, Edouard JB, Sobhan K. Durability of Fly Ash–Based Geopolymer Structural Concrete in the Marine Environment. Journal of Materials in Civil Engineering. 2013;25(6):781-787. doi:10.1061/(asce)mt.1943-5533.0000632
- Maranan G, Manalo A, Karunasena K, Benmokrane B. Bond Stress-Slip Behavior: Case of GFRP Bars in Geopolymer Concrete. Journal of Materials in Civil Engineering. 2015;27(1). doi:10.1061/(asce)mt.1943-5533.0001046
- Effect of Na2SiO3/NaOH Ratios and NaOH Molarities on Compressive Strength of Fly-Ash-Based Geopolymer. ACI Materials Journal. 2012;109(5). doi:10.14359/51684080
- Wiyono D, Antoni, Hardjito D. Improving the Durability of Pozzolan Concrete Using Alkaline Solution and Geopolymer Coating. Procedia Engineering. 2015;125:747-753. doi:10.1016/j.proeng.2015.11.121
- Sharma U, Gupta N, Verma M. Prediction of compressive strength of GGBFS and Flyash-based geopolymer composite by linear regression, lasso regression, and ridge regression. Asian Journal of Civil Engineering. 2023;24(8):3399-3411. doi:10.1007/s42107-023-00721-2
- Shaikh FUA. Mechanical and durability properties of fly ash geopolymer concrete containing recycled coarse aggregates. International Journal of Sustainable Built Environment. 2016;5(2):277-287. doi:10.1016/j.ijsbe.2016.05.009
- Kabir SMA, Alengaram UJ, Jumaat MZ, Yusoff S, Sharmin A, Bashar II. Performance evaluation and some durability characteristics of environmental friendly palm oil clinker based geopolymer concrete. Journal of Cleaner Production. 2017;161:477-492. doi:10.1016/j.jclepro.2017.05.002
- Moni SMFK, Ikeora O, Pritzel C, Görtz B, Trettin R. Preparation and properties of fly ash-based geopolymer concrete with alkaline waste water obtained from foundry sand regeneration process. Journal of Material Cycles and Waste Management. 2020;22(5):1434-1443. doi:10.1007/s10163-020-01032-3
- Bidwe, S.S.; Hamane, A.A. Effect of Different Molarities of Sodium Hydroxide Solution on the Strength of Geopolymer Concrete. Am. J. Eng. Res. 2015, 4, 139–145.
- Habert G, d’Espinose de Lacaillerie JB, Roussel N. An environmental evaluation of geopolymer based concrete production: reviewing current research trends. Journal of Cleaner Production. 2011;19(11):1229-1238. doi:10.1016/j.jclepro.2011.03.012
- Yost JR, Radlińska A, Ernst S, Salera M. Structural behavior of alkali activated fly ash concrete. Part 1: mixture design, material properties and sample fabrication. Materials and Structures. 2012;46(3):435-447. doi:10.1617/s11527-012-9919-x
- Puligilla S, Mondal P. Role of slag in microstructural development and hardening of fly ash-slag geopolymer. Cement and Concrete Research. 2013;43:70-80. doi:10.1016/j.cemconres.2012.10.004
- Verma, M. Study on Behaviour of Geopolymer Concrete, Delhi Technological University: New Delhi, 2021.
- Kumar R, Verma M, Dev N. Analysis of PCE-based Superplasticiser for the Different Types of Cement using Marsh Cone Test. Evergreen. 2024;11(2):665-672. doi:10.5109/7183337
- Ren W, Xu J, Bai E. Strength and Ultrasonic Characteristics of Alkali-Activated Fly Ash-Slag Geopolymer Concrete after Exposure to Elevated Temperatures. Journal of Materials in Civil Engineering. 2016;28(2). doi:10.1061/(asce)mt.1943-5533.0001406
- Hamidi F, Aslani F, Valizadeh A. Compressive and tensile strength fracture models for heavyweight geopolymer concrete. Engineering Fracture Mechanics. 2020;231:107023. doi:10.1016/j.engfracmech.2020.107023
- Kumar R, Verma M, Dev N. Investigation on the Effect of Seawater Condition, Sulphate Attack, Acid Attack, Freeze–Thaw Condition, and Wetting–Drying on the Geopolymer Concrete. Iranian Journal of Science and Technology, Transactions of Civil Engineering. 2021;46(4):2823-2853. doi:10.1007/s40996-021-00767-9
- Kumar R, Dev N, Ram S, Verma M. Investigation of dry-wet cycles effect on the durability of modified rubberised concrete. Forces in Mechanics. 2023;10:100168. doi:10.1016/j.finmec.2023.100168
- Law, C.G.S.S. and D.W.; Gunasekera, C.; Setunge, S.; Law, D.W.; Law, C.G.S.S. and D.W.; Gunasekera, C.; Setunge, S.; Law, D.W.; Law, C.G.S.S. and D.W.; Law, Chamila Gunasekera, S.S. and D.W.; et al. Correlations between Mechanical Properties of Low-Calcium Fly Ash Geopolymer Concretes. J. Mater. Civ. Eng. 2017, 9, 04017111–04017119, doi:10.1061/(ASCE).
- Kumar R, Verma M, Dev N, Lamba N. Influence of chloride and sulfate solution on the long‐term durability of modified rubberized concrete. Journal of Applied Polymer Science. 2022;139(37). doi:10.1002/app.52880
- Tran TT, Pham TM, Hao H. Effect of hybrid fibers on shear behaviour of geopolymer concrete beams reinforced by basalt fiber reinforced polymer (BFRP) bars without stirrups. Composite Structures. 2020;243:112236. doi:10.1016/j.compstruct.2020.112236
- Ferdous W, Manalo A, Khennane A, Kayali O. Geopolymer concrete-filled pultruded composite beams – Concrete mix design and application. Cement and Concrete Composites. 2015;58:1-13. doi:10.1016/j.cemconcomp.2014.12.012
- Noushini A, Castel A, Aldred J, Rawal A. Chloride diffusion resistance and chloride binding capacity of fly ash-based geopolymer concrete. Cement and Concrete Composites. 2020;105:103290. doi:10.1016/j.cemconcomp.2019.04.006
- T.V. Srinivas Murthy, D.A.K.R.; Srinivas Murthy, T.; Kumar Rai, A. Geopolymer Concrete, An Earth Friendly Concrete, Very Promising in the Industry. Int. J. Civ. Eng. Technol. 2014, 5, 113–122.
- Kong DLY, Sanjayan JG. Damage behavior of geopolymer composites exposed to elevated temperatures. Cement and Concrete Composites. 2008;30(10):986-991. doi:10.1016/j.cemconcomp.2008.08.001
- Verma M, Dev N. Sodium hydroxide effect on the mechanical properties of flyash‐slag based geopolymer concrete. Structural Concrete. 2020;22(S1). doi:10.1002/suco.202000068
- Tran TT, Pham TM, Hao H. Experimental and analytical investigation on flexural behaviour of ambient cured geopolymer concrete beams reinforced with steel fibers. Engineering Structures. 2019;200:109707. doi:10.1016/j.engstruct.2019.109707
- Praveen Kumar VV, Naga Prasad, Dey S. Influence of metakaolin on strength and durability characteristics of ground granulated blast furnace slag based geopolymer concrete. Structural Concrete. 2019;21(3):1040-1050. doi:10.1002/suco.201900415
- Nguyen KT, Nguyen QD, Le TA, Shin J, Lee K. Analyzing the compressive strength of green fly ash based geopolymer concrete using experiment and machine learning approaches. Construction and Building Materials. 2020;247:118581. doi:10.1016/j.conbuildmat.2020.118581
- Özcan A, Karakoç MB. The Resistance of Blast Furnace Slag- and Ferrochrome Slag-Based Geopolymer Concrete Against Acid Attack. International Journal of Civil Engineering. 2019;17(10):1571-1583. doi:10.1007/s40999-019-00425-2
- Biondi L, Perry M, Vlachakis C, Wu Z, Hamilton A, McAlorum J. Ambient Cured Fly Ash Geopolymer Coatings for Concrete. Materials. 2019;12(6):923. doi:10.3390/ma12060923
- Sharma U, Gupta N, Bahrami A, Özkılıç YO, Verma M, Berwal P, et al. Behavior of Fibers in Geopolymer Concrete: A Comprehensive Review. Buildings. 2024;14(1):136. doi:10.3390/buildings14010136
- Verma M, Dev N. Effect of SNF-Based Superplasticizer on Physical, Mechanical and Thermal Properties of the Geopolymer Concrete. Silicon. 2021;14(3):965-975. doi:10.1007/s12633-020-00840-4
- Upreti K, Verma M, Agrawal M, Garg J, Kaushik R, Agrawal C, et al. Prediction of Mechanical Strength by Using an Artificial Neural Network and Random Forest Algorithm. Journal of Nanomaterials. 2022;2022(1). doi:10.1155/2022/7791582
- Zhang YS, Sun W, Li JZ. Hydration process of interfacial transition in potassium polysialate (K-PSDS) geopolymer concrete. Magazine of Concrete Research. 2005;57(1):33-38. doi:10.1680/macr.2005.57.1.33
- Kastiukas G, Ruan S, Liang S, Zhou X. Development of precast geopolymer concrete via oven and microwave radiation curing with an environmental assessment. Journal of Cleaner Production. 2020;255:120290. doi:10.1016/j.jclepro.2020.120290
- Çevik A, Alzeebaree R, Humur G, Niş A, Gülşan ME. Effect of nano-silica on the chemical durability and mechanical performance of fly ash based geopolymer concrete. Ceramics International. 2018;44(11):12253-12264. doi:10.1016/j.ceramint.2018.04.009
- Nagalia G, Park Y, Abolmaali A, Aswath P. Compressive Strength and Microstructural Properties of Fly Ash–Based Geopolymer Concrete. Journal of Materials in Civil Engineering. 2016;28(12). doi:10.1061/(asce)mt.1943-5533.0001656
- Zhang H, Li L, Sarker PK, Long T, Shi X, Wang Q, et al. Investigating Various Factors Affecting the Long-Term Compressive Strength of Heat-Cured Fly Ash Geopolymer Concrete and the Use of Orthogonal Experimental Design Method. International Journal of Concrete Structures and Materials. 2019;13(1). doi:10.1186/s40069-019-0375-7
- Al-Majidi MH, Lampropoulos A, Cundy A, Meikle S. Development of geopolymer mortar under ambient temperature for in situ applications. Construction and Building Materials. 2016;120:198-211. doi:10.1016/j.conbuildmat.2016.05.085
- Moradikhou AB, Esparham A, Jamshidi Avanaki M. Physical & mechanical properties of fiber reinforced metakaolin-based geopolymer concrete. Construction and Building Materials. 2020;251:118965. doi:10.1016/j.conbuildmat.2020.118965
- Rangan, B. V; Rangan, B.V.; Cpeng, F.; Rtd, (; Faci, ); Fici, H.; Professor, E. Fly Ash-Based Geopolymer Concrete; Allied Publishers Private Limited, 2010;
- Rajini B, Rao AVN, C.Sashidhar. COST ANALYSIS OF GEOPOLYMER CONCRETE OVER CONVENTIONAL CONCRETE. 2020. doi:10.31224/osf.io/3mxgz
- Elchalakani M, Dong M, Karrech A, Li G, Mohamed Ali MS, Manalo A. Behaviour and design of air-cured GFRP-reinforced geopolymer concrete square columns. Magazine of Concrete Research. 2019;71(19):1006-1024. doi:10.1680/jmacr.17.00534
- Yuan Y, Zhao R, Li R, Wang Y, Cheng Z, Li F, et al. Frost resistance of fiber-reinforced blended slag and Class F fly ash-based geopolymer concrete under the coupling effect of freeze-thaw cycling and axial compressive loading. Construction and Building Materials. 2020;250:118831. doi:10.1016/j.conbuildmat.2020.118831
- Aguirre-Guerrero AM, Robayo-Salazar RA, de Gutiérrez RM. A novel geopolymer application: Coatings to protect reinforced concrete against corrosion. Applied Clay Science. 2017;135:437-446. doi:10.1016/j.clay.2016.10.029
- Nath P, Sarker PK. Flexural strength and elastic modulus of ambient-cured blended low-calcium fly ash geopolymer concrete. Construction and Building Materials. 2017;130:22-31. doi:10.1016/j.conbuildmat.2016.11.034
- Mathew, B.J.; Sudhakar, M.; Natarajan, C. Strength , Economic and Sustainability Characteristics of Coal Ash – GGBS Based Geopolymer Concrete . Int. J. Comput. Eng. Res. 2013, 3, 207–212.