Journal of Polymer & Composites Article Open Access

Mechanical Performance Degradation of Naturally Aged Nitrile Butadiene Rubber in Low Frequency Range...

  1. Syam Prasad Amminen Department of Mechanical Engineering, JNTUK
  2. Ch. Nagaraju Department of Mechanical Engineering, Maturi Venkata Subba Rao (MVSR) Engineering College
  3. D. Linga Raju

Abstract

For good mechanical design, damping is often still an invisible requirement. Nitrile Butadiene Rubber (NBR) has a wide range of applications as a damping and sealing material. To offer the long-term service of NBR, it is important to estimate the degradation of modal properties under complex mechanical and environmental loading. The present work aims to correlate the experimental data with generalized higher-order Maxwell models and curve fitting techniques to find the damping characteristics of NBR in low-frequency ranges with age. Nitrile Butadiene Rubber (NBR) is assumed to be homogeneous and isotropic, and it is allowed to age naturally in the oxidative environment with no load. Mechanical tests are performed to find hardness, true stress-strain behavior, and failure stress of virgin NBR and the naturally aged NBR. Deterioration of damping ability of NBR is studied by Dynamic Mechanical Analysis (DMA) tests to relate the complex properties of naturally aged material at an operating temperature of 40˚C, with virgin material in the frequency domain. The developed curve fitting techniques are well acceptable with experimental data and higher-order maxwell models. Relaxation modulus in shear mode is calculated for virgin and aged NBR. Based on experimental results, it has been observed that the Mechanical properties, such as yield strength, tensile strength, Elastic modulus are deteriorated with natural oxidative aging. Modal properties of NBR namely storage modulus by 52%, loss modulus by 66%, loss factor by 31%, relaxation modulus by 43.9%, and damping coefficient by 31.25%, as well as damping ability has deteriorated with age.

Keywords

References (30)

  1. Peng Q, Zhu Z, Jiang C, Jiang H. Effect of stress relaxation on accelerated physical aging of hydrogenated nitrile butadiene rubber using time-temperature-strain superposition principle. Advanced Industrial and Engineering Polymer Research. 2019;2(2):61-68. doi:10.1016/j.aiepr.2019.03.002
  2. Bendjaouahdou C, Bensaad S. Aging studies of a polypropylene and natural rubber blend. International Journal of Industrial Chemistry. 2018;9(4):345-352. doi:10.1007/s40090-018-0163-2
  3. Feng J, Zhang Q, Tu Z, Tu W, Wan Z, Pan M, et al. Degradation of silicone rubbers with different hardness in various aqueous solutions. Polymer Degradation and Stability. 2014;109:122-128. doi:10.1016/j.polymdegradstab.2014.07.011
  4. Choi SS, Kim JC. Lifetime prediction and thermal aging behaviors of SBR and NBR composites using crosslink density changes. Journal of Industrial and Engineering Chemistry. 2012;18(3):1166-1170. doi:10.1016/j.jiec.2012.01.011
  5. Lyu P, Li W, Ma Y, Cui Y. Effect of ageing on constrained damping structure of viscoelastic material. AIP Conference Proceedings. 2018;2036:030003. doi:10.1063/1.5075656
  6. Ge T, Huang XH, Guo YQ, He ZF, Hu ZW. Investigation of Mechanical and Damping Performances of Cylindrical Viscoelastic Dampers in Wide Frequency Range. Actuators. 2021;10(4):71. doi:10.3390/act10040071
  7. Vašina M, Pöschl M, Zádrapa P. A Study of Significant Factors Affecting Viscoelastic Damping Properties of Polymer Materials. Manufacturing Technology. 2018;18(3):523-529. doi:10.21062/ujep/132.2018/a/1213-2489/mt/18/3/523
  8. R. Lakes, R.S. Lakes, Viscoelastic Materials, Cambridge University Press, 2009.
  9. D.I.G. Jones, Handbook of Viscoelastic Vibration Damping, John Wiley & Sons, 2001.
  10. Ko YS, Forsman WC. Dynamic Mechanical Testing of Viscoelastic Solids in Free and Forced Oscillation: Experiments with a Modified Weissenberg Rheogoniometer. International Journal of Polymeric Materials and Polymeric Biomaterials. 1980;8(1):53-63. doi:10.1080/00914038008077934
  11. Woo CS, Choi SS, Lee SB, Kim HS. Useful Lifetime Prediction of Rubber Components Using Accelerated Testing. IEEE Transactions on Reliability. 2010;59(1):11-17. doi:10.1109/tr.2010.2042103
  12. Y. Qian, H. Xiao, M. Nie, Y. Zhao, Y. Luo, S. Gong, Lifetime Prediction and Aging Behaviors of Nitrile Butadiene Rubber under Operating Environment of Transformer, J. Electr. Eng. Technol. 13 (2018) 918–927. https://doi.org/10.5370/JEET.2018.13.2.918.
  13. Musil B, Johlitz M, Lion A. On the ageing behaviour of NBR: chemomechanical experiments, modelling and simulation of tension set. Continuum Mechanics and Thermodynamics. 2018;32(2):369-385. doi:10.1007/s00161-018-0728-5
  14. Nait Abdelaziz M, Ayoub G, Colin X, Benhassine M, Mouwakeh M. New developments in fracture of rubbers: Predictive tools and influence of thermal aging. International Journal of Solids and Structures. 2019;165:127-136. doi:10.1016/j.ijsolstr.2019.02.001
  15. Liu J, Li X, Xu L, Zhang P. Investigation of aging behavior and mechanism of nitrile-butadiene rubber (NBR) in the accelerated thermal aging environment. Polymer Testing. 2016;54:59-66. doi:10.1016/j.polymertesting.2016.06.010
  16. Q.Y. Tang, W.F. Zhang, Environmental Factors on Aging of Nitrile Butadiene Rubber (NBR) - A Review, Adv. Mater. Res. 1033–1034 (2014) 987–990. https://doi.org/10.4028/ www.scientific.net/AMR.1033-1034.987.
  17. Xiong Y, Chen G, Guo S, Li G. Lifetime prediction of NBR composite sheet in aviation kerosene by using nonlinear curve fitting of ATR-FTIR spectra. Journal of Industrial and Engineering Chemistry. 2013;19(5):1611-1616. doi:10.1016/j.jiec.2013.01.031
  18. Nakagawa T, Toya T, Oyama M. Ozone Resistance of Highly Saturated Nitrile Rubber (HNBR). Journal of Elastomers & Plastics. 1992;24(3):240-261. doi:10.1177/009524439202400307
  19. Zheng W, Zhao X, Li Q, Chan TW, Zhang L, Wu S. Compressive stress relaxation modeling of butadiene rubber under thermo‐oxidative aging. Journal of Applied Polymer Science. 2016;134(12). doi:10.1002/app.44630
  20. Plota A, Masek A. Lifetime Prediction Methods for Degradable Polymeric Materials—A Short Review. Materials. 2020;13(20):4507. doi:10.3390/ma13204507
  21. Review of Accelerated Ageing Methods and Lifetime Prediction Techniques for Polymeric Materials, National Physical Laboratory, 2005.
  22. Ozawa T. A New Method of Analyzing Thermogravimetric Data. Bulletin of the Chemical Society of Japan. 1965;38(11):1881-1886. doi:10.1246/bcsj.38.1881
  23. Hussain M, Yasin S, Memon H, Li Z, Fan X, Akram MA, et al. Rheological and Mechanical Properties of Silica/Nitrile Butadiene Rubber Vulcanizates with Eco-Friendly Ionic Liquid. Polymers. 2020;12(11):2763. doi:10.3390/polym12112763
  24. E.J. Graesser, C.R. Wong, The Relationship of Traditional Damping Measures for Materials with High Damping Capacity., David Taylor Research Center Bethesda MD Ship Materials Engineering DEPT, 1991. https://apps.dtic.mil/sti/citations/ADA235347 (accessed February 15, 2022).
  25. J.D. Ferry, Viscoelastic Properties of Polymers, John Wiley & Sons, 1980.
  26. Williams ML, Blatz PJ, Schapery RA. FUNDAMENTAL STUDIES RELATING TO SYSTEMS ANALYSIS OF SOLID PROPELLANTS. 1961. doi:10.21236/ad0256905
  27. N.W. Tschoegl, The Phenomenological Theory of Linear Viscoelastic Behavior: An Introduction, Springer-Verlag, 1989.
  28. Baumgaertel M, Winter HH. Determination of discrete relaxation and retardation time spectra from dynamic mechanical data. Rheologica Acta. 1989;28(6):511-519. doi:10.1007/bf01332922
  29. Han R, Wu Y, Quan X, Niu K. Effects of crosslinking densities on mechanical properties of nitrile rubber composites in thermal oxidative aging environment. Journal of Applied Polymer Science. 2020;137(36). doi:10.1002/app.49076
  30. C. Tzikang, Determining a Prony Series for a Viscoelastic Material From Time Varying Strain Data, NASA Langley Technical Report Server, 2000.
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