thermal cycling
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Nano-Silica Reinforced Crosslinked Biopolymer–PCM Composites for Improved Thermal Cycling Durability
Abstract: Crosslinked biopolymer–PCM composites reinforced with nano-silica were developed to enhance thermal cycling durability, leakage resistance, and structural stability for advanced thermal energy storage applications. A starch-based biopolymer was chemically crosslinked using citric acid to create a stable polymer network, while paraffin was employed as the phase-change medium and nano-silica (1–4 wt%) served as a multifunctional inorganic reinforcement. FTIR analysis confirmed successful esterification between citric acid and the polymer backbone, indicated …
Published in Journal of Polymer & Composites · Vol. 14, Issue 1, 2026 · pp. 1–10 Read article