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116 articles for “electronic spectra”
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Synthesis and Characterization of Co(II), Ni(II), Cu(II) and Zn(II) Complexes with Schiff Bases Derived from 3-Substituted-4-Amino-5-Mercapto-1,2,4-Triazoles and Ethylvanillin
Abstract: Normal 0 false false false MicrosoftInternetExplorer4 Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4 The synthesis and structural characterization of two novel compounds, 4-(3-ethoxy-4-hydroxybenzylideneamino)-3-methyl-5-mercapto-s-triazole and 3-ethyl-4-(3-ethoxy-4-hydroxybenzylideneamino)-5-mercapto-s-triazole and their Co(II), Ni(II), Cu(II), Zn(II) complexes in 1:1 and 1:2 molar ratio have been described with the help of different techniques like IR, 1H-NMR, magnetic moment, electronic spectra, thermal and XRD studies. The Schiff bases are coordinated to metal ion through S …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 4, Issue 2, 2013 · pp. 19–25 Read article
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Effect of Time Exposure on Human Blood by Laser Flash Photolysis
Abstract: Diffuse reflectance laser flash photolysis has been used in blood sample to measure transient triplet spectra of free radical or reactive oxygen species (OH, O2, H2O2) generated in free cell systems was investigated using laser flash photolysis and electronic absorption spectra. In all cases, triplet–triplet absorption spectra with the application of this technique to studies concentration of normal human blood sample. The concentration of normal human blood sample is reduced …
Published in Journal of Materials & Metallurgical Engineering · Vol. 10, Issue 2, 2020 · pp. 15–20 Read article
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Synthesis, Characterization and Biological Activity: Co(II), Ni(II), Cu(II) and Zn(II) Complexes of Schiff Bases Derived from 4-Cyanobenzaldehye and 4-Amino-5-Mercapto-3-Methyl/Ethyl-1,2,4-triazoles
Abstract: Co(II), Ni(II), Cu(II) and Zn(II) complexes of bidentate Schiff bases derived from the condensation of 4-amino-5-mercapto-3-methyl-1,2,4-triazole and 4-amino-3-ethyl-5-mercapto-1,2,4-triazole with 4-cyanobenzaldehyde have been synthesized. The synthesized Schiff bases and their metal complexes were then characterized by elemental analysis, spectroscopic methods (IR, NMR, electronic spectra), magnetic moment measurement and thermogravimetric techniques. The electronic spectra and magnetic moment studies suggest octahedral geometry for Co(II), Ni(II) and Zn(II) complexes and square planar geometry for …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 2, 2014 · pp. 27–36 Read article
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Synthesis, Structural Characterization and Biological Studies of Schiff Base Complexes Bearing Indole Moiety
Abstract: Schiff base complexes of N2O2 type derived from indole-3-carboxaldehyde(ind) and amino acids such as glycine(gly), L-valine(val), and L-tryptophan(try) with Cu(II), Ni(II), Zn(II), Co(II) and Mn(II) were synthesized and characterized by physical and analytical techniques. The complexes are of non-electrolytic nature having 1:2 (metal:ligand) ratio. The geometry of the complexes was predicted with the combined data obtained from electronic spectral and magnetic susceptibility measurements. The mode of coordination of the Schiff …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 4, Issue 1, 2013 · pp. 31–42 Read article
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Synthesis And Spectral Of Some Biologically Active Chromium (III) Complexes With Macrocyclic Ligands
Abstract: A large number of modern techniques have been developed for the synthesis of macrocyclic complexes. Forty chromium complexes of the type [CrX2.L1-20]X; (Where X=Cl or NO3; L=macrocyclic ligands) derived from condensation of 2,3-butanedione or 1, 2-diphenyl-ethane 1,2-dione (2mmol) with different aliphatic diamines (2mmol) have been synthesized and characterized by elemental analysis, molar conductivity, electronic spectra, IR spectra, magnetic moment and X-ray photoelectron data (i.e. XPS data). An octahedral geometry is …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 14, Issue 3, 2023 · pp. 19–26 Read article
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Spectral, thermal, electrochemical and biological studies of Co(II), Ni(II), Cu(II) and Zn(II) complexes derived from 4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine.
Abstract: The Schiff base4-(3-bromo-4-hydroxy-5-methoxybenzylideneamino)-3-mercapto-6-methyl-5-oxo-1,2,4-triazine and its Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized and characterized by IR, NMR, electronic, ESR, fluorescence, thermal, magnetic moment and electrochemical studies. IR and thermal data support the presence of coordinated water in the metal complexes. The electronic spectral and magnetic moment measurements indicate octahedral geometry for Co(II), Ni(II) and Zn(II) complexes and square planar for Cu(II) complexes. Biological studies of the ligand and …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 1, 2014 · pp. 6–16 Read article
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Synthesis of Zeolite Y-Encapsulated Copper(II) Complexes with Aminobenzonitriles and Carbonitriles by Flexible Ligand Method
Abstract: Zeolite Y encapsulated copper(II) sulphate complexes with 2-, 3- and 4- aminobenzonitrile and carbonitrile have been prepared by flexible ligand synthesis method. Complexes are characterized by magnetic susceptibility, infra-red and electronic spectral techniques. The data clearly suggests the presence of metal complexes in zeolite matrix.
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 41–52 Read article
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Synthesis and Spectroscopic Studies of 12-Membered Macrocyclic Transition Metal Complexes with Tetradentate Ligand
Abstract: Tetra-aza macrocyclic transition metals complexes of type: [M(C12H4N8)X2]; where, M = Co (II), Ni(II), Cu(II), Zn(II); X= Cl-1 , NO3 - , CH3COOhave been synthesized and characterized. On the basis of conductance data; elemental analyses, the character of the complexes have been suggest and it was found that all the complexes have 1:2:2 stoichiometry and are nonelectrolytic in nature. Tentative geometry of the new synthesized macrocyclic complexes had been proposed …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 2, 2016 · pp. 9–19 Read article
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Effect of Radiation Dose, Dose Rate and Annealing Temperature on Edible Potato Starch by Spectroscopic Methods
Abstract: Potato starch (PS) is a favorite food choice in different forms. During its storage and applications the PS is exposed to different radiations. In the present study the authors attempt to compare radiation effects (gamma and Electron beam of same radiation dose) in PS by Electron spin resonance (ESR) and Fourier transform infrared (FTIR) methods. ESR spectra of gamma irradiated PS appeared to have resolved shapes than the electron beam …
Published in Journal of Polymer & Composites · Vol. 13, Issue 1, 2025 · pp. 198–209 Read article
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Comparative study of the Antibacterial Properties of Modified Textile Materials with Different Metal Nanoparticles
Abstract: A number of metal particles have proven antibacterial properties. In this study, a comparative analysis was made of two types of metal particles: zinc oxide and titanium oxide nanoparticles respectively, which were deposited on cellulose material and were fixed by means of a cross-linked gelatin hydrogel. Three methods were applied under different reaction conditions for obtaining the biocomposite materials. The biomaterials were investigated by means of scanning electron microscopy, transmittance …
Published in Journal of Polymer & Composites · Vol. 12, Issue 3, 2024 · pp. 92–101 Read article
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Harmonic Analysis of 6-Pulse Diode Bridge Rectifier Circuits
Abstract: This paper analyzes the steady-state harmonic performance of the six-diode, 3-phase rectifier bridge circuits. A procedure for determining the frequency spectra of the different voltages and currents within the bridge circuit, resulting from a 60-Hz 3-phase supply, is presented. The effect of the smoothing shunt-capacitor is also demonstrated. Based on a Mathematica code, the paper presents the results of a comprehensive list of case studies. The procedure can handle unsymmetrical …
Published in Journal of Power Electronics and Power Systems · Vol. 10, Issue 2, 2020 · pp. 1–10 Read article
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Harmonic Analysis of Full-Wave Diode Bridge Rectifier Circuits
Abstract: This paper analyzes the steady-state harmonic performance of four-diode, single-phase full-wave rectifier bridge circuits. The frequency spectra of the source and load currents are presented. The effect of the load resistance, the source inductance, the smoothing shunt- capacitor as well as the waveform of the supply voltage is illustrated. The approach can also handle cases involving non-sinusoidal sources and non-linear loads. Based on a Mathematica code, the paper presents the …
Published in Trends in Electrical Engineering · Vol. 10, Issue 1, 2020 · pp. 7–21 Read article
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Cerium Admixture Effect on the Surface Magnetic Properties of Ceramics Based on Yttrium Oxide
Abstract: The influence of 10 mol.% cerium oxide dopant on phase transformations, morphology, and surface magnetic properties (magnetic structure) of polycrystalline ceramics obtained in the CeO2–Y2O3 system, depending on the conditions of its heat treatment, was studied. Using the X-ray phase analysis method, it was established that heat treatment at 120°C does not lead to the interaction of the initial components, and when the oxide mixture is fired at a temperature …
Published in Research & Reviews : Journal of Physics · Vol. 11, Issue 2, 2022 · pp. 9–19 Read article
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A Mini-Review on Spectral (UV Visible, FT-IR, 1H NMR, GC-MS) Analysis of Various Shaded Dried Leaves Extracts
Abstract: To collect the different types of leaves in various places, wash collected leaves with distilled water and dried these leaves in various processes like under shade dry for 15 days, place oven (45 oC) for 1 hour. Grind well using the above-dried leaves, so these leaves are changed to powder form. Utilize these shaded dried leaves powder, to prepare extract with solvents like methanol, ethanol, hexane, carbon tetrachloride, petroleum ether, …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 13, Issue 1, 2022 · pp. 1–8 Read article
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Absorption Spectra Calculation and Charge Distribution Analysis of para-azoxyanisole: A Semiempirical Study
Abstract: AbstractSemiempirical study of electronic structure of para-azoxyanisole (PAA) has been carried out. In order to obtain more information on the reactivity of PAA molecule towards nucleophile and electrophile, semiempirical (CNDO/S, and INDO/S) based calculations have been performed to evaluate the negative and positive charge distribution. Further, CNDO/S + CI and INDO/S + CI methods have been employed to calculate and analyze the absorbance spectral measurements in UV-visible range, and charge …
Published in Research & Reviews : Journal of Physics · Vol. 6, Issue 1, 2017 · pp. 5–11 Read article
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Synthesis and Characterization of Mn Doped ZnO Nanoparticles by Chemical Precipitation Method
Abstract: Normal 0 false false false EN-IN X-NONE X-NONE Nanosized Mn doped ZnO semiconductor (where Mn 0.5%–2.5%) has been synthesized via a chemical precipitation method using zinc acetate hydrate, MnCl2 in alcoholic medium and utilizing polyvinyl pyrolidone (PVP) as capping agent. A differential thermal analysis (DTA) and a thermo-gravimetric analysis (TGA) where used determine the thermal properties of ZnO:Mn. The structural characteristics were examined using X-ray diffraction (XRD).scanning electron microscopy (SEM) …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 2, 2012 · pp. 45–55 Read article
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Synthesis by Sol–Gel Method and Characterization of CaAlO: Mn, Dy Nanoparticles
Abstract: Dy and Mn doped Calcium Aluminate nanoparticles were synthesized by using Sol-gel method. Heat treated material was characterized by X-ray diffraction(XRD), optical study of photoluminescence (PL) emission spectra, morphological study of scanning electron microscopy (SEM) combined with X-ray analysis. The Dy and Mn doped phosphor exhibits emission at the excitation of the material with 380 nm wavelength generates a strong emission at 480 nm. Besides this, subsidiary maxima at 417, …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 4, Issue 2, 2014 · pp. 23–27 Read article
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A Simple Sol–Gel Route for the Synthesis and Characterization of Tm-Doped CaAl2O4 Nanophosphor
Abstract: Calcium Aluminate nanophosphor doped with Thulium (CaAl2O4: Tm) was synthesized by simple sol–gel route. The obtained nanophosphor was characterized by X-ray diffraction technique (XRD). The surface morphology was determined by scanning electron microscopy (SEM). Also photoluminescence spectra (PL), and thermogravimetric analysis/differential scanning calorimetry (TGA/DSC) characterization were done. The XRD revealed the formation of monoclinic structure and the particle size was determined by Scherrer formula. It showed that the particles were …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 6, Issue 1, 2016 · pp. 6–10 Read article
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Application of Bloch Analysis to Evaluate Activation of Energy of Irradiated Polyacrylonitrile
Abstract: AbstractPolyacrylonitile is one of the important polymers of technical and scientific importance. During its usage, the polymer is exposed to different types of radiations, limiting its use. In order to investigate the processes involved in radiation effect in PAN, various efforts have been made. In this context, the authors have also made an attempt to investigate radiation induced process in PAN by electron spin resonance (ESR) technique. ESR spectra of …
Published in Journal of Polymer & Composites · Vol. 4, Issue 2, 2016 · pp. 25–28 Read article
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Electron Beam and Gamma Radiation Dose Dependency on the Degradation Products of Polytetrafluoroethylene (PTFE)
Abstract: AbstractGamma radiation induced degradation phenomena of polytetrafluoroethylene (PTFE) in the form of granules has been studied. The Electron Spin Resonance (ESR) technique was used to study radical generation and behavior under different conditions. The ESR spectra of PTFE irradiated at low or very high doses of irradiation were doublets, characteristic of peroxy radicals. Similarly spectra at different temperatures are also doublets. In order to study nature of free radicals, the …
Published in Research & Reviews : Journal of Physics · Vol. 8, Issue 1, 2019 · pp. 104–114 Read article