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6 articles for “ESR spectrum”
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Radiation Effects in Acrylonitrile (AN) Ethyl Methacrylate Copolymer by Spectroscopic and Thermal Methods
Abstract: Gamma irradiation effects in acrylonitrile (AN) ethyl methacrylate (EMA) (AE) copolymer have been investigated by electron spin resonance (ESR), Fourier transform infrared (FTIR) and differential scanning calorimetric (DSC) techniques. Temperature and radiation dose dependent effects have been investigated by recording ESR spectra under different conditions. Computer simulation techniques are used to analyze ESR spectra to identify of free radical produced on irradiation of copolymer. As such, ESR spectrum of irradiated …
Published in Journal of Polymer & Composites · Vol. 5, Issue 3, 2017 · pp. 22–29 Read article
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Dosimetric Aspects of Poly(ethylene- g - maleic anhydride)
Abstract: Electron spin resonance (ESR) spectroscopy is considered to be finger print technique to identify chemical structures of irradiated polymers. To prove this, ESR spectra of unirradiated and irradiated maleic anhydride grafted poly ethylene (MANPE)are recorded under different conditions. The ESR spectra show multiplehyperfine lines with latent structure corresponding to macro radicals . Radiation dose dependency on chemical structure of MANPE has been investigated by recording ESR spectra at various radiation …
Published in Journal of Polymer & Composites · Vol. 7, Issue 3, 2019 · pp. 20–23 Read article
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COMPOSITION, RADIATION DOSE AND TEMPERATURE DEPENDENT DEGRADATION STUDIES OF POLYAMIDE 6 HOMOPOLYMER AND COPOLYMERS
Abstract: Composition radiation dose temperature dependency on free radicals generated in PA6, PA6/ PA12 copolymer, has been investigated by electron spin resonance (ESR) and FTIR techniques. ESR spectra of -irradiated PA6 has shown complex shaped and number of hyperfine lines is observed to be in between 6-10. This complex spectrum is assigned to macro-radicals of the type ~CH2CHCH2~, which in principle has to give a ten line ESR spectrum. However, due …
Published in Journal of Catalyst & Catalysis · Vol. 5, Issue 1, 2018 · pp. 25–37 Read article
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Modification of Acrylonitrile-Methylacrylate Copolymer by Gamma Irradiation
Abstract: AbstractRadiative degradation of acrylonitrile-methylacrylate (AM) copolymer has been investigated by electron spin resonance (ESR) and infrared (IR) spectroscopy. The ESR spectrum observed for AM copolymer irradiated to a dose of 12 Mrad is a triplet with an intensity ratio of 1:3:1. The ESR spectrum is simulated by total-curve-fitting method and component spectra are generated. Magnetic parameters of component spectra are evaluated. Component triplet spectrum with magnetic parameters ni=3, mi=1 is …
Published in Journal of Polymer & Composites · Vol. 3, Issue 3, 2015 · pp. 16–19 Read article
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Characterization and Gamma Irradiated MA-EMA Copolymer by ESR and FTIR Techniques
Abstract: AbstractGamma irradiation effect of methacrylamide-ethyl methacrylate (MA-EMA) copolymer has been investigated by electron spin resonance (ESR) and Fourier Transform infrared (FTIR) spectroscopic techniques. The ESR spectrum observed for gamma irradiated MA-EMA copolymer has shown resolved hyperfine (hf) pattern at lower temperatures (77K) while at higher temperatures the spectrum is appeared to be broadened. Fourier Transform Infrared spectra of pure and gamma irradiated MA-EMA copolymer have been recorded for the copolymer …
Published in Journal of Polymer & Composites · Vol. 4, Issue 3, 2016 · pp. 40–44 Read article
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Application of Bloch Analysis to Evaluate Activation of Energy of Irradiated Polyacrylonitrile
Abstract: AbstractPolyacrylonitile is one of the important polymers of technical and scientific importance. During its usage, the polymer is exposed to different types of radiations, limiting its use. In order to investigate the processes involved in radiation effect in PAN, various efforts have been made. In this context, the authors have also made an attempt to investigate radiation induced process in PAN by electron spin resonance (ESR) technique. ESR spectra of …
Published in Journal of Polymer & Composites · Vol. 4, Issue 2, 2016 · pp. 25–28 Read article