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50 articles for “Copolymer”
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A Study on the Synthesis and Characterization of Silver Metal Nano Particles with Acrylic Acid– Acrylamide (Aa) Copolymer as Mediating Agent
Abstract: Silver metal nano-particles (MNP) have been synthesized by chemical methods with acrylic acid- acryl amide (AA) copolymer as mediating agent. Formation and interaction of silver metal nano- particles with AA copolymer has been confirmed by ultraviolet–visible (UV-VIS), Fourier Transform Infrared (FTIR) techniques. Thermal and morphological properties of the composite have been studied by Differential Scanning Calorimetry (DSC) and Scanning Electron Microscope (SEM) techniques. Change in intensity together with shift of …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 6, Issue 3, 2016 · pp. 1–4 Read article
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Radiation Effects in Acrylonitrile (AN) Ethyl Methacrylate Copolymer by Spectroscopic and Thermal Methods
Abstract: Gamma irradiation effects in acrylonitrile (AN) ethyl methacrylate (EMA) (AE) copolymer have been investigated by electron spin resonance (ESR), Fourier transform infrared (FTIR) and differential scanning calorimetric (DSC) techniques. Temperature and radiation dose dependent effects have been investigated by recording ESR spectra under different conditions. Computer simulation techniques are used to analyze ESR spectra to identify of free radical produced on irradiation of copolymer. As such, ESR spectrum of irradiated …
Published in Journal of Polymer & Composites · Vol. 5, Issue 3, 2017 · pp. 22–29 Read article
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Design and Synthesis of Functionalized Copolymers for Enhanced Interfacial Compatibility in Polymer Matrix Composites
Abstract: Interfacial adhesion between the polymer matrix reinforcing phase affects significantly the mechanical and thermal behavior of polymer composites. The study reports on the design and synthesis of functionalized copolymers in the efforts to establish interfacial compatibility based on chemical design. The reinforcements were functionalized doping polar functional groups such as glycidyl methacrylate and maleic anhydride during free-radical copolymerization to form copolymerizing reactive sites that interacted with the reinforcement surfaces. Confirmation …
Published in Journal of Polymer & Composites · Vol. 14, Issue 2, 2026 · pp. 1404–1418 Read article
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Studies on the Self-Assembly of Steroids and DNA Mediated by Naphthalene-Based Amphiphilic Block Copolymer
Abstract: Amphiphilic block copolymers have attracted considerable interest in pharmaceutical and biomedical applications, including controlled drug release, gene delivery, and biomolecular sensing. In this study, fluorescent amphiphilic block copolymers were designed to facilitate interactions with biological molecules, such as DNA and antiviral agents, enabling their behavior to be monitored through fluorescence spectroscopy. Two novel block copolymers, poly(methyl methacrylate)-b-poly(dimethylaminoethyl methacrylate-co-naphthyl methacrylate) [PMMA-b-P(DMAEMA-co-NMA)] and poly(styrene)-b-poly(tert-butyl acrylate-co-naphthyl methacrylate) [PS-b-P(t-BA-co-NMA)], were synthesized successfully via atom …
Published in Journal of Polymer & Composites · Vol. 14, Issue 5, 2026 · pp. 183–196 Read article
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Spectroscopic, Thermal and Morphological Properties of Pa6 Copolymers
Abstract: Spectroscopic, thermal and morphological properties of PA6/PA12 copolymers have been reported in the present study. FTIR studies indicate the chemical interaction occurring between PA6 and PA12 homopolymers. Thermal properties of copolymers have been investigated by DTA technique. Among the PA6 copolymer, hydrolyzed PA6 has more Tg and Tm then the copolymer. Thermal degradation of copolymer is studied by TGA and DTG technique. The studies suggest that hydrolyzed PA6 has more …
Published in Research & Reviews : Journal of Physics · Vol. 7, Issue 3, 2018 · pp. 56–62 Read article
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Characterization and Gamma Irradiated MA-EMA Copolymer by ESR and FTIR Techniques
Abstract: AbstractGamma irradiation effect of methacrylamide-ethyl methacrylate (MA-EMA) copolymer has been investigated by electron spin resonance (ESR) and Fourier Transform infrared (FTIR) spectroscopic techniques. The ESR spectrum observed for gamma irradiated MA-EMA copolymer has shown resolved hyperfine (hf) pattern at lower temperatures (77K) while at higher temperatures the spectrum is appeared to be broadened. Fourier Transform Infrared spectra of pure and gamma irradiated MA-EMA copolymer have been recorded for the copolymer …
Published in Journal of Polymer & Composites · Vol. 4, Issue 3, 2016 · pp. 40–44 Read article
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Synthesis and Characterization of Emulsion Paint Binder from a Copolymer Composite of Dimethylol Urea/Polystyrene
Abstract: AbstractIn our desire to reduce formaldehyde emission from urea formaldehyde resin (UF), dimethylol urea (DMU) was synthesized. Liquid polystyrene (PS) obtained from waste PS material was copolymerized by blending with the DMU at varying concentrations (10–70%). Infrared spectra infers a reactive blending between DMU and PS, while some physical property tests carried out reveals reduction in moisture uptake, rigidity and further reduction in formaldehyde emission among the favorable changes in …
Published in Journal of Polymer & Composites · Vol. 3, Issue 2, 2015 · pp. 11–21 Read article
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Polysaccharide based Graft Copolymers and their Applications as Flocculants for Drilling Fluid Wastes
Abstract: Pure water is essential for the survival of living beings. It is used for human consumption, agricultural and industrial activities. During oil and gas well drillinglarge amount of drilling fluid are used. These drilling fluids are mainly water based bentonite solutions which plays a major role in keeping safe and efficient oil and gas well drilling. After their prolonged use, these drilling fluid wastes needs to be disposed of in …
Published in Journal of Petroleum Engineering & Technology · Vol. 8, Issue 2, 2018 · pp. 9–21 Read article
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A Study on Radiation Effects in Acrylonitrile-AMPS Copolymer
Abstract: Radiation behavior of Acrylonitrile AMPS copolymer has been investigated by Electron Spin Resonance (ESR), Fourier Transform Infrared (FTIR) techniques. Temperature dependent ESR studies indicate that free radicals responsible for irradiated copolymer decay at around 100°C. Presence of macro-radicals and polyene radicals is detected. FTIR spectra of copolymer of unirradiated and irradiated are compared and chemical groups influenced by gamma irradiation are identified. The studies suggest that chain cleavage occur either …
Published in Research & Reviews : Journal of Physics · Vol. 7, Issue 2, 2018 · pp. 62–71 Read article
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COMPOSITION, RADIATION DOSE AND TEMPERATURE DEPENDENT DEGRADATION STUDIES OF POLYAMIDE 6 HOMOPOLYMER AND COPOLYMERS
Abstract: Composition radiation dose temperature dependency on free radicals generated in PA6, PA6/ PA12 copolymer, has been investigated by electron spin resonance (ESR) and FTIR techniques. ESR spectra of -irradiated PA6 has shown complex shaped and number of hyperfine lines is observed to be in between 6-10. This complex spectrum is assigned to macro-radicals of the type ~CH2CHCH2~, which in principle has to give a ten line ESR spectrum. However, due …
Published in Journal of Catalyst & Catalysis · Vol. 5, Issue 1, 2018 · pp. 25–37 Read article
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Modification of Acrylonitrile-Methylacrylate Copolymer by Gamma Irradiation
Abstract: AbstractRadiative degradation of acrylonitrile-methylacrylate (AM) copolymer has been investigated by electron spin resonance (ESR) and infrared (IR) spectroscopy. The ESR spectrum observed for AM copolymer irradiated to a dose of 12 Mrad is a triplet with an intensity ratio of 1:3:1. The ESR spectrum is simulated by total-curve-fitting method and component spectra are generated. Magnetic parameters of component spectra are evaluated. Component triplet spectrum with magnetic parameters ni=3, mi=1 is …
Published in Journal of Polymer & Composites · Vol. 3, Issue 3, 2015 · pp. 16–19 Read article
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Synthesis, Characterization and Drug Delivery Application of Poly (Acid Fuchsin) Based Triblock Copolymer
Abstract: Synthesis, characterization and its drug delivery application of Poly (acid fuchsin) (PAF) was done under inert atmosphere. The (M0/I0) was maintained at 100. In order to increase the molecular weight and processability, it was block copolymerized with ε-caprolactone (CL) and tetrahydrofuran (THF) separately. The conductivity value of PAF was found to be decreased after the chemical conjugation with poly(ε-caprolctone) (PCL) and poly(tetrahydrofuran) (PTHF) blocks. Thus obtained triblock copolymer was subjected …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 2, 2016 · pp. 33–43 Read article
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Free Radical Copolymerization of N-(4-chloro-2-methyl phenyl) Maleimide with Vinyl Monomers and Characterization of Polymers
Abstract: The free radical copolymerization of N-(4-chloro-2-methyl phenyl) maleimide (CMPM) with ethyl acrylate, methyl acrylate and vinyl acetate in THF at 65ºC using free radical initiator was described. The physical characteristics like solubility, intrinsic viscosity and molecular weight were determined and discuss the effect of vinyl monomer in properties of polymers. The structure was ascertained by spectral analysis. The thermal stability of copolymers was evaluated by TGA. Keywords: N-(4-chloro-2-methyl phenyl) maleimide, …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 2, 2012 · pp. 1–8 Read article
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Synthesis, Characterization and Drug delivery Application of Poly (Safranine) based triblock copolymer
Abstract: Synthesis, characterization and humidity sensor application of poly(safranin) (PSaf) was carried out under inert atmosphere. The monomer to initiator ratio [M0/I0] was maintained accurately at 100. In order to improve the molecular weight and processability it was block copolymerized with bio-compatible and bio-degradable ε-caprolactone (CL) and water-soluble tetrahydrofuran (THF) separately. Thus, the derived triblock copolymer was subjected to humidity sensor application and the results are viewed in broad approach and …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 9, Issue 2, 2018 · pp. 1–7 Read article
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A Study of Hyperfine Interactions of Peroxy Radicals in Irradiated PE Copolymer at Low Temperatures
Abstract: Hyperfine interactions occurring around the magnetic environment of peroxy radical are investigated by electron spin resonance (ESR) technique. For this purpose, ESR spectra are recorded in the temperature range of 77 to 300 K. ESR spectra at 77 K possess some hyperfine structure together with peroxy doublet; while at high temperatures only peroxy doublet is observed. Hyperfine parameters like g-values, peak to peak separation, spread are calculated and their temperature …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 8, Issue 2, 2017 · pp. 13–19 Read article
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Synthesis, Characterization and Applications of Poly (2-Methyl Aniline-co-2-Chloro Aniline) and Poly (2-Methyl Aniline-co-2-Chloro Aniline)-Nanocomposite-CuO
Abstract: The copolymer and its composite, poly (2-methyl aniline-co-2-chloro aniline) and poly (2-methyl aniline-co-2-chloro aniline)-nanocomposite-CuO respectively were synthesized by chemical oxidative polymerization method using ammonium persulphate as oxidant, sodium lauryl sulphate as surfactant and HCl as dopant. The synthesized copolymer and composite were characterized by FTIR, UV-Visible and 1H NMR spectroscopy. The thermal stability was determined by TGA/DTA. The copolymer and copolymer nanocomposite with CuO were found to be thermally more …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 3, 2016 · pp. 35–45 Read article
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Chemical Synthesis, Spectral Characterization and Electrical Conductivity Behavior of Poly(2-Methoxyaniline-Co-2-Chloroaniline) and its CuO Nanocomposite and Polypropylene Glycol Blend
Abstract: AbstractCopolymerization of 2-chloro aniline and 2-methoxy aniline was achieved chemically by oxidative polymerization technique using ammonium persulphate as the oxidizing agent in acidic medium in the presence of sodium lauryl sulphate, an anionic surfactant. Copolymerization was also carried out in the absence of the surfactant to study the effect of surfactant on the thermal stability and electrical conductivity. The copolymer composite with CuO nano particles and blend with poly propylene …
Published in Journal of Polymer & Composites · Vol. 6, Issue 3, 2018 · pp. 1–13 Read article
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Polymer Modifications (Grafting): Approach to Enhance Versatility of Natural/Renewable Polymeric Materials
Abstract: Graft copolymers are branched copolymers containing a long chain of one monomer called preformed or backbone polymer and branches/grafts of long sequences of usually another monomer. A number of monomeric units can be grafted on the biopolymeric backbone by free radical graft copolymerization reaction using chemical free radical initiator to produce reactive sites on the backbone of biopolymer. The chemical combination of natural and synthetic polymers yields new materials which …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 8, Issue 3, 2017 · pp. 24–32 Read article
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Engineered Polymer Composites for Non-Surgical Lip Posture Correction in Facial Paralysis
Abstract: Facial paralysis presents significant functional and aesthetic challenges, particularly through lip posture deficits such as drooping and drooling, often inadequately addressed by traditional surgical or drug-based interventions, especially in debilitated patients. This study explores the application of engineered polymer composites in a novel, non-surgical lip posture corrector designed to statically suspend and correct lip position without requiring surgical or dental support. The device utilizes a precisely formulated blend of polymethylmethacrylate …
Published in Journal of Polymer & Composites · Vol. 13, Issue 5, 2025 Read article
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Polymer Chemistry of Ion-Selective Membranes and Hydrogels for Clinical Sodium Sensing: Advances and Perspectives
Abstract: Accurate and timely monitoring of serum sodium levels is critical in diagnosing and managing hyponatremia, a common and potentially life-threatening electrolyte disorder. Recent advances in polymer chemistry have driven the development of ion-selective membranes and hydrogels tailored for clinical sodium sensing, bridging the gap between material science and biomedical diagnostics. This review critically examines the design and synthesis of polymeric materials—focusing on block copolymers, conductive polymers, and stimuli-responsive hydrogels—used to …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 895–901 Read article