Search
200 articles for “Catalysts”
-
Synthesis and Immobilization of N-doped Titanium Dioxide for Degradation of Amaranth Dye under Visible Light Irradiation from Light Emitting Diodes
Abstract: Titanium dioxide photocatalysis has a great potential as green and sustainable technology to treat pollutants present in water. In the present study, N-TiO2 (nitrogen doped titanium dioxide)photocatalyst was prepared by wet method using titanium tetra iso-propoxide and NH3. The calcination of the prepared photocatalyst was performed at different temperatures. The prepared catalyst was characterized by DRS, FE SEM and TEM. The N-TiO2 was immobilized on the surface of the quartz …
Published in Emerging Trends in Chemical Engineering · Vol. 3, Issue 2, 2016 · pp. 11–17 Read article
-
Optimization of Process Parameters for Isopropylation of Toluene over Modified Zeolite using Response Surface Methodology
Abstract: Vapor-phase isopropylation of toluene with isopropanol has been investigated in a fixed-bed flow reactor under atmospheric pressure using N2 carrier gas over Cerium modified 13X zeolite catalyst. The main product of this alkylation reaction was p-cymene followed by meta-isomer, while ortho-cymene was negligibly formed. Response surface methodology was used to study the combined effects of temperature, reactant molar ratio and space time on the conversion of toluene and selectivity of …
Published in Emerging Trends in Chemical Engineering · Vol. 1, Issue 1, 2014 · pp. 22–30 Read article
-
Design of a Plant for the Production of Ammonia and Urea Using Aspen HYSYS
Abstract: The design of a plant for the production of 1800 MT/Day of ammonia and 1400 MT/Day of urea using aspen HYSYS was carried out in this work. Ammonia is produced through the Haber-Bosch process, where hydrogen and nitrogen react in the presence of a catalyst producing mixture containing ammonia while urea is produced by the reaction between ammonia and carbon IV oxide. In this work, aspen HYSYS, chemical engineering design …
Published in Emerging Trends in Chemical Engineering · Vol. 9, Issue 1, 2022 · pp. 29–44 Read article
-
Experimental Investigation on 4-Stroke Diesel Engine Using Waste Cooking Oil Biodiesel Fuel
Abstract: Due to using of fossil fuels, the world today is faced with serious environmental pollution. However, these fuels are limited and depleting day by day as the consumption is increasing very rapidly. Hence, it is necessary to find out a clean alternative fuel produced from renewable sources. Biodiesel production and applications are gaining popularity in recent times due to diminishing petroleum reserves and detrimental environmental impacts. Edible and non-edible oils …
Published in Journal of Automobile Engineering and Applications · Vol. 2, Issue 2, 2015 · pp. 19–28 Read article
-
The Rheological Effect of SiO2 Nanoparticles Additives for NBR/CR Blends
Abstract: The rheological alteration of NBR/CR after adding various nano-quantities of silicon oxide (0–50) wt.% was studied. The rheological properties that were tested are viscosity, scorch time, cure time and max torque. Oscillating disk rheometer was used for measuring the above properties. The experimental results have shown that the silicon oxide additives have a good effect on viscosity and max torque during vulcanization, but at the same time the scorch and …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 1–4 Read article
-
Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
-
Removal of AB 10B from Water by Copper Oxide Nano- Particles through Adsorption: A Kinetics and Thermodynamic Study
Abstract: Copper oxide nanoparticle was synthesized by a simple method. Consequently, adsorbent was characterized by using FTIR, XRD, and SEM techniques. The study of optimized parameter contains pH, initial dye concentration, adsorbent dose and contact time. Langmuir, Freundlich and Tempkin models were pragmatic for evaluating adsorption equilibrium data of AB 10B as the adsorbent but experiment show the Langmuir model is best for it. The adsorption kinetic model study was done …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 37–48 Read article
-
Thermal Adsorption Processing of Hydrocarbon Residues
Abstract: The raw materials of secondary catalytic processes must be pre-refined. Among these refining processes are the deasphalting and demetallization including their thermo-adsorption (or thermo-contact adsorption) variety. In oil processing, four main processes of thermo-adsorption refining of hydrocarbon residues are used—Asphalt Residual Treating- residues deasphaltizing (ART), Discriminatory Destructive Distillation (3D), developed in the US; Adsorption-Contact Treatment (ACT) and Express Thermo-Contact Cracking (ETCC), developed in Russia. ART and ACT are processes with …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 1, 2017 · pp. 6–10 Read article
-
Review on Design and Experiment Analysis of Two Cell Stack Proton Exchange Membrane Fuel Cell
Abstract: Design and experimental analysis of two cell stack PEM fuel cell with curvilinear flow field plate is done for doing comparison with single cell PEM fuel cell with serpentine flow field pattern to see the changes in output based on design of flow field and by increasing the active area. Following review is specially done on two cell stack PEM fuel cell in which the active area is 25 cm2; …
Published in Journal of Catalyst & Catalysis · Vol. 3, Issue 1, 2016 · pp. 15–24 Read article
-
Materials for Catalysis: Connecting Academia to Industry
Abstract: This article emphasizes the importance of catalysis technology and catalysts particularly in Indian perspective. The growth of the catalysis technology used in the existing industries in India is enormous and also the catalysis research in Indian academia is significant. However, in pedagogical teaching catalysis is always being neglected in the chemistry syllabus in this country. A conclusion has been drawn addressing the importance of teaching catalysis to the undergraduates and …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 1–3 Read article
-
Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium
Abstract: The kinetics of ruthenium(III) catalyzed degradative oxidation of methylparaben by the copper complex, diperiodatocuprate(III) in alkaline medium is studied at 25ºC and at a ionic strength of 8.0 × 10−2 mol dm−3. In the presence of catalyst ruthenium(III), the reaction between methylparaben and diperiodatocuprate(III) in aqueous alkaline medium exhibits 1:1 stoichiometry. The oxidation products were identified by UV-visible, GC-MS and IR spectroscopy. The reaction exhibited unit order in case of …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 4–17 Read article
-
Mechanistic and Catalytic Behavior of Os(VIII) for the Chlorpheniramine Maleate and Bromamine-B Redox System: A Kinetics Based Approach
Abstract: Chlorpheniramine maleate (CPM) is an important antihistamine agent. To the best of our knowledge there is no report in the literature about the oxidation of CPM with halogen + 1 oxidant from the stand point of its kinetics and mechanistic chemistry. Hence, a systematic kinetics and mechanistic study on the oxidation of CPM with bromamine-B (BAB) in the presence of NaOH and Os(VIII) catalyst has been carried out at 303 …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 18–31 Read article
-
Isomerization of Lighter Alkanes by Heteropoly Acids: A Review
Abstract: Isomerization is the reaction used to enhance the octane number of gasoline and thereby helps in increasing the life of the automobile engines. Although a number of methods are known, researchers are still struggling for a low cost catalytic material in order to replace the previous expensive ones. Heteropoly acid has come out as one of the promising alternatives to meet the requirements and is considered to be a bi-functional …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 2, 2015 · pp. 1–14 Read article
-
Alcohol Oxidation in Ionic Liquids Catalysed by Recyclable Platinum Nanoparticles: A Green Approach
Abstract: The effect of particle size on the catalytic performance of materials in organic reactions is of scientific and industrial importance. In the present case we demonstrate the use of room temperature ionic liquids as effective agents of dispersion of platinum nanoparticles prepared from potassium tetrachloroplatinate. The platinum nanoparticles in the range 2.5±0.5 nm are recyclable catalysts for aerobic oxidation of alcohols under mild conditions. The particles suspended in ionic liquids …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 15–22 Read article
-
An Efficient Synthesis of Annulated Novel Dihydropyridine Derivatives using Zeolite H-BEA and Zeolite BEA-SO3H
Abstract: Modified zeolite (zeolite BEA-SO3H) was synthesized with intent to improve the surface area and Si/Al ratio by loading chlorosulphonic acid onto zeolite H-BEA. Parent and modified zeolite were characterized by variety of characterization techniques such as, ICP, FT-IR, XRD, TGA, NH3-TPD,BET surface area, etc. The catalytic applications of parent and modified zeolite H-BEA were demonstrated through the synthesis of novel quinoline and benzoquinoline substituted dihydropyridines (DHPs) via one pot Hantzsch …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 1–12 Read article
-
CuO/TiO2 Nanocomposites: Effect of Calcination on Photocatalytic Hydrogen Production
Abstract: Hydrothermally synthesized TiO2 nanorods were subjected to calcination from 350 to 550 °C and tested their catalytic performance for hydrogen (H2) production in aqueous glycerol solution under solar irradiation. High rate of H2 evolution ca.300 µmol.h−1.g−1cat was recorded with TiO2 nanorods calcined at 500 °C. The nanocomposites were prepared by varying Cu-loading 0.1 to 2.0 wt% and activated at 350 or 500 °C. About 25 folds enhancement in H2 production …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 13–20 Read article
-
Catalytic Applications of Copper Species in Organic Transformations: A Review
Abstract: Copper a naturally occurring element is present in the earth's crust, in oceans, lakes, and rivers, from minute trace element levels through to rich mine deposits. It is essential to life – plants, fish, animals and humans all need copper to function properly. Homogeneous copper catalyzed reactions are widely used for the construction of important organic molecules, including pharmaceuticals, commodity chemicals, and polymers. The development of copper catalysis has been …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 2, 2014 · pp. 21–34 Read article
-
Importance of Engineering of the Protein Molecules: A Review
Abstract: Engineering of the proteins is a powerful tool for production of the novel proteins that serve as catalysts to induce selective chemical and biological transformations that would not otherwise be possible. The methods of rational and random (methods entailing evolution, selection and the screening) are employed for the purpose to alter the specificity of the substarte profiles of selectivity through mutating the enzymes. The proteins identified through these techniques are …
Published in Journal of Catalyst & Catalysis · Vol. 7, Issue 2, 2020 · pp. 5–30 Read article
-
Mechanism Action of Catalysis
Abstract: Catalysis is a method for speeding up the rate of a reaction. It is of three types homogeneous, biocatalysis and heterogeneous catalysis which further involve acid base catalysis, that is based on Brønsted-Lowry concept which state that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a base and in enzymatic catalysis every enzyme is specific to …
Published in Journal of Catalyst & Catalysis · Vol. 8, Issue 3, 2021 · pp. 22–28 Read article
-
An Application of PARETO Chart for Investigation of Defects in FNB Casting Process
Abstract: Casting is one of the widely used manufacturing processes consisting of melting and pouring the metal into the mould to get the desired shape. Furan no-bake system is a binder system consisting of furan resin and acid catalyst. It is a fast growing system due to its excellent surface finish and dimensional accuracy. Although having high dimensional accuracy, many defects arise in FNB casting such as sand inclusion, gas porosity, …
Published in Journal of Experimental & Applied Mechanics · Vol. 9, Issue 1, 2018 · pp. 33–39 Read article