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25 articles for “oxidation-kinetics”
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Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
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Ru(III)-Catalyzed Oxidative Cleavage of Ritodrine Hydrochloride: A Kinetic and Mechanistic Study
Abstract: A systematic kinetic and mechanistic study of the oxidation of ritodrine hydrochloride (RTH) with chloramine-T (CAT) in both HClO4 and NaOH media has been carried out at 303 K. In acid medium, the reaction rate is very sluggish to be measured kinetically. Ruthenium (III) chloride ([Ru(III)]) was found to be an efficient catalyst. The reaction rate exhibits a first-order dependence on [CAT]0 in both media. It shows a fractional-order on …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 29–40 Read article
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Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium
Abstract: The kinetics of ruthenium(III) catalyzed degradative oxidation of methylparaben by the copper complex, diperiodatocuprate(III) in alkaline medium is studied at 25ºC and at a ionic strength of 8.0 × 10−2 mol dm−3. In the presence of catalyst ruthenium(III), the reaction between methylparaben and diperiodatocuprate(III) in aqueous alkaline medium exhibits 1:1 stoichiometry. The oxidation products were identified by UV-visible, GC-MS and IR spectroscopy. The reaction exhibited unit order in case of …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 4–17 Read article
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Removal of AB 10B from Water by Copper Oxide Nano- Particles through Adsorption: A Kinetics and Thermodynamic Study
Abstract: Copper oxide nanoparticle was synthesized by a simple method. Consequently, adsorbent was characterized by using FTIR, XRD, and SEM techniques. The study of optimized parameter contains pH, initial dye concentration, adsorbent dose and contact time. Langmuir, Freundlich and Tempkin models were pragmatic for evaluating adsorption equilibrium data of AB 10B as the adsorbent but experiment show the Langmuir model is best for it. The adsorption kinetic model study was done …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 37–48 Read article
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Mechanistic and Catalytic Behavior of Os(VIII) for the Chlorpheniramine Maleate and Bromamine-B Redox System: A Kinetics Based Approach
Abstract: Chlorpheniramine maleate (CPM) is an important antihistamine agent. To the best of our knowledge there is no report in the literature about the oxidation of CPM with halogen + 1 oxidant from the stand point of its kinetics and mechanistic chemistry. Hence, a systematic kinetics and mechanistic study on the oxidation of CPM with bromamine-B (BAB) in the presence of NaOH and Os(VIII) catalyst has been carried out at 303 …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 18–31 Read article
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Hot Corrosion Behaviour of Sol-Gel Alumina Coated IN625 Alloy in Alkali Metal Chlorides and Sulphates Salt Deposit Systems
Abstract: Sol-gel derived alumina coating was applied on Inconel 625 alloy using dip coating technique and their hot corrosion studies were carried out in LiCl-NaCl and Na2SO4-K2SO4 salt deposits system at 650 °C and 850 °C respectively. Oxidation kinetics measurement indicated the occurrence of an order of magnitude lower oxidation rate and around 15–20 % higher activation energy for the coated substrate as compared to uncoated one. EDS analysis of the …
Published in Journal of Thin Films, Coating Science Technology & Application · Vol. 3, Issue 1, 2016 · pp. 9–16 Read article
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Analysis of Oxidation Behavior on T-22 Boiler steel at 800°C
Abstract: The behavior of boiler steel T-22 in a rich air environment has been studied under the condition of isothermal at 800°C for 50 cycles in a cyclic manner. The kinetics of oxidation was established for boiler steel T-22under cyclic conditions for 50 cycles by weight change technique per unit area. Each cycle heating the sample at 1 hour followed by cooling 20 minutes at ambient temperature. Detonation gun spray techniques …
Published in Journal of Polymer & Composites · Vol. 8, Issue 1, 2020 · pp. 18–25 Read article
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Compatative Catalytic Study of Oxidation of Thiourea by Chromium (VI) in Presence of Different Catalysts and Micelles
Abstract: The series of catalysts like acetate, oxalate, EDTA, the varies micelles viz, CTAB, SDS, TRITON X-100 was carried out in the kinetic study of oxidation of Thiourea by Cr(VI) as an oxidant in water medium. The effect of catalytic efficiency has been study for varies catalyst and micelles by volumetric method and UV spectroscopic methods. The product was confirmed by IR studies. UV study reveals shows that higher catalytic efficiency …
Published in International Journal of Advance in Molecular Engineering · Vol. 4, Issue 1, 2026 · pp. 9–21 Read article
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Comparative studies of Oxidation and hot corrosion behaviors of uncoated and detonation gun sprayed Cr3C2-25NiCr coating on SA-213 boiler steel at 8000C
Abstract: Fe-based alloys suffer oxidation and hot corrosion when the surfaces were in contact with air (oxidation) as well as the salty atmosphere (Hot corrosion) at elevated temperatures. In these atmospheric conditions, non-protective oxide Fe2O3 was formed on the surface of alloys. Oxidation and hot corrosion have been recognized as a major problem in the applications of the diesel engine, boilers, gas turbines, and chemical power plant etc. Detonation-gun sprayed Cr3C2-25NiCr …
Published in Journal of Thin Films, Coating Science Technology & Application · Vol. 6, Issue 1, 2019 · pp. 17–22 Read article
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The Comparative Catalytic Activities of Tungstate and Molybdate Ions on Oxygen Transfer Reactions Used in Production of Some Petrochemicals
Abstract: The comparative catalytic activities and kinetics of formation of glycerine from oxidation of allyl alcohol by hydrogen peroxide in the presence of sodium tungstate and sodium molybdate as catalyst have been studied. The reaction is zero order with respect to hydrogen peroxide concentration and the reaction is first order with respect to allyl alcohol and catalyst (sodium tungstate or sodium molybdate) concentrations. Tungstate catalyzed formation of glycerine from allyl alcohol …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 1, 2017 · pp. 24–29 Read article
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Pt (II) Schiff Base Complex Catalyzed Oxidation of Internal and Terminal Alkenes
Abstract: Pt (II) complexes of Schiff base ligands were found highly efficient towards the catalytic oxidation of internal alkenes and terminal alkenes in dimethylformamide (DMF) solvent under normal pressure of molecular oxygen. In some catalytic reactions, H2O2 was also used as co-oxidant. No diminished catalytic activity was observed even after six to eight repeated catalytic runs. Effect of temperature and extra ligand etc. on the rate of oxidation, nature and percentage …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 3, 2015 · pp. 7–15 Read article
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Synthesis and characterization of mixed SnO2-ZnO Nano composites material to study the kinetics of catalytic reduction of Aromatic Nitro compounds
Abstract: A straightforward and cost-effective method was employed to synthesize zinc oxide (ZnO) nanostructures supported on tin oxide (SnO₂) for catalytic applications. This hybrid nanocomposite, formed by integrating ZnO with SnO₂, exhibited impressive catalytic activity in the reduction of various nitro compounds. The synergistic interaction between ZnO and SnO₂ significantly enhanced the surface area and active sites of the catalyst, thereby improving its overall efficiency. The resulting SnO₂-ZnO nanocomposite not only …
Published in Journal of Nanoscience, NanoEngineering & Applications · Vol. 15, Issue 3, 2025 · pp. 8–14 Read article
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Experimental Evaluation of MDM@Gd2O3:Eu3+ and Protein@MDM@Gd2O3:Eu3+ Functional Nanomaterial
Abstract: Lanthanide cation like Eu3+ (europium Xe 4f66s0) doped functional nanomaterials of lanthanide oxides especially of gadolinium oxide (Gd2O3) as nanorods capped with monodispersed macromolecule (MDM) like polyvinylpyrrolidone (PVP) coated with natural biopolymers like proteins as human serum albumin (HSA) have been the most demanding and applied nanomaterials in areas of the biosensor, optical distinguisher, electronic fluoresces, upconversion, and surface plasmonic resonance (SPR) nanomaterials and others. The Gd3+ and Eu3+lanthanide cations …
Published in Journal of Polymer & Composites · Vol. 12, Issue 6, 2024 · pp. 214–223 Read article
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Experimental and Simulation Study on Reduction Kinetics of Magnetite Ore by using Hydrogen
Abstract: In the present work, magnetite ore fines pellets were prepared for a study of reduction kinetics using hydrogen gas. In the present work, various parameters are investigated to assess their influence on reduction kinetics with respect to hydrogen utilisation. The different input variables influence the process, yielding the reduction fraction. The effect of temperature on reduction kinetics with hydrogen flow rate was explored for the optimum value of these parameters. …
Published in Journal of Materials & Metallurgical Engineering · Vol. 16, Issue 1, 2026 · pp. 71–81 Read article
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Hydrogen-based Steel Making - The future?
Abstract: The largest energy consumer i.e. 5% of global energy consumption and 7% of global CO2 emissions are produced by the iron and steel sector. The steel industry is a significant contributor to anthropogenic CO2 emissions, largely due to the use of carbon as a reducing agent in the production of virgin steel. The main cause of these emissions is the decrease in iron ore. While recycling scrap steel in electric …
Published in Journal of Materials & Metallurgical Engineering · Vol. 14, Issue 2, 2024 · pp. 38–65 Read article
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Oxidation Behaviour of Plasma Sprayed Carbon Nanotubes-Alumina Coated ASME-SA213-T291 Boiler Tube Steel
Abstract: In this research work, oxidation behaviour of Carbon Nanotubes reinforced Al2O3 coated ASME-SA213-T91 boiler tube steel specimens were investigated at 900°C temperature in air. The different CNTs-Alumina composite coatings were deposited using plasma spray technique and NiCr was used as bond coat before applying CNTs-Al2O3 coatings. The hot corrosion studies were conducted on all coated specimens in air at 900°C under cyclic conditions. The thermogravimetric technique was used to establish …
Published in Journal of Materials & Metallurgical Engineering · Vol. 7, Issue 3, 2017 · pp. 1–15 Read article
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Digital Twin Assisted Intelligent Prediction of Polymer Composite Degradation Under Environmental Exposure
Abstract: Polymer matrix composites (PMCs) deployed in aerospace, marine, automotive, and renewable-energy structures are continuously subjected to coupled environmental stressors — ultraviolet (UV) radiation, moisture ingress, thermal cycling, and mechanical loading — that progressively degrade their mechanical performance. Conventional accelerated ageing tests and empirical lifetime models are time-consuming, destructive, and poorly suited to in-service, asset-specific degradation forecasting. This paper proposes a Digital Twin (DT) assisted intelligent prediction framework that fuses a …
Published in Journal of Polymer & Composites · Vol. 14, Issue 4, 2026 Read article
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Improved Photocatalytic Activity for Removal of Methylene Blue Dye from Aqueous Solutions with La2O3-Modified Ceria Heterostructured Binary Oxide Nanocomposite Particles
Abstract: The current study aimed to examine the photocatalytic efficacy of a bimetallic CeO2-La2O3 hetero-NC in comparison to monometallic CeO2 and La2O3 nanoparticles (NPs), utilizing Methylene Blue (MB)as pollutant sample under natural solar and UV irradiation. The coprecipitation method was utilized to produce a bimetallic CeO2-La2O3 hetero-NC. Following this, the nanostructures underwent characterization through various techniques including FT-IR, FE-SEM, XRD, UV Vis- DRS, Raman, and Photoluminescence spectroscopy. The catalytic activity of …
Published in Journal of Polymer & Composites · Vol. 13, Issue 4, 2025 · pp. 514–532 Read article
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A Critical Analysis of Cold Spray Coatings and its Tribological Performances
Abstract: Coatings are utilized for temperature barrier, protection against corrosion and wear etc. Cold spray is a solid-state processing method that is unique among thermal deposition procedures since it deposits particles at temperatures below their melting point. This technology does not involve particle melting, hence retaining the original properties of the materials. Increased coating strength is achieved by retaining of feedstock powder microstructures and characteristics, which prevents oxide formation and other …
Published in Journal of Polymer & Composites · Vol. 12, Issue 3, 2024 · pp. 220–226 Read article
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An Ultraviolet-Curable Nano Cerium Oxide Coating and Its Anti Ultraviolet /Blue Light Properties
Abstract: An ultraviolet (UV)-curable nano cerium oxide (CeO2) coating with enhanced blue light and UV shielding properties, prepared using an ultrasonic blending method, is presented. This study systematically investigated the optimal synthesis conditions for nano CeO2, as well as the effects of UV intensity and CeO2 concentration on the curing kinetics and blue/UV light shielding performance of the UV-curable nanocomposite. The results indicate that the synthesized nano CeO2 exhibited improved mechanical …
Published in Journal of Polymer & Composites · Vol. 13, Issue 6, 2025 · pp. 306–324 Read article