STM Journals Peer-reviewed research from Consortium e-Learning Network

OmniScience: A Multi-disciplinary Journal Original Research

New Analytical Reagents and Study of Preparation, Spectral Characterization, Scanning Microscopy, and Solubility Behaviors

  1. Nemah Sahib Mohammed Husien Department of Medical Laboratories Techniques, Altoosi University College

Abstract

Chemical reagents used in chemical processes vary depending on the process in which they are used, but in general, chemical reagents are used to conduct quality analyses, to determine the contents of various chemical elements in raw materials and in finished products, to adjust the pH and alkalinity of chemical solutions, and to react with other chemicals and produce products. There are some examples of chemical reagents used in chemical processes, such as selectivity reagents, contamination reagents with ions and elements, and environmental pollution reagents. Many identical techniques used to give evidences for preparation our reagents. Reagents are the basis for measurements of pollution, environmental preservation, water elements, etc. Therefore, modern research has focused on preparing analytical reagents from materials with great sensitivity to pollutants, especially heavy metal pollutants. For this reason, aldamine reagents and azo reagents, which are known to be highly sensitive to low-concentration elements, were prepared. Several attempts have been made in the past decades to prepare reagents from macroscopic cyclic compounds because they are highly sensitive to environmental pollution of soil and water components, but their sensitivity was only limited to small concentrations of elements, so researchers turned to manufacturing other reagents with higher sensitivity, represented by aldamine reagents. Macroscopic analytical reagents, such as aldamine reagents, are considered very sensitive to ions, especially the transition elements, because they are characterized by clear color changes when in coordination with ions and give the colors of deep-colored complexes due to the successive chromophore and oxo-chrome groups in their composition, to which the color intensity of these reagents is due. Macroscopic analytical reagents, such as aldamine reagents, are considered very sensitive to ions, especially the transition elements, because they are characterized by clear color changes when in coordination with ions and give the colors of deep-colored complexes due to the successive chromophore and exochrome groups in their composition, to which the color intensity of these reagents is due.

Keywords

References (26)

  1. Mazurek W, Kennedy BJ, Murray KS, O'Connor MJ, Rodgers JR, Snow MR, et al. Magnetic interactions in metal complexes of binucleating ligands. 2. Synthesis and properties of binuclear copper(II) compounds containing exogenous ligands that bridge through two atoms. Crystal and molecular structure of a binuclear .mu.-pyrazolato-N,N'-bridged dicopper(II) complex of 1,3-bis(salicylideneamino)propan-2-ol. Inorganic Chemistry. 1985;24(20):3258-3264. doi:10.1021/ic00214a033
  2. Schoustra SK, Groeneveld T, Smulders MMJ. The effect of polarity on the molecular exchange dynamics in imine-based covalent adaptable networks. Polymer Chemistry. 2021;12(11):1635-1642. doi:10.1039/d0py01555e
  3. Schoustra SK, Dijksman JA, Zuilhof H, Smulders MMJ. Molecular control over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials. Chemical Science. 2021;12(1):293-302. doi:10.1039/d0sc05458e
  4. Wang P, Yang L, Dai B, Yang Z, Guo S, Gao G, et al. A self-healing transparent polydimethylsiloxane elastomer based on imine bonds. European Polymer Journal. 2020;123:109382. doi:10.1016/j.eurpolymj.2019.109382
  5. Alexakis A, Aujard I, Kanger T, Mangeney P. (R,R)- and (S,S)-N,N'-dimethyl-1,2-diphenylethylene-1,2-diamine. Org Synth. 1999;76:23–36.
  6. Borchert AJ, Ernst DC, Downs DM. Reactive Enamines and Imines In Vivo: Lessons from the RidA Paradigm. Trends in Biochemical Sciences. 2019;44(10):849-860. doi:10.1016/j.tibs.2019.04.011
  7. Eliot AC, Kirsch JF. Pyridoxal Phosphate Enzymes: Mechanistic, Structural, and Evolutionary Considerations. Annual Review of Biochemistry. 2004;73(1):383-415. doi:10.1146/annurev.biochem.73.011303.074021
  8. Mangas-Sanchez J, France SP, Montgomery SL, Aleku GA, Man H, Sharma M, et al. Imine reductases (IREDs). Current Opinion in Chemical Biology. 2017;37:19-25. doi:10.1016/j.cbpa.2016.11.022
  9. Nozaki H, Takaya H, Moriuti S, Noyori R. Homogeneous catalysis in the decomposition of diazo compounds by copper chelates. Tetrahedron. 1968;24(9):3655-3669. doi:10.1016/s0040-4020(01)91998-2
  10. Aljamali NM. Synthesis and biological study of hetero (atoms and cycles) compounds. Der Pharma Chemica. 2016; 8(6): 40–8.
  11. Talib AA, Kadhium AJ, Mohammed MS. Preparation, characterization and biological study of complexes of Co(II) and Cu(II) with mixed ligands of azo naphthol compounds. J Chem Health Risks. 2023;13(4):177–180.
  12. Aljamali NM. Synthesis and Chemical Identification of Macro Compounds of (Thiazol and Imidazol). Research Journal of Pharmacy and Technology. 2015;8(1):78. doi:10.5958/0974-360x.2015.00016.5
  13. ALabbasy AJ, Naeem AK. The biosynthesis of metal nanoparticles by a variety of organisms. J Alharf. 2024 Feb;20:63-73.
  14. Mandler MD, Truong PM, Zavalij PY, Doyle MP. Catalytic Conversion of Diazocarbonyl Compounds to Imines: Applications to the Synthesis of Tetrahydropyrimidines and β-Lactams. Organic Letters. 2014;16(3):740-743. doi:10.1021/ol403427s
  15. Hosseini M, Mashreghi M, Eshghi H. Biosynthesis and antibacterial activity of gold nanoparticles coated with reductase enzymes. Micro & Nano Letters. 2016;11(9):484-489. doi:10.1049/mnl.2016.0065
  16. Jawad AAR, Aljamali DNM. Triazole-Anil and Triazol-Azo Reagents (Creation, Spectral Categorization, Scanning Microscopy, Thermal Analysis). NeuroQuantology. 2021;19(11):84-94. doi:10.14704/nq.2021.19.11.nq21178
  17. Aljamali NM. "Inventing of Macrocyclic Formazan Compounds with Their Evaluation in Nano- Behavior in the Scanning Microscope and Chromatography". Biomedical Journal of Scientific & Technical Research. 2022;41(3). doi:10.26717/bjstr.2022.41.006616
  18. Saito T, Kimura S, Nishiyama Y, Isogai A. Cellulose Nanofibers Prepared by TEMPO-Mediated Oxidation of Native Cellulose. Biomacromolecules. 2007;8(8):2485-2491. doi:10.1021/bm0703970
  19. Fan Y, Saito T, Isogai A. Individual chitin nano-whiskers prepared from partially deacetylated α-chitin by fibril surface cationization. Carbohydrate Polymers. 2010;79(4):1046-1051. doi:10.1016/j.carbpol.2009.10.044
  20. Habibi Y. Key advances in the chemical modification of nanocelluloses. Chem. Soc. Rev. 2014;43(5):1519-1542. doi:10.1039/c3cs60204d
  21. Loo Jacky Fong-Chuen, Chien Yi-Hsin, Yin Feng, Kong Siu-Kai, Ho Ho-Pui, Yong Ken-Tye. Up conversion and down conversion nanoparticles for biophotonics and nanomedicine. Coord Chem Rev. 2019; 400: 213042. doi:10.1016/j.ccr.2019.213042. S2CID 203938224.
  22. Yu P, Yao Y, Wu J, Niu X, Rogach AL, Wang Z. Effects of Plasmonic Metal Core -Dielectric Shell Nanoparticles on the Broadband Light Absorption Enhancement in Thin Film Solar Cells. Scientific Reports. 2017;7(1). doi:10.1038/s41598-017-08077-9
  23. Torres-Torres C, López-Suárez A, Can-Uc B, Rangel-Rojo R, Tamayo-Rivera L, Oliver A. Collective optical Kerr effect exhibited by an integrated configuration of silicon quantum dots and gold nanoparticles embedded in ion-implanted silica. Nanotechnology. 2015;26(29):295701. doi:10.1088/0957-4484/26/29/295701
  24. Shishodia S, Chouchene B, Gries T, Schneider R. Selected I-III-VI2 Semiconductors: Synthesis, Properties and Applications in Photovoltaic Cells. Nanomaterials. 2023;13(21):2889. doi:10.3390/nano13212889
  25. Chae SY, Park MK, Lee SK, Kim TY, Kim SK, Lee WI. Preparation of Size-Controlled TiO2 Nanoparticles and Derivation of Optically Transparent Photocatalytic Films. Chemistry of Materials. 2003;15(17):3326-3331. doi:10.1021/cm030171d
  26. Simonis JJ, Basson AK. Evaluation of a low-cost ceramic micro-porous filter for elimination of common disease microorganisms. Physics and Chemistry of the Earth, Parts A/B/C. 2011;36(14-15):1129-1134. doi:10.1016/j.pce.2011.07.064
Support