Journal of Thin Films, Coating Science Technology & Application Review Article

Strategic Dispersion and Stabilization Protocols for Aqueous Organic Pigments: High-Speed Dispersion vs. Bead Mill Systems.

  1. Nilesh P. Badgujar ✉ Professor & Head, Department of Chemical Technology, UPL University of Sustainable Technology, At. Vataia, Ankleshwar- 393135, Gujarat India

This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.

Abstract

In modern coating industry era, aqueous organic pigment dispersions are critical components for the development of flexo and inkjet inks, textile colorants, and various commercial water-based tinting systems. So converting raw, hydrophobic, and heavily agglomerated pigment powders into the finely dispersed, sub-micron colloidal suspensions. It will achieving peak color strength, transparency, gloss, and multi-year shelf stability requires
This review examines the mechano-chemical and thermodynamic forces driving the aqueous pigment dispersion process. In the pigment dispersion process—surface wetting, mechanical breakdown or deagglomeration and colloidal stabilization—and find out the how structured "anchor-block" polymeric surfactants function across electrostatic, steric, and electrosteric regimes. Finally, we evaluate the performance of High-Speed Dispersers (HSD) against Media-Assisted Agitator Bead Mills, focusing on local energy density, shear rate distribution, particle size reduction mechanics, and the rheological properties.

Keywords

References (36)

  1. 1. Moutsinas GA, Meletiadis G, Patetsou Z, Prampromis DS, Patitsas KD, Dritsas SE. The Alignment of Greece with the Environmental Law of the European Union: Historical Development, Current Trends and Critical Implications with Regard to the Challenge of Intragenerational and Intergenerational Justice. Open Journal of Social Sciences. 2022 Feb 28;10(2):476-501.
  2. 2. Tadros TF. Polymeric surfactants: dispersion stability and industrial applications. Walter de Gruyter GmbH & Co KG; 2017 May 8.
  3. 3. Farrokhpay S, Filippov L, Fornasiero D. Flotation of fine particles: A review. Mineral Processing and Extractive Metallurgy Review. 2021 Oct 3;42(7):473-83.
  4. 4. Winkler K, Hoffmann MM, Krane V, Drechsler C, Wanner C, German Diabetes and Dialysis Study Investigators. Lipoprotein‐associated phospholipase A2 and outcome in patients with type 2 diabetes on haemodialysis. European journal of clinical investigation. 2012 Jul;42(7):693-701.
  5. 5. Mende S, Stenger F, Peukert W, Schwedes J. Mechanical production and stabilization of submicron particles in stirred media mills. Powder technology. 2003 May 29;132(1):64-73.
  6. 6. Athanasiu AA, Deaconu M, Crudu M, Doncea S, Stoica R, Oproiu L, Senin R, Ruse M, Rosu D, Filipescu C. Synthesis and characterization of nanosized copper (II)-phthalocyanine pigment (P BI 15: 3) with the modified surface. i. Rev. De Chim. 2017 Feb 1; 68:343-9.
  7. 7. Conley, R. F. (1996). Practical dispersion: A guide to understanding and formulating slurries. John Wiley & Sons.
  8. 8. Gregory, P. (1991). High-technology applications of organic colorants. Springer. https://doi.org/10.1007/978-1-4615-3822-6
  9. 9. Herbst, W., & Hunger, K. (2004). Industrial organic pigments: Production, properties, applications (3rd ed.). Wiley-VCH.
  10. 10. Kwok DY, Li A, Lam CN, Wu R, Zschoche S, Pöschel K, Gietzelt T, Grundke K, Jacobasch HJ, Neumann AW. Low‐rate dynamic contact angles on poly [styrene‐alt‐(hexyl/10‐carboxydecyl (90/10) maleimide)] and the determination of solid surface tensions. Macromolecular Chemistry and Physics. 1999 May 1;200(5):1121-33.
  11. 11. Washburn EW. The dynamics of capillary flow. Physical review. 1921 Mar 1;17(3):273.
  12. 12. Derjaguin, B., & Landau, L. (1941). Theory of the stability of strongly charged lyophobic sols and of the adhesion of strongly charged particles in solutions of electrolytes. Acta Physicochimica URSS, 14, 633–662.
  13. 13. Verwey, E. J. W., & Overbeek, J. T. G. (1948). Theory of the stability of lyophobic colloids: The interaction of sol particles having an electric double layer. Elsevier.
  14. 14. Napper, D. H. (1983). Polymeric stabilization of colloidal dispersions. Academic Press.
  15. 15. Sato, T., & Ruch, R. (1980). Stabilization of colloidal dispersions by polymer adsorption. Marcel Dekker.
  16. 16. Flory, P. J. (1953). Principles of polymer chemistry. Cornell University Press.
  17. 17. Malamatari M, Taylor KM, Malamataris S, Douroumis D, Kachrimanis K. Pharmaceutical nanocrystals: production by wet milling and applications. Drug discovery today. 2018 Mar 1;23(3):534-47.
  18. 18. Kwade, A. (1999). Determination of the most important grinding mechanism in stirred media mills by calculating stress intensity and stress number. Powder Technology, 105(1–3), 382–388. https://doi.org/10.1016/S0032-5910(99)00162-X
  19. 19. Stenger, F., Mende, S., Schwedes, J., & Peukert, W. (2005). Nanomilling in stirred media mills. Chemical Engineering Science, 60(16), 4557–4565. https://doi.org/10.1016/j.ces.2005.02.057
  20. 20. Janković, A. (2003). Variables affecting the fine grinding of minerals using stirred mills. Minerals Engineering, 16(4), 337–345. https://doi.org/10.1016/S0892-6875(03)00007-4
  21. 21. Spinelli HJ. Polymeric dispersants in ink jet technology. Advanced Materials. 1998 Oct;10(15):1215-8.
  22. 22. Holmberg, K., Jönsson, B., Kronberg, B., & Lindman, B. (2002). Surfactants and polymers in aqueous solution (2nd ed.). John Wiley & Sons.
  23. 23. Hunter, R. J. (2001). Foundations of colloid science (2nd ed.). Oxford University Press.
  24. 24. Mewis, J., & Wagner, N. J. (2012). Colloidal suspension rheology. Cambridge University Press.
  25. 25. Barnes, H. A. (1997). Thixotropy—A review. Journal of Non-Newtonian Fluid Mechanics, 70(1–2), 1–33. https://doi.org/10.1016/S0377-0257(97)00004-9
  26. 26. Israelachvili, J. N. (2011). Intermolecular and surface forces (3rd ed.). Academic Press.
  27. 27. van de Ven, T. G. M. (1989). Colloidal hydrodynamics. Academic Press.
  28. 28. Russel, W. B., Saville, D. A., & Schowalter, W. R. (1989). Colloidal dispersions. Cambridge University Press.
  29. 29. Everett, D. H. (1988). Basic principles of colloid science. Royal Society of Chemistry.
  30. 30. Cosgrove, T. (Ed.). (2010). Colloid science: Principles, methods and applications (2nd ed.). Wiley-Blackwell.
  31. 31. McClements, D. J. (2015). Food emulsions: Principles, practices, and techniques (3rd ed.). CRC Press.
  32. 32. Myers, D. (2005). Surfaces, interfaces, and colloids: Principles and applications (2nd ed.). Wiley-VCH.
  33. 33. Rosen, M. J., & Kunjappu, J. T. (2012). Surfactants and interfacial phenomena (4th ed.). John Wiley & Sons.
  34. 34. Binks, B. P. (2002). Particles as surfactants—Similarities and differences. Current Opinion in Colloid & Interface Science, 7(1–2), 21–41. https://doi.org/10.1016/S1359-0294(02)00008-0
  35. 35. Müller, B., & Poth, U. (2011). Coatings formulation: An introduction. Vincentz Network.
  36. 36. Bieleman, J. (Ed.). (2000). Additives for coatings. Wiley-VCH

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