Journal of Polymer & Composites Original Research Special issue

Effect of Aging on the Performance of Polymer Composite: A Review

  1. Ajay Kumar Department of Mechanical Engineering, GLA University, Mathura
  2. Pankaj Sonia Department of Mechanical Engineering, GLA University, Mathura
  3. Vijay Verma Department of mechanical Engineering, BIET Jhansi

Abstract

The exceptional robustness, corrosion resistance, and lightweight design, polymer composites (PCs) are crucial to modern engineering escalating the utilization of polymer composite in structural applications including aerospace engineering, automobile engineering, etc. With a greater number of positive aspects, the polymer composite also deteriorate by different environment conditions with their exposing duration considered as aging of polymer composites. However, a variety of elements influencing the ageing process determine their long-term performance. The polymer composite commonly influenced by hydrothermal, radiation, thermal, mechanical and biodegradation aging significantly reduce the fracture toughness and tensile strength. Due to aging polymer composite deteriorate by weight loss, delamination, plasticization, micro cracking and fibre pullout defects. This covers general deterioration, environmental factors, and the effects of synthesis and production methods. The study offers important new insights into how aging affects the dependability and durability of certain materials. Additionally, it investigates accelerated ageing techniques and other experimental methodologies, providing workable solutions to improve the durability of polymer composites by adding reinforcements to the polymer matrix, such as nanofillers or nano clays. Through the advancement and consolidation of current information, this study provides engineers and researchers with useful guidance and practical tools to enhance the durability of polymer composites in a variety of applications.

Keywords

References (57)

  1. Gupta AK, Kiran R, Zafar S, Pathak H. Effect of hygrothermal ageing on the mechanical properties of glass fiber reinforced polymer composite: Experimental and numerical approaches. Materials Today Communications. 2024;41:111060. doi:10.1016/j.mtcomm.2024.111060
  2. Gupta A, Kumar N, Sachdeva A. Factors affecting the ageing of polymer composite: A state of art. Polymer Degradation and Stability. 2024;221:110670. doi:10.1016/j.polymdegradstab.2024.110670
  3. Miao C, Xingzhong G, Bolin T, Zhengwei D, Haidong L, Jie Y. Multiscale thermal oxidative ageing mechanisms of carbon fiber/epoxy plain woven composites under short beam shear loading. Thin-Walled Structures. 2023;185:110566. doi:10.1016/j.tws.2023.110566
  4. Stankevich S, Zeleniakiene D, Sevcenko J, Bulderberga O, Zetkova K, Tedim J, et al. Moisture Absorption and Mechanical Degradation of Polymer Systems Incorporated with Layered Double Hydroxide Particles. Polymers. 2024;16(23):3388. doi:10.3390/polym16233388
  5. Bhuvaneswari V, Devarajan B, Arulmurugan B, Mahendran R, Rajkumar S, Sharma S, et al. A Critical Review on Hygrothermal and Sound Absorption Behavior of Natural-Fiber-Reinforced Polymer Composites. Polymers. 2022;14(21):4727. doi:10.3390/polym14214727
  6. Xu X, Zhang B, Shi F, Liu K, Peng G, Gao L, et al. Study on the Influence of Hygrothermal Aging on the Mechanical Properties of Carbon Fabric/Polyetheretherketone Composites. Polymers. 2025;17(6):724. doi:10.3390/polym17060724
  7. Jean-Fulcrand A, Léger E, Dau F, Dubé M, Tabiai I. Degradation mechanisms of CF/PPS, CF/PEI, and CF/PEEK under combined UV radiation and condensation. Composites Part A: Applied Science and Manufacturing. 2025;198:109131. doi:10.1016/j.compositesa.2025.109131
  8. Tostes MDVPH, d’Almeida JRM. Effect of UV Radiation Exposure and Simulated Particle Erosion Damage on the Mechanical Behavior of Carbon/Glass Hybrid Composites. Polymers. 2025;17(7):861. doi:10.3390/polym17070861
  9. Zafari B, Toby Mottram J, Purnell P, Grammatikos S, Evernden M. Hygrothermal Aging of Pultruded Fiber–Polymer Composite with Predictions for Design Service Lives. Journal of Composites for Construction. 2025;29(1). doi:10.1061/jccof2.cceng-4854
  10. Yao X, Yang X, Lu Y, Qiu Y, Zeng Q. Review of the Synthesis and Degradation Mechanisms of Some Biodegradable Polymers in Natural Environments. Polymers. 2024;17(1):66. doi:10.3390/polym17010066
  11. Chaffey B, Marchante-Rodriguez V, Brighton J, Grasso M. Degradation mechanisms effect on the mechanical properties of pultruded CFRPS: a review. Discover Polymers. 2025;2(1). doi:10.1007/s44347-025-00029-1
  12. Hu Y, Li X, Lang AW, Zhang Y, Nutt SR. Water immersion aging of polydicyclopentadiene resin and glass fiber composites. Polymer Degradation and Stability. 2016;124:35-42. doi:10.1016/j.polymdegradstab.2015.12.008
  13. Camelia, “Effects of the Long-Time Immersion on the Mechanical Behaviour in Case of Some E-glass / Resin Composite Materials,” 2010.
  14. Fang Y, Wang K, Hui D, Xu F, Liu W, Yang S, et al. Monitoring of seawater immersion degradation in glass fibre reinforced polymer composites using quantum dots. Composites Part B: Engineering. 2017;112:93-102. doi:10.1016/j.compositesb.2016.12.043
  15. Xin H, Liu Y, Mosallam A, Zhang Y. Moisture diffusion and hygrothermal aging of pultruded glass fiber reinforced polymer laminates in bridge application. Composites Part B: Engineering. 2016;100:197-207. doi:10.1016/j.compositesb.2016.04.085
  16. DHAKAL H, ZHANG Z, RICHARDSON M. Effect of water absorption on the mechanical properties of hemp fibre reinforced unsaturated polyester composites. Composites Science and Technology. 2007;67(7-8):1674-1683. doi:10.1016/j.compscitech.2006.06.019
  17. Shi J, Yuan S, Zhang W, Zhang J, Chen H. Hydrothermal aging mechanisms and service life prediction of twisted bamboo fiber wound composites. Materials & Design. 2023;227:111716. doi:10.1016/j.matdes.2023.111716
  18. Kamau-Devers K, Kortum Z, Miller SA. Hydrothermal aging of bio-based poly(lactic acid) (PLA) wood polymer composites: Studies on sorption behavior, morphology, and heat conductance. Construction and Building Materials. 2019;214:290-302. doi:10.1016/j.conbuildmat.2019.04.098
  19. Sang L, Wang C, Wang Y, Hou W. Effects of hydrothermal aging on moisture absorption and property prediction of short carbon fiber reinforced polyamide 6 composites. Composites Part B: Engineering. 2018;153:306-314. doi:10.1016/j.compositesb.2018.08.138
  20. Rajeesh KR, Gnanamoorthy R, Velmurugan R. Effect of humidity on the indentation hardness and flexural fatigue behavior of polyamide 6 nanocomposite. Materials Science and Engineering: A. 2010;527(12):2826-2830. doi:10.1016/j.msea.2010.01.070
  21. Javier C, LeBlanc J, Shukla A. Hydrothermally degraded carbon fiber / epoxy plates subjected to underwater explosive loading in a fully submerged environment. Marine Structures. 2020;72:102761. doi:10.1016/j.marstruc.2020.102761
  22. Sunny J, Palacios Moreno J, Nazaripoor H, Mertiny P. Hydrothermal Aging and Humidity Exposure of Carbon and Basalt Fibers and Life Time Prediction. Fibers. 2024;12(7):58. doi:10.3390/fib12070058
  23. Chowdhury IR, Rao PS, O'Dowd NP, Comer AJ. Hygrothermal ageing effects on failure behaviour of fibre-reinforced polymer composite materials under in-situ SEM testing. Composites Part B: Engineering. 2025;294:112148. doi:10.1016/j.compositesb.2025.112148
  24. Sunny J, Nazaripoor H, Palacios Moreno J, Mertiny P. Accelerated Zero-Stress Hydrothermal Aging of Dry E-Glass Fibers and Service Life Prediction Using Arrhenius Model. Fibers. 2023;11(8):70. doi:10.3390/fib11080070
  25. Sang L, Wang Y, Wang C, Peng X, Hou W, Tong L. Moisture diffusion and damage characteristics of carbon fabric reinforced polyamide 6 laminates under hydrothermal aging. Composites Part A: Applied Science and Manufacturing. 2019;123:242-252. doi:10.1016/j.compositesa.2019.05.023
  26. Agarwal S, Pai Y, Pai D, Mahesha GT. Assessment of ageing effect on the mechanical and damping characteristics of thin quasi-isotropic hybrid carbon-Kevlar/epoxy intraply composites. Cogent Engineering. 2023;10(1). doi:10.1080/23311916.2023.2235111
  27. Starkova O, Platnieks O, Sabalina A, Gaidukovs S. Hydrothermal Ageing Effect on Reinforcement Efficiency of Nanofibrillated Cellulose/Biobased Poly(butylene succinate) Composites. Polymers. 2022;14(2):221. doi:10.3390/polym14020221
  28. Ugochukwu S, Ridzuan MJM, Abdul Majid MS, Cheng EM, Razlan ZM, Marsi N. Effect of thermal ageing on the scratch resistance of natural-fibre-reinforced epoxy composites. Composite Structures. 2021;261:113586. doi:10.1016/j.compstruct.2021.113586
  29. Xie K, Long G, Qin Y, Luo X, Huang K. Atomic insights into the impact of thermal oxidation aging on graphene/epoxy resin interfaces. Applied Surface Science. 2025;700:163168. doi:10.1016/j.apsusc.2025.163168
  30. Doriat A, Gigliotti M, Beringhier M, Lalizel G, Dorignac E, Berterretche P, et al. Effect of high-temperature high-speed airflow on the thermo-oxidative aging of epoxy polymer and composite: An experimental study. Polymer Testing. 2025;153:109019. doi:10.1016/j.polymertesting.2025.109019
  31. Karbhari VM, Xian G, Hong S. Effect of thermal exposure on carbon fiber reinforced composites used in civil infrastructure rehabilitation. Composites Part A: Applied Science and Manufacturing. 2021;149:106570. doi:10.1016/j.compositesa.2021.106570
  32. Croll SG, Hinderliter BR, Liu S. Statistical approaches for predicting weathering degradation and service life. Progress in Organic Coatings. 2006;55(2):75-87. doi:10.1016/j.porgcoat.2005.08.006
  33. Carra G, Carvelli V. Ageing of pultruded glass fibre reinforced polymer composites exposed to combined environmental agents. Composite Structures. 2014;108:1019-1026. doi:10.1016/j.compstruct.2013.10.042
  34. Commereuc S, Askanian H, Verney V, Celli A, Marchese P, Berti C. About the end life of novel aliphatic and aliphatic-aromatic (co)polyesters after UV-weathering: Structure/degradability relationships. Polymer Degradation and Stability. 2013;98(7):1321-1328. doi:10.1016/j.polymdegradstab.2013.03.030
  35. Al-Turaif HA. Surface morphology and chemistry of epoxy-based coatings after exposure to ultraviolet radiation. Progress in Organic Coatings. 2013;76(4):677-681. doi:10.1016/j.porgcoat.2012.12.010
  36. Lu T, Solis-Ramos E, Yi YB, Kumosa M. Synergistic environmental degradation of glass reinforced polymer composites. Polymer Degradation and Stability. 2016;131:1-8. doi:10.1016/j.polymdegradstab.2016.06.025
  37. Lu T, Solis-Ramos E, Yi Y, Kumosa M. UV degradation model for polymers and polymer matrix composites. Polymer Degradation and Stability. 2018;154:203-210. doi:10.1016/j.polymdegradstab.2018.06.004
  38. Khotbehsara MM, Manalo A, Aravinthan T, Turner J, Ferdous W, Hota G. Effects of ultraviolet solar radiation on the properties of particulate-filled epoxy based polymer coating. Polymer Degradation and Stability. 2020;181:109352. doi:10.1016/j.polymdegradstab.2020.109352
  39. Varghese AM, Rangaraj VM, Luckachan G, Mittal V. UV Aging Behavior of Functionalized Mullite Nanofiber-Reinforced Polypropylene. ACS Omega. 2020;5(42):27083-27093. doi:10.1021/acsomega.0c02437
  40. Haider I, Gul IH, Aziz S, Faraz MI, Khan MA, Jaffery SHI, et al. Environmental aging of reinforced polymer composite radome: reliability and performance investigation. Frontiers in Materials. 2024;11. doi:10.3389/fmats.2024.1427541
  41. Cheng L, Farooq A, Yang HW, Wang P, Qiao Q, Guo M, et al. A low-dosage chemicals, short process alternative approach to reactive dyeing of golden cocoon-like silk fibers with robust color fastness. Polymer Testing. 2023;123:108035. doi:10.1016/j.polymertesting.2023.108035
  42. Pan B, Shao L, Jiang J, Zou S, Kong H, Hou R, et al. 3D printing sacrificial templates for manufacturing hydrogel constructs with channel networks. Materials & Design. 2022;222:111012. doi:10.1016/j.matdes.2022.111012
  43. Ci S, Wang B, Di C, Wang M, Zhu B, Qiao K. Effect of Ultraviolet Aging on Properties of Epoxy Resin and Its Pultruded Fiber-Reinforced Composite. Polymers. 2025;17(3):294. doi:10.3390/polym17030294
  44. Moreno DDP, Hirayama D, Saron C. Accelerated aging of pine wood waste/recycled LDPE composite. Polymer Degradation and Stability. 2018;149:39-44. doi:10.1016/j.polymdegradstab.2018.01.014
  45. Nguyen T, Petersen EJ, Pellegrin B, Gorham JM, Lam T, Zhao M, et al. Impact of UV irradiation on multiwall carbon nanotubes in nanocomposites: Formation of entangled surface layer and mechanisms of release resistance. Carbon. 2017;116:191-200. doi:10.1016/j.carbon.2017.01.097
  46. Keith MJ, Román-Ramírez LA, Leeke G, Ingram A. Recycling a carbon fibre reinforced polymer with a supercritical acetone/water solvent mixture: Comprehensive analysis of reaction kinetics. Polymer Degradation and Stability. 2019;161:225-234. doi:10.1016/j.polymdegradstab.2019.01.015
  47. Wang G, Li L, Yang P, Chen J. Glass fiber reinforced nylon-6/nylon-1012 composite material serves as automotive rearview mirror bracket. Next Materials. 2025;8:100666. doi:10.1016/j.nxmate.2025.100666
  48. Maraveas C, Kyrtopoulos IV, Arvanitis KG, Bartzanas T. The Aging of Polymers under Electromagnetic Radiation. Polymers. 2024;16(5):689. doi:10.3390/polym16050689
  49. Jirků P, Muller M, Mishra RK, Svobodová J. Effect of Recycling and UV Ageing on the Properties of PLA-Based Materials Used in Additive Manufacturing. Polymers. 2025;17(13):1862. doi:10.3390/polym17131862
  50. Banerjee A, Borah A, Chah CN, Dhal MK, Madhu K, Katiyar V, et al. Decoding the complex interplay of biological and chemical factors in Polylactic acid biodegradation: A systematic review. International Journal of Biological Macromolecules. 2024;282:136956. doi:10.1016/j.ijbiomac.2024.136956
  51. Chatterjee and E. Fosso-Kankeu, “A Review on Biodegradable Polymers Production From Agricultural Wastes: A Green, Sustainable and Eco-friendly Approach,” in Reference Module in Materials Science and Materials Engineering, Elsevier, 2024.
  52. Jesus LCC, Teixeira LA, Luz SM. Microfibrillated cellulose for enhanced performance of PLA composites after soil degradation and water absorption. Journal of Thermoplastic Composite Materials. 2025;39(6):3276-3298. doi:10.1177/08927057251404435
  53. Vasile C, Pamfil D, Râpă M, Darie-Niţă RN, Mitelut AC, Popa EE, et al. Study of the soil burial degradation of some PLA/CS biocomposites. Composites Part B: Engineering. 2018;142:251-262. doi:10.1016/j.compositesb.2018.01.026
  54. Saadi Z, Rasmont A, Cesar G, Bewa H, Benguigui L. Fungal Degradation of Poly(l-lactide) in Soil and in Compost. Journal of Polymers and the Environment. 2011;20(2):273-282. doi:10.1007/s10924-011-0399-9
  55. Lim H, Jung S, Kim S, Kim J, Kim SG, Seo J, et al. Torrefied hemp fiber as a sustainable reinforcement for biodegradable PHA composites: enhancing interfacial compatibility and environmental stability. Composites Part B: Engineering. 2025;304:112653. doi:10.1016/j.compositesb.2025.112653
  56. Lila MK, Shukla K, Komal UK, Singh I. Accelerated thermal ageing behaviour of bagasse fibers reinforced Poly (Lactic Acid) based biocomposites. Composites Part B: Engineering. 2019;156:121-127. doi:10.1016/j.compositesb.2018.08.068
  57. Costa LADM, Costa MSSDM, Damaceno FM, Chiarelotto M, Bofinger J, Gazzola W. Bioaugmentation as a strategy to improve the compost quality in the composting process of agro-industrial wastes. Environmental Technology & Innovation. 2021;22:101478. doi:10.1016/j.eti.2021.101478
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