Journal of Polymer & Composites Original Research Special issue
Fabrication and Assessment of Tribological Performance of Nickel-Graphene-MXene Hybrid Nano-composites
Abstract
As industries such as aerospace, automotive, defence, and electronics demand materials with superior wear resistance, high strength, and thermal stability, traditional metals are reaching their performance limits. Hybrid nanocomposites offer a pathway to meet these stringent requirements. In this study, novel Nickel-Graphene-MXene hybrid nanocomposites were fabricated using a powder metallurgy route, incorporating varying weight percentages (up to 2 wt.%) of MXene and 1 wt.% graphene nanosheets into a nickel matrix and evaluated for their tribological performance. Comprehensive characterization using FTIR, XRD, Raman spectroscopy, and FESEM-EDS confirmed the uniform dispersion of reinforcements and successful phase integration. Tribological performance was assessed under dry sliding conditions against a Si3N4 ball at room temperature, with results showing a significant reduction in both the friction coefficient and specific wear rate upon the addition of graphene and MXene. The composite containing 2.0 wt.% MXene (NG1M2.0) exhibited the best performance, achieving a ~61% reduction in the friction coefficient and an ~85% decrease in wear rate compared to pure nickel. Enhanced performance was attributed to the formation of stable tribo- and transfer films, which minimized direct contact and wear. These findings highlight the promising potential of Nickel-Graphene-MXene composites for advanced applications requiring superior wear resistance and mechanical durability.
Keywords
References (32)
- Khan F, Hossain N, Mim JJ, Rahman SM, Iqbal MJ, Billah M, et al. Advances of composite materials in automobile applications – A review. Journal of Engineering Research. 2025;13(2):1001-1023. doi:10.1016/j.jer.2024.02.017
- Sharma M, Babu DV, Gour M, Anandhan A, Kumar S, K JGL. Design and Characterization of High-Performance Polymer Nanocomposites for Aerospace Applications. J Polym Compos. 2025;13:178–93.
- Nautiyal H, Singh S, Gautam RKS, Goswami RN, Khatri OP, Verma P, et al. The state of art on lubrication methods in space environment. Physica Scripta. 2024;99(2):022003. doi:10.1088/1402-4896/ad1d3e
- Gautam RKS, Tripathi VM, Gautam JK, Singhania S, Singh S, Jha P, et al. Elevated temperature tribological assessment of Ni-based cermet self-lubricating coatings deposited by cold spray. Surface and Coatings Technology. 2024;477:130380. doi:10.1016/j.surfcoat.2024.130380
- John M, Menezes PL. Self-Lubricating Materials for Extreme Condition Applications. Materials. 2021;14(19):5588. doi:10.3390/ma14195588
- Holmberg K, Erdemir A. Influence of tribology on global energy consumption, costs and emissions. Friction. 2017;5(3):263-284. doi:10.1007/s40544-017-0183-5
- Erdemir A, Ramirez G, Eryilmaz OL, Narayanan B, Liao Y, Kamath G, et al. Carbon-based tribofilms from lubricating oils. Nature. 2016;536(7614):67-71. doi:10.1038/nature18948
- Berman D, Deshmukh SA, Sankaranarayanan SKRS, Erdemir A, Sumant AV. Macroscale superlubricity enabled by graphene nanoscroll formation. Science. 2015;348(6239):1118-1122. doi:10.1126/science.1262024
- Dwivedi N, Ott AK, Sasikumar K, Dou C, Yeo RJ, Narayanan B, et al. Graphene overcoats for ultra-high storage density magnetic media. Nature Communications. 2021;12(1). doi:10.1038/s41467-021-22687-y
- Dwivedi N, Neogi A, Patra TK, Dhand C, Dutta T, Yeo RJ, et al. Angstrom-Scale Transparent Overcoats: Interfacial Nitrogen-Driven Atomic Intermingling Promotes Lubricity and Surface Protection of Ultrathin Carbon. Nano Letters. 2021;21(21):8960-8969. doi:10.1021/acs.nanolett.1c01997
- Bharti P, Sunkara SV, Vishwakarma J, Jaiswal S, Dhand C, Kumar R, et al. Simultaneous Control of Sliding Contact and Oxidation via Graphene-Based Materials. ACS Applied Engineering Materials. 2023;1(8):2062-2074. doi:10.1021/acsaenm.3c00222
- Lee C, Li Q, Kalb W, Liu XZ, Berger H, Carpick RW, et al. Frictional Characteristics of Atomically Thin Sheets. Science. 2010;328(5974):76-80. doi:10.1126/science.1184167
- Bharti P, Neogi A, Sharma R, Dhand C, Kumar R, Kumar P, et al. Decision trees within 1D/2D material systems for enabling highly lubricious and wear resistant surfaces. Carbon. 2024;217:118603. doi:10.1016/j.carbon.2023.118603
- Mukhtar F, Munawar T, Nadeem MS, ur Rehman MN, Mahmood K, Batool S, et al. Enhancement in carrier separation of ZnO-Ho2O3-Sm2O3 hetrostuctured nanocomposite with rGO and PANI supported direct dual Z-scheme for antimicrobial inactivation and sunlight driven photocatalysis. Advanced Powder Technology. 2021;32(10):3770-3787. doi:10.1016/j.apt.2021.08.022
- Munawar T, Mukhtar F, Nadeem MS, Mahmood K, Hasan M, Hussain A, et al. Novel direct dual-Z-scheme ZnO-Er2O3-Nd2O3@reduced graphene oxide heterostructured nanocomposite: Synthesis, characterization and superior antibacterial and photocatalytic activity. Materials Chemistry and Physics. 2020;253:123249. doi:10.1016/j.matchemphys.2020.123249
- Berman D, Erdemir A, Sumant AV. Graphene: a new emerging lubricant. Materials Today. 2014;17(1):31-42. doi:10.1016/j.mattod.2013.12.003
- Zeng X, Peng Y, Lang H. A novel approach to decrease friction of graphene. Carbon. 2017;118:233-240. doi:10.1016/j.carbon.2017.03.042
- Patil SJ, Gawande GD, Khairnar Y, Sharma M, Patil MK. Graphene-Polymer Nanocomposites for Drug Delivery Applications. J Polym Compos. 2025;13:362–74.
- Rosenkranz A, Liu Y, Yang L, Chen L. 2D nano-materials beyond graphene: from synthesis to tribological studies. Applied Nanoscience. 2020;10(9):3353-3388. doi:10.1007/s13204-020-01466-z
- Berman D, Narayanan B, Cherukara MJ, Sankaranarayanan SKRS, Erdemir A, Zinovev A, et al. Operando tribochemical formation of onion-like-carbon leads to macroscale superlubricity. Nature Communications. 2018;9(1). doi:10.1038/s41467-018-03549-6
- Berman D, Erdemir A, Sumant AV. Approaches for Achieving Superlubricity in Two-Dimensional Materials. ACS Nano. 2018;12(3):2122-2137. doi:10.1021/acsnano.7b09046
- Naguib M, Kurtoglu M, Presser V, Lu J, Niu J, Heon M, et al. Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2. Advanced Materials. 2011;23(37):4248-4253. doi:10.1002/adma.201102306
- Naguib M, Mochalin VN, Barsoum MW, Gogotsi Y. 25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials. Advanced Materials. 2013;26(7):992-1005. doi:10.1002/adma.201304138
- Zhang H, Wang L, Chen Q, Li P, Zhou A, Cao X, et al. Preparation, mechanical and anti-friction performance of MXene/polymer composites. Materials & Design. 2016;92:682-689. doi:10.1016/j.matdes.2015.12.084
- Zhou X, Guo Y, Wang D, Xu Q. Nano friction and adhesion properties on Ti3C2 and Nb2C MXene studied by AFM. Tribology International. 2021;153:106646. doi:10.1016/j.triboint.2020.106646
- Huang S, Mochalin VN. Understanding Chemistry of Two-Dimensional Transition Metal Carbides and Carbonitrides (MXenes) with Gas Analysis. ACS Nano. 2020;14(8):10251-10257. doi:10.1021/acsnano.0c03602
- Natu V, Hart JL, Sokol M, Chiang H, Taheri ML, Barsoum MW. Edge Capping of 2D‐MXene Sheets with Polyanionic Salts To Mitigate Oxidation in Aqueous Colloidal Suspensions. Angewandte Chemie International Edition. 2019;58(36):12655-12660. doi:10.1002/anie.201906138
- Yan Z, Shi X, Huang Y, Deng X, Yang K, Liu X. Tribological Performance of Ni3Al Matrix Self-Lubricating Composites Containing Multilayer Graphene and Ti3SiC2 at Elevated Temperatures. Journal of Materials Engineering and Performance. 2017;26(9):4605-4614. doi:10.1007/s11665-017-2907-0
- Petrus M, Woźniak J, Cygan T, Lachowski A, Moszczyńska D, Adamczyk-Cieślak B, et al. Influence of Ti3C2Tx MXene and Surface-Modified Ti3C2Tx MXene Addition on Microstructure and Mechanical Properties of Silicon Carbide Composites Sintered via Spark Plasma Sintering Method. Materials. 2021;14(13):3558. doi:10.3390/ma14133558
- Singh S, Han T, Chen X, Zhang C. Fabrication and assessment of dry sliding behavior of Ti3C2Tx-MXene reinforced nickel aluminide composites. Tribology International. 2024;200:110131. doi:10.1016/j.triboint.2024.110131
- E28 Committee. Test Methods for Vickers Hardness and Knoop Hardness of Metallic Materials. doi:10.1520/e0092-23
- G02 Committee. Test Method for Wear Testing with a Pin-on-Disk Apparatus. doi:10.1520/g0099-23