Journal of Polymer & Composites Original Research Open Access

Hybrid Supercapacitor Application for Future E-mobility

  1. Amit Pal Department of Mechanical Engineering, Delhi Technological University
  2. Manish Mishra Mechanical Engineering, Delhi Technological University
  3. Amrish K. Panwar Department of Applied Physics, Delhi Technological University

Abstract

With the rise in demand for automobiles, there is an increase in pollution levels and global warming since the past decade, there is a strong need for an alternative mode of commuting like Electric vehicles against conventional gasoline/diesel-powered vehicles to safeguard the planet and its flora and fauna. Battery technology like lithium-ion and others has already revolutionized the automotive world, but there is a limitation of fast charging, operating temperature range, and low cycle life due to degradation in the battery because of chemical reactions associated with each charge and discharge cycle. This aging or degradation minimizes operating life, slow charge/discharge process due to electrochemical reactions involved, low safety rating, usage of rare earth elements like cobalt, nickel, and lithium, etc. contributed to the extraordinary cost of LIBs system. These factors are major challenges that are hindering electric vehicle acceptance widely. Against other energy storage devices, supercapacitors and BSHs can be the potential alternatives in the domain of energy storage systems for future mobility which can address all the battery concerns. However, low specific energy is the prime concern that is required to optimize to maximize the higher range of EVs. This paper deals with types of supercapacitors and battery-type super hybrid capacitors (BSHs), it’s working, along with factors influencing specific energy of supercapacitor/BSHs by improving specific capacitance and their operating voltage, also the adoption of alternate biodegradable, abundant materials for bringing down the cost of BSHs. The main goal of the study is to present BSHs as the best alternative for future mobility, having the best of LIBs and supercapacitor benefits, also brief information about the scope for the usage of alternate materials for electrodes and electrolytes for offsetting the higher cost of raw materials like lithium, graphene, etc.

Keywords

References (80)

  1. Armand M, Tarascon JM. Building better batteries. Nature. 2008;451(7179):652-657. doi:10.1038/451652a
  2. Miller JR, Simon P. Electrochemical Capacitors for Energy Management. Science. 2008;321(5889):651-652. doi:10.1126/science.1158736
  3. Bonaccorso F, Colombo L, Yu G, Stoller M, Tozzini V, Ferrari AC, et al. Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage. Science. 2015;347(6217). doi:10.1126/science.1246501
  4. Li W, Zeng L, Wu Y, Yu Y. Nanostructured electrode materials for lithium-ion and sodium-ion batteries via electrospinning. Sci China Mater. 2016; 59(4): 287–321. doi:10.1007/s40843–016–5039–6.
  5. Wang G, Zhang L, Zhang J. A review of electrode materials for electrochemical supercapacitors. Chemical Society Reviews. 2012;41(2):797-828. doi:10.1039/c1cs15060j
  6. Wang B. Supercapacitors Game Changing Improvement on Energy Density Compared to Batteries; 2017. Available from: http://www.nextbigfuture.com.
  7. Keenan M. Avnet Abacus: Hybrid capacitors combine the best of both worlds, Power Electronics/Power Management 2020.
  8. Yan J, Wang Q, Wei T, Fan Z. Recent Advances in Design and Fabrication of Electrochemical Supercapacitors with High Energy Densities. Advanced Energy Materials. 2013;4(4). doi:10.1002/aenm.201300816
  9. Wu S, Zhu Y. Highly densified carbon electrode materials towards practical supercapacitor devices. Sci China Mater. 2017; 60(1): 25–38. doi:10.1007/s40843–016–5109–4.
  10. Conway BE. Electrochemical supercapacitors: scientific fundamentals and technological applications. New York: Kluwer Publishers-Plenum; 1999.
  11. Conway BE. Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage. Journal of The Electrochemical Society. 1991;138(6):1539-1548. doi:10.1149/1.2085829
  12. Conway BE, Birss V, et al. The role and utilization of pseudo capacitance for energy storage by supercapacitors. J Power Sources. 1997; 66(1–2): 1–14.
  13. Kim IH, Kim KB. Ruthenium Oxide Thin Film Electrodes for Supercapacitors. Electrochemical and Solid-State Letters. 2001;4(5):A62. doi:10.1149/1.1359956
  14. Mastragostino MC Arbizzani, et al.: Polymer-based supercapacitors. J Power Sources. 2001:97–8, 812–5.
  15. Ryu KS, Kim KM, Park NG, Park YJ, Chang SH. Symmetric redox supercapacitor with conducting polyaniline electrodes. Journal of Power Sources. 2002;103(2):305-309. doi:10.1016/s0378-7753(01)00862-x
  16. Béguin F, Presser V, Balducci A, Frackowiak E. Carbons and Electrolytes for Advanced Supercapacitors. Advanced Materials. 2014;26(14):2219-2251. doi:10.1002/adma.201304137
  17. Hao L, Li X, Zhi L. Carbonaceous Electrode Materials for Supercapacitors. Advanced Materials. 2013;25(28):3899-3904. doi:10.1002/adma.201301204
  18. Largeot C, Portet C, Chmiola J, Taberna PL, Gogotsi Y, Simon P. Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor. Journal of the American Chemical Society. 2008;130(9):2730-2731. doi:10.1021/ja7106178
  19. Simon P, Gogotsi Y. Materials for electrochemical capacitors. Nature Materials. 2008;7(11):845-854. doi:10.1038/nmat2297
  20. Zhu Y, Murali S, Stoller MD, Ganesh KJ, Cai W, Ferreira PJ, et al. Carbon-Based Supercapacitors Produced by Activation of Graphene. Science. 2011;332(6037):1537-1541. doi:10.1126/science.1200770
  21. Hou J, Cao T, Idrees F, Cao C. A co-sol-emulsion-gel synthesis of tunable and uniform hollow carbon nanospheres with interconnected mesoporous shells. Nanoscale. 2016;8(1):451-457. doi:10.1039/c5nr06279a
  22. Xu J, Tan Z, Zeng W, Chen G, Wu S, Zhao Y, et al. A Hierarchical Carbon Derived from Sponge‐Templated Activation of Graphene Oxide for High‐Performance Supercapacitor Electrodes. Advanced Materials. 2016;28(26):5222-5228. doi:10.1002/adma.201600586
  23. Kim T, Jung G, Yoo S, Suh KS, Ruoff RS. Activated Graphene-Based Carbons as Supercapacitor Electrodes with Macro- and Mesopores. ACS Nano. 2013;7(8):6899-6905. doi:10.1021/nn402077v
  24. Sevilla M, Fuertes AB. Direct Synthesis of Highly Porous Interconnected Carbon Nanosheets and Their Application as High-Performance Supercapacitors. ACS Nano. 2014;8(5):5069-5078. doi:10.1021/nn501124h
  25. Wang H, Xu Z, Kohandehghan A, Li Z, Cui K, Tan X, et al. Interconnected Carbon Nanosheets Derived from Hemp for Ultrafast Supercapacitors with High Energy. ACS Nano. 2013;7(6):5131-5141. doi:10.1021/nn400731g
  26. Xu Y, Lin Z, Zhong X, Huang X, Weiss NO, Huang Y, et al. Holey graphene frameworks for highly efficient capacitive energy storage. Nature Communications. 2014;5(1). doi:10.1038/ncomms5554
  27. Li Y, Li Z, Shen PK. Simultaneous Formation of Ultrahigh Surface Area and Three‐Dimensional Hierarchical Porous Graphene‐Like Networks for Fast and Highly Stable Supercapacitors. Advanced Materials. 2013;25(17):2474-2480. doi:10.1002/adma.201205332
  28. Lin T, Chen IW, Liu F, Yang C, Bi H, Xu F, et al. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science. 2015;350(6267):1508-1513. doi:10.1126/science.aab3798
  29. Chen LF, Zhang XD, Liang HW, Kong M, Guan QF, Chen P, et al. Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors. ACS Nano. 2012;6(8):7092-7102. doi:10.1021/nn302147s
  30. Xia W, Qu C, Liang Z, Zhao B, Dai S, Qiu B, et al. High-Performance Energy Storage and Conversion Materials Derived from a Single Metal–Organic Framework/Graphene Aerogel Composite. Nano Letters. 2017;17(5):2788-2795. doi:10.1021/acs.nanolett.6b05004
  31. Zhang W, Xu C, Ma C, Li G, Wang Y, Zhang K, et al. Nitrogen‐Superdoped 3D Graphene Networks for High‐Performance Supercapacitors. Advanced Materials. 2017;29(36). doi:10.1002/adma.201701677
  32. Qie L, Chen W, Xu H, Xiong X, Jiang Y, Zou F, et al. Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors. Energy & Environmental Science. 2013;6(8):2497. doi:10.1039/c3ee41638k
  33. Zhong M, Kim EK, McGann JP, Chun SE, Whitacre JF, Jaroniec M, et al. Electrochemically Active Nitrogen-Enriched Nanocarbons with Well-Defined Morphology Synthesized by Pyrolysis of Self-Assembled Block Copolymer. Journal of the American Chemical Society. 2012;134(36):14846-14857. doi:10.1021/ja304352n
  34. Guo DC, Mi J, Hao GP, Dong W, Xiong G, Li WC, et al. Ionic liquid C 16 mimBF 4 assisted synthesis of poly(benzoxazine-co-resol)-based hierarchically porous carbons with superior performance in supercapacitors. Energy Environ. Sci. 2013;6(2):652-659. doi:10.1039/c2ee23127a
  35. Hou J, Cao C, Idrees F, Ma X. Hierarchical Porous Nitrogen-Doped Carbon Nanosheets Derived from Silk for Ultrahigh-Capacity Battery Anodes and Supercapacitors. ACS Nano. 2015;9(3):2556-2564. doi:10.1021/nn506394r
  36. Qian W, Sun F, Xu Y, Qiu L, Liu C, Wang S, et al. Human hair-derived carbon flakes for electrochemical supercapacitors. Energy Environ. Sci. 2014;7(1):379-386. doi:10.1039/c3ee43111h
  37. Hou J, Cao C, Ma X, Idrees F, Xu B, Hao X, et al. From Rice Bran to High Energy Density Supercapacitors: A New Route to Control Porous Structure of 3D Carbon. Scientific Reports. 2014;4(1). doi:10.1038/srep07260
  38. Zhu J, Shan Y, Wang T, Sun H, Zhao Z, Mei L, et al. A hyperaccumulation pathway to three-dimensional hierarchical porous nanocomposites for highly robust high-power electrodes. Nature Communications. 2016;7(1). doi:10.1038/ncomms13432
  39. Kang D, Liu Q, Gu J, Su Y, Zhang W, Zhang D. “Egg-Box”-Assisted Fabrication of Porous Carbon with Small Mesopores for High-Rate Electric Double Layer Capacitors. ACS Nano. 2015;9(11):11225-11233. doi:10.1021/acsnano.5b04821
  40. Chen C, Zhang Y, Li Y, Dai J, Song J, Yao Y, et al. All-wood, low tortuosity, aqueous, biodegradable supercapacitors with ultra-high capacitance. Energy & Environmental Science. 2017;10(2):538-545. doi:10.1039/c6ee03716j
  41. Biswal M, Banerjee A, Deo M, Ogale S. From dead leaves to high energy density supercapacitors. Energy & Environmental Science. 2013;6(4):1249. doi:10.1039/c3ee22325f
  42. Zhao Y, Liu J, Horn M, Motta N, Hu M, Li Y. Recent advancements in metal organic framework-based electrodes for supercapacitors. Sci China Mater. 2018; 61(2): 159–84. doi:10.1007/s40843–017–9153-x.
  43. Sheberla D, Bachman JC, Elias JS, Sun CJ, Shao-Horn Y, Dincă M. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nature Materials. 2016;16(2):220-224. doi:10.1038/nmat4766
  44. Hou J, Jiang K, Tahir M, Wu X, Idrees F, Shen M, et al. Tunable porous structure of carbon nanosheets derived from puffed rice for high energy density supercapacitors. Journal of Power Sources. 2017;371:148-155. doi:10.1016/j.jpowsour.2017.10.045
  45. Wu Y, Cao C. The way to improve the energy density of supercapacitors: Progress and perspective. Science China Materials. 2018;61(12):1517-1526. doi:10.1007/s40843-018-9290-y
  46. Hou J, Jiang K, Wei R, Tahir M, Wu X, Shen M, et al. Popcorn-Derived Porous Carbon Flakes with an Ultrahigh Specific Surface Area for Superior Performance Supercapacitors. ACS Applied Materials & Interfaces. 2017;9(36):30626-30634. doi:10.1021/acsami.7b07746
  47. Khalid S, Cao C, Wang L, Zhu Y. Microwave Assisted Synthesis of Porous NiCo2O4 Microspheres: Application as High Performance Asymmetric and Symmetric Supercapacitors with Large Areal Capacitance. Scientific Reports. 2016;6(1). doi:10.1038/srep22699
  48. Mahmood N, Tahir M, Mahmood A, Zhu J, Cao C, Hou Y. Chlorine-doped carbonated cobalt hydroxide for supercapacitors with enormously high pseudocapacitive performance and energy density. Nano Energy. 2015;11:267-276. doi:10.1016/j.nanoen.2014.11.015
  49. Ali Z, Tahir M, Cao C, Mahmood A, Mahmood N, Butt FK, et al. Solid waste for energy storage material as electrode of supercapacitors. Materials Letters. 2016;181:191-195. doi:10.1016/j.matlet.2016.05.159
  50. Salunkhe RR, Kaneti YV, Yamauchi Y. Metal–Organic Framework-Derived Nanoporous Metal Oxides toward Supercapacitor Applications: Progress and Prospects. ACS Nano. 2017;11(6):5293-5308. doi:10.1021/acsnano.7b02796
  51. Idrees F, Hou J, Cao C, Butt FK, Shakir I, Tahir M, et al. Template-free synthesis of highly ordered 3D-hollow hierarchical Nb 2 O 5 superstructures as an asymmetric supercapacitor by using inorganic electrolyte. Electrochimica Acta. 2016;216:332-338. doi:10.1016/j.electacta.2016.09.031
  52. Zhang X, Zhang H, Lin Z, Yu M, Lu X, Tong Y. Recent advances and challenges of stretchable supercapacitors based on carbon materials. Sci China Mater. 2016; 59(6): 475–94. doi:10.1007/s40843–016–5061–1.
  53. Hao J, Peng S, Qin T, Wang Z, Wen Y, He D, et al. Fabrication of hybrid Co3O4/NiCo2O4 nanosheets sandwiched by nanoneedles for high-performance supercapacitors using a novel electrochemical ion exchange. Sci China Mater. 2017; 60(12): 1168–78. doi:10.1007/s40843–017–9139–8.
  54. Khalid S, Cao C, Wang L, Zhu Y, Wu Y. A high performance solid state asymmetric supercapacitor device based upon NiCo 2 O 4 nanosheets//MnO 2 microspheres. RSC Advances. 2016;6(74):70292-70302. doi:10.1039/c6ra15420d
  55. Zhu Y, Cao C, Tao S, Chu W, Wu Z, Li Y. Ultrathin Nickel Hydroxide and Oxide Nanosheets: Synthesis, Characterizations and Excellent Supercapacitor Performances. Scientific Reports. 2014;4(1). doi:10.1038/srep05787
  56. Khalid S, Cao C, Naveed M, Younas W. 3D hierarchical MnO 2 microspheres: a prospective material for high performance supercapacitors and lithium-ion batteries. Sustainable Energy & Fuels. 2017;1(8):1795-1804. doi:10.1039/c7se00317j
  57. Zheng C, Cao C, Chang R, Hou J, Zhai H. Hierarchical mesoporous NiCo2O4 hollow nanocubes for supercapacitors. Phys Chem Chem Phys. 2016; 18(8): 6268–74. doi:10.1039/C5CP07997G.
  58. Khalid S, Cao C, Ahmad A, Wang L, Tanveer M, Aslam I, et al. Microwave assisted synthesis of mesoporous NiCo 2 O 4 nanosheets as electrode material for advanced flexible supercapacitors. RSC Advances. 2015;5(42):33146-33154. doi:10.1039/c5ra02180d
  59. Choudhary N, Li C, Moore J, Nagaiah N, Zhai L, Jung Y, et al. Asymmetric Supercapacitor Electrodes and Devices. Advanced Materials. 2017;29(21). doi:10.1002/adma.201605336
  60. Zheng M, Xiao X, Li L, Gu P, Dai X, Tang H, et al. Hierarchically nanostructured transition metal oxides for supercapacitors. Science China Materials. 2017;61(2):185-209. doi:10.1007/s40843-017-9095-4
  61. Yan J, Fan Z, Sun W, Ning G, Wei T, Zhang Q, et al. Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density. Advanced Functional Materials. 2012;22(12):2632-2641. doi:10.1002/adfm.201102839
  62. Owusu KA, Qu L, Li J, Wang Z, Zhao K, Yang C, et al. Low-crystalline iron oxide hydroxide nanoparticle anode for high-performance supercapacitors. Nature Communications. 2017;8(1). doi:10.1038/ncomms14264
  63. Boruah BD, Misra A. Internal Asymmetric Tandem Supercapacitor for High Working Voltage along with Superior Rate Performance. ACS Energy Letters. 2017;2(8):1720-1728. doi:10.1021/acsenergylett.7b00379
  64. Kim M, Kim J. Development of high power and energy density microsphere silicon carbide–MnO2 nanoneedles and thermally oxidized activated carbon asymmetric electrochemical supercapacitors. Physical Chemistry Chemical Physics. 2014;16(23):11323. doi:10.1039/c4cp01141d
  65. Qiu Y, Li G, Hou Y, Pan Z, Li H, Li W, et al. Vertically Aligned Carbon Nanotubes on Carbon Nanofibers: A Hierarchical Three-Dimensional Carbon Nanostructure for High-Energy Flexible Supercapacitors. Chemistry of Materials. 2015;27(4):1194-1200. doi:10.1021/cm503784x
  66. Liu C, Yu Z, Neff D, Zhamu A, Jang BZ. Graphene-Based Supercapacitor with an Ultrahigh Energy Density. Nano Letters. 2010;10(12):4863-4868. doi:10.1021/nl102661q
  67. Hwang JY, El-Kady MF, Wang Y, Wang L, Shao Y, Marsh K, et al. Direct preparation and processing of graphene/RuO2 nanocomposite electrodes for high-performance capacitive energy storage. Nano Energy. 2015;18:57-70. doi:10.1016/j.nanoen.2015.09.009
  68. Wu ZS, Ren W, Wang DW, Li F, Liu B, Cheng HM. High-Energy MnO2 Nanowire/Graphene and Graphene Asymmetric Electrochemical Capacitors. ACS Nano. 2010;4(10):5835-5842. doi:10.1021/nn101754k
  69. Ji J, Zhang LL, Ji H, Li Y, Zhao X, Bai X, et al. Nanoporous Ni(OH)2 Thin Film on 3D Ultrathin-Graphite Foam for Asymmetric Supercapacitor. ACS Nano. 2013;7(7):6237-6243. doi:10.1021/nn4021955
  70. Zuo W, Li R, Zhou C, Li Y, Xia J, Liu J. Battery‐Supercapacitor Hybrid Devices: Recent Progress and Future Prospects. Advanced Science. 2017;4(7). doi:10.1002/advs.201600539
  71. Li B, Dai F, Xiao Q, Yang L, Shen J, Zhang C, et al. Nitrogen-doped activated carbon for a high energy hybrid supercapacitor. Energy & Environmental Science. 2016;9(1):102-106. doi:10.1039/c5ee03149d
  72. Lim E, Jo C, Kim H, Kim MH, Mun Y, Chun J, et al. Facile Synthesis of Nb2O5@Carbon Core–Shell Nanocrystals with Controlled Crystalline Structure for High-Power Anodes in Hybrid Supercapacitors. ACS Nano. 2015;9(7):7497-7505. doi:10.1021/acsnano.5b02601
  73. Wang YG, Luo JY, Wang CX, Xia YY. Hybrid Aqueous Energy Storage Cells Using Activated Carbon and Lithium-Ion Intercalated Compounds. Journal of The Electrochemical Society. 2006;153(8):A1425. doi:10.1149/1.2203772
  74. Shen L, Lv H, Chen S, Kopold P, van Aken PA, Wu X, et al. Peapod‐like Li3VO4/N‐Doped Carbon Nanowires with Pseudocapacitive Properties as Advanced Materials for High‐Energy Lithium‐Ion Capacitors. Advanced Materials. 2017;29(27). doi:10.1002/adma.201700142
  75. Sun Y, Tang J, Qin F, Yuan J, Zhang K, Li J, et al. Hybrid lithium-ion capacitors with asymmetric graphene electrodes. Journal of Materials Chemistry A. 2017;5(26):13601-13609. doi:10.1039/c7ta01113j
  76. Ding J, Wang H, Li Z, Cui K, Karpuzov D, Tan X, et al. Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors. Energy & Environmental Science. 2015;8(3):941-955. doi:10.1039/c4ee02986k
  77. Jabeen N, Hussain A, Xia Q, Sun S, Zhu J, Xia H. High‐Performance 2.6 V Aqueous Asymmetric Supercapacitors based on In Situ Formed Na0.5MnO2 Nanosheet Assembled Nanowall Arrays. Advanced Materials. 2017;29(32). doi:10.1002/adma.201700804
  78. Guoshen Yang Jialei H, Wan Xuhao, Zhu Y, Liu B, et al. A low cost, wide temperature range, and high energy density flexible quasi-solid-state zinc-ion hybrid supercapacitors enabled by sustainable cathode and electrolyte design. Nano Energy;90(A). doi: 10.6500(2021).
  79. Wang S, Li T, Yin Y, Chang N, Zhang H, Li X. High-energy-density aqueous zinc-based hybrid supercapacitor-battery with uniform zinc deposition achieved by multifunctional decoupled additive. Nano Energy. 2022;96:107120. doi:10.1016/j.nanoen.2022.107120
  80. Peng S, Li L, Wu HB, Madhavi S, Lou XWD. Controlled Growth of NiMoO4 Nanosheet and Nanorod Arrays on Various Conductive Substrates as Advanced Electrodes for Asymmetric Supercapacitors. Advanced Energy Materials. 2014;5(2). doi:10.1002/aenm.201401172
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