International Journal of Crystalline Materials Original Research
Self-Healing Thin Films: Paving the Way for Smart, and Sustainable Corrosion Protection
Abstract
Corrosion is one of the serious problems that industries and infrastructures of every type face, ranked among such threats as huge economic losses and concerns to global safety. Recent developments in the area of self-healing thin films make them a really promising innovation for enhancing corrosion protection. This review considers the development, mechanisms, and applications of self-healing thin films. Detailed here are intrinsic and extrinsic self-healing strategies oriented toward chemical and physical mechanisms realizing autonomous repair. It covers in detail current fabrication methods, such as layer-by-layer assembly and sol-gel techniques, and surface enhancement and application methodologies like spraying and dip- coating. Case studies demonstrate the successful application of self-healing coatings in the marine and automotive industries, among others. The review further discusses performance evaluation techniques of corrosion resistance and self-healing efficacy, including standard and novel testing methods. While discussing the improvement in properties and functions of self-healing materials, a focus has been put on the development in nanotechnology and biotechnology. The discussion finally extends to future prospects and emerging trends and possible amalgamation of smart coatings with IoT for real-time monitoring. The review also addressed formulation, application, durability, environmental stability, and economic issues. It concludes with reflections on the transformative power of self-healing technologies in materials science and engineering and provides insights into commercialization and industrial adoption.
Keywords
References (86)
- Khan MAA, Irfan OM, Djavanroodi F, Asad M. Development of Sustainable Inhibitors for Corrosion Control. Sustainability. 2022;14(15):9502. doi:10.3390/su14159502
- Nzerem P, Adeleke AA, Salihu A, Anosike-Francis EN, Samuel AA, Olosho AI, et al. Green Corrosion Inhibition Practices. 2023 2nd International Conference on Multidisciplinary Engineering and Applied Science (ICMEAS). 2023:1-4. doi:10.1109/icmeas58693.2023.10429885
- Alamri AH. Localized corrosion and mitigation approach of steel materials used in oil and gas pipelines – An overview. Engineering Failure Analysis. 2020;116:104735. doi:10.1016/j.engfailanal.2020.104735
- Hossain N, Asaduzzaman Chowdhury M, Kchaou M. An overview of green corrosion inhibitors for sustainable and environment friendly industrial development. Journal of Adhesion Science and Technology. 2020;35(7):673-690. doi:10.1080/01694243.2020.1816793
- Ionescu GC, Ionescu GL, Marin L. Modern Theoretical and Practical Protection Methods of Metallic Structures Against the Effects of Corrosion. Journal of Applied Engineering Sciences. 2024;14(1):97-102. doi:10.2478/jaes-2024-0012
- Zhang F, Ju P, Pan M, Zhang D, Huang Y, Li G, et al. Self-healing mechanisms in smart protective coatings: A review. Corrosion Science. 2018;144:74-88. doi:10.1016/j.corsci.2018.08.005
- Gautam BR, Khan NI, Gosvami NN, Das S. Recent advancements in self-healing materials and their application in coating industry. Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications. 2024;239(3):411-427. doi:10.1177/14644207241269558
- Habib S, Shakoor RA, Kahraman R. A focused review on smart carriers tailored for corrosion protection: Developments, applications, and challenges. Progress in Organic Coatings. 2021;154:106218. doi:10.1016/j.porgcoat.2021.106218
- Ataei S, Khorasani SN, Neisiany RE. Biofriendly vegetable oil healing agents used for developing self-healing coatings: A review. Progress in Organic Coatings. 2019;129:77-95. doi:10.1016/j.porgcoat.2019.01.012
- Ananthapadmanabhan S, Mishra G, Parida S. A brief review on the development of self-healing, hydrophobic and antifouling epoxy coating. J Metall Mater Sci. 2020;66:1-15.
- Bednarczyk P, Mozelewska K, Klebeko J, Rokicka J, Ossowicz-Rupniewska P. Impact of the Chemical Structure of Photoreactive Urethane (Meth)Acrylates with Various (Meth)Acrylate Groups and Built-In Diels–Alder Reaction Adducts on the UV-Curing Process and Self-Healing Properties. Polymers. 2023;15(4):924. doi:10.3390/polym15040924
- Odarczenko M, Thakare D, Li W, Venkateswaran SP, Sottos NR, White SR. Sunlight‐Activated Self‐Healing Polymer Coatings. Advanced Engineering Materials. 2019;22(3). doi:10.1002/adem.201901223
- Wen J, Lei J, Chen J, Liu L, Zhang X, Li L. Polyethylenimine wrapped mesoporous silica loaded benzotriazole with high pH-sensitivity for assembling self-healing anti-corrosive coatings. Materials Chemistry and Physics. 2020;253:123425. doi:10.1016/j.matchemphys.2020.123425
- Huang J, Zhang J, Zhu G, Yu X, Hu Y, Shang Q, et al. Self-healing, high-performance, and high-biobased-content UV-curable coatings derived from rubber seed oil and itaconic acid. Progress in Organic Coatings. 2021;159:106391. doi:10.1016/j.porgcoat.2021.106391
- Yu X, Hu Y, Lei W, Liu C, Zhou Y. Development of Catalyst-Free Self-Healing Biobased UV-Curable Coatings via Maleate Monoester Transesterification. Coatings. 2023;13(1):110. doi:10.3390/coatings13010110
- Irzhak VI, Uflyand IE, Dzhardimalieva GI. Self-Healing of Polymers and Polymer Composites. Polymers. 2022;14(24):5404. doi:10.3390/polym14245404
- Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR, White SR. Self-Healing Polymers and Composites. Annual Review of Materials Research. 2010;40(1):179-211. doi:10.1146/annurev-matsci-070909-104532
- El Choufi N, Mustapha S, Tehrani B. A, Grady BP. An Overview of Self‐Healable Polymers and Recent Advances in the Field. Macromolecular Rapid Communications. 2022;43(17). doi:10.1002/marc.202200164
- Choong PS, Chong NX, Wai Tam EK, Seayad AM, Seayad J, Jana S. Biobased Nonisocyanate Polyurethanes as Recyclable and Intrinsic Self-Healing Coating with Triple Healing Sites. ACS Macro Letters. 2021;10(5):635-641. doi:10.1021/acsmacrolett.1c00163
- Pulikkalparambil H, Siengchin S, Parameswaranpillai J. Corrosion protective self-healing epoxy resin coatings based on inhibitor and polymeric healing agents encapsulated in organic and inorganic micro and nanocontainers. Nano-Structures & Nano-Objects. 2018;16:381-395. doi:10.1016/j.nanoso.2018.09.010
- Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, et al. Self‐Healing Polymer Coatings Based on Crosslinked Metallosupramolecular Copolymers. Advanced Materials. 2013;25(11):1634-1638. doi:10.1002/adma.201203865
- Jang DH, Park BM, Kwon KH, Ree M, Han KY. Nanoscratch self-healing characteristics of polyvinyl polymer thin films embedded with Al2O3 nanoparticles with thermal and UV energy reactivity. Materials Today Communications. 2020;25:101375. doi:10.1016/j.mtcomm.2020.101375
- Zhong M, Liu YT, Xie XM. Self-healable, super tough graphene oxide–poly(acrylic acid) nanocomposite hydrogels facilitated by dual cross-linking effects through dynamic ionic interactions. Journal of Materials Chemistry B. 2015;3(19):4001-4008. doi:10.1039/c5tb00075k
- Schäfer S, Kickelbick G. Self-healing polymer nanocomposites based on Diels-Alder-reactions with silica nanoparticles: The role of the polymer matrix. Polymer. 2015;69:357-368. doi:10.1016/j.polymer.2015.03.017
- Froimowicz P, Klinger D, Landfester K. Photoreactive Nanoparticles as Nanometric Building Blocks for the Generation of Self‐Healing Hydrogel Thin Films. Chemistry – A European Journal. 2011;17(44):12465-12475. doi:10.1002/chem.201100685
- Riul A, de Barros A, Gaál G, Braunger ML, Martinez Jimenez MJ, Avila-Avendano C, et al. Self-Healing E-tongue. ACS Applied Materials & Interfaces. 2023;15(47):55073-55081. doi:10.1021/acsami.3c11590
- Wang S, Urban MW. Self-healing polymers. Nature Reviews Materials. 2020;5(8):562-583. doi:10.1038/s41578-020-0202-4
- Postiglione G, Turri S, Levi M. Effect of the plasticizer on the self-healing properties of a polymer coating based on the thermoreversible Diels–Alder reaction. Progress in Organic Coatings. 2015;78:526-531. doi:10.1016/j.porgcoat.2014.05.022
- Zhang H, Ma Y, Tan J, Fan X, Liu Y, Gu J, et al. Robust, self-healing, superhydrophobic coatings highlighted by a novel branched thiol-ene fluorinated siloxane nanocomposites. Composites Science and Technology. 2016;137:78-86. doi:10.1016/j.compscitech.2016.10.023
- Karaxi EK, Kartsonakis IA, Charitidis CA. Assessment of Self-Healing Epoxy-Based Coatings Containing Microcapsules Applied on Hot Dipped Galvanized Steel. Frontiers in Materials. 2019;6. doi:10.3389/fmats.2019.00222
- Chen L, Xu J, Zhu M, Zeng Z, Song Y, Zhang X, et al. Self-healing polymers through hydrogen-bond cross-linking: synthesis and electronic applications. Mater Horiz. 2023.
- Li J, Ejima H, Yoshie N. Seawater-Assisted Self-Healing of Catechol Polymers via Hydrogen Bonding and Coordination Interactions. ACS Applied Materials & Interfaces. 2016;8(29):19047-19053. doi:10.1021/acsami.6b04075
- Hao E, Lian T. Buildup of Polymer/Au Nanoparticle Multilayer Thin Films Based on Hydrogen Bonding. Chemistry of Materials. 2000;12(11):3392-3396. doi:10.1021/cm000565u
- Zheludkevich ML, Salvado IM, Ferreira MGS. Sol–gel coatings for corrosion protection of metals. Journal of Materials Chemistry. 2005;15(48):5099. doi:10.1039/b419153f
- Lamaka SV, Montemor MF, Galio AF, Zheludkevich ML, Trindade C, Dick LF, et al. Novel hybrid sol–gel coatings for corrosion protection of AZ31B magnesium alloy. Electrochimica Acta. 2008;53(14):4773-4783. doi:10.1016/j.electacta.2008.02.015
- Sheffer M, Groysman A, Starosvetsky D, Savchenko N, Mandler D. Anion embedded sol–gel films on Al for corrosion protection. Corrosion Science. 2004;46(12):2975-2985. doi:10.1016/j.corsci.2004.05.001
- Quinet M, Neveu B, Moutarlier V, Audebert P, Ricq L. Corrosion protection of sol–gel coatings doped with an organic corrosion inhibitor: Chloranil. Progress in Organic Coatings. 2007;58(1):46-53. doi:10.1016/j.porgcoat.2006.11.007
- Khelifa F, Druart ME, Habibi Y, Bénard F, Leclère P, Olivier M, et al. Sol–gel incorporation of silica nanofillers for tuning the anti-corrosion protection of acrylate-based coatings. Progress in Organic Coatings. 2013;76(5):900-911. doi:10.1016/j.porgcoat.2013.02.005
- Kong H, Luo X, Zhang P, Feng J, Li P, Hu W, et al. Self-Healing, Solvent-Free, Anti-Corrosion Coating Based on Skin-like Polyurethane/Carbon Nanotubes Composites with Real-Time Damage Monitoring. Nanomaterials. 2022;13(1):124. doi:10.3390/nano13010124
- Abbaspoor S, Ashrafi A, Abolfarsi R. Development of self-healing coatings based on ethyl cellulose micro/nano-capsules. Surface Engineering. 2018;35(3):273-280. doi:10.1080/02670844.2018.1502966
- Li B, Njuko D, Meng M, Tang A, Li Y. Designing Smart Microcapsules with Natural Polyelectrolytes to Improve Self-Healing Performance for Water-Based Polyurethane Coatings. ACS Applied Materials & Interfaces. 2022;14(47):53370-53379. doi:10.1021/acsami.2c18339
- Idumah CI, Obele CM, Emmanuel EO, Hassan A. Recently Emerging Nanotechnological Advancements in Polymer Nanocomposite Coatings for Anti-corrosion, Anti-fouling and Self-healing. Surfaces and Interfaces. 2020;21:100734. doi:10.1016/j.surfin.2020.100734
- Yabuki A. Self-Healing Coatings for Corrosion Inhibition of Metals. Modern Applied Science. 2015;9(7):214. doi:10.5539/mas.v9n7p214
- Montemor MF, Snihirova DV, Taryba MG, Lamaka SV, Kartsonakis IA, Balaskas AC, et al. Evaluation of self-healing ability in protective coatings modified with combinations of layered double hydroxides and cerium molibdate nanocontainers filled with corrosion inhibitors. Electrochimica Acta. 2012;60:31-40. doi:10.1016/j.electacta.2011.10.078
- Zhang J, Wei J, Li B, Zhao X, Zhang J. Long-term corrosion protection for magnesium alloy by two-layer self-healing superamphiphobic coatings based on shape memory polymers and attapulgite. Journal of Colloid and Interface Science. 2021;594:836-847. doi:10.1016/j.jcis.2021.03.005
- Nazeer AA, Madkour M. Potential use of smart coatings for corrosion protection of metals and alloys: A review. Journal of Molecular Liquids. 2018;253:11-22. doi:10.1016/j.molliq.2018.01.027
- Manna U, Dhar J, Nayak R, Patil S. Multilayer single-component thin films and microcapsules via covalent bonded layer-by-layer self-assembly. Chemical Communications. 2010;46(13):2250. doi:10.1039/b924240f
- Richardson JJ, Björnmalm M, Caruso F. Technology-driven layer-by-layer assembly of nanofilms. Science. 2015;348(6233). doi:10.1126/science.aaa2491
- Zhang J, Wei J, Li B, Zhao X, Zhang J. Long-term corrosion protection for magnesium alloy by two-layer self-healing superamphiphobic coatings based on shape memory polymers and attapulgite. Journal of Colloid and Interface Science. 2021;594:836-847. doi:10.1016/j.jcis.2021.03.005
- Yuan D, Solouki Bonab V, Patel A, Yilmaz T, Gross RA, Manas-Zloczower I. Design Strategy for Self-Healing Epoxy Coatings. Coatings. 2020;10(1):50. doi:10.3390/coatings10010050
- Zou Y, Fang L, Chen T, Sun M, Lu C, Xu Z. Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers. Polymers. 2018;10(5):474. doi:10.3390/polym10050474
- Zheludkevich ML, Yasakau KA, Bastos AC, Karavai OV, Ferreira MGS. On the application of electrochemical impedance spectroscopy to study the self-healing properties of protective coatings. Electrochemistry Communications. 2007;9(10):2622-2628. doi:10.1016/j.elecom.2007.08.012
- Roy N, Buhler E, Tomović Ž, Lehn J. Surface morphology and self-healing capabilities in hydrogen-bonding polymers. Chem Eur J. 2016;22(38):13513-13520. doi:10.1002/chem.201601378.
- Rao SR, Sharma R. Environmental and biological implications of nanoparticle-based self-healing coatings. Environ Sci Nano. 2018;5(2):428-439. doi:10.1039/C7EN00911H.
- Wang J, Patel A, Bonab VS. Self-healing epoxy coatings for automotive applications. Prog Org Coat. 2020;140:105510. doi:10.1016/j.porgcoat.2020.105510.
- Feng W, Patel SH, Young MY, Zunino JL, Xanthos M. Smart polymeric coatings—recent advances. Advances in Polymer Technology. 2007;26(1):1-13. doi:10.1002/adv.20083
- Jamil H, Faizan M, Adeel M, Jesionowski T, Boczkaj G, Balčiūnaitė A. Recent Advances in Polymer Nanocomposites: Unveiling the Frontier of Shape Memory and Self-Healing Properties—A Comprehensive Review. Molecules. 2024;29(6):1267. doi:10.3390/molecules29061267
- Haddadi SA, Hu S, Ghaderi S, Ghanbari A, Ahmadipour M, Pung SY, et al. Amino-Functionalized MXene Nanosheets Doped with Ce(III) as Potent Nanocontainers toward Self-Healing Epoxy Nanocomposite Coating for Corrosion Protection of Mild Steel. ACS Applied Materials & Interfaces. 2021;13(35):42074-42093. doi:10.1021/acsami.1c13055
- Thangavel G, Tan MWM, Lee PS. Advances in self-healing supramolecular soft materials and nanocomposites. Nano Convergence. 2019;6(1). doi:10.1186/s40580-019-0199-9
- Wang Z, Liang H, Yang H, Xiong L, Zhou J, Huang S, et al. UV-curable self-healing polyurethane coating based on thiol-ene and Diels-Alder double click reactions. Progress in Organic Coatings. 2019;137:105282. doi:10.1016/j.porgcoat.2019.105282
- Stankiewicz A, Szczygieł I, Szczygieł B. Self-healing coatings in anti-corrosion applications. Journal of Materials Science. 2013;48(23):8041-8051. doi:10.1007/s10853-013-7616-y
- Nesterova T, Dam-Johansen K, Pedersen LT, Kiil S. Microcapsule-based self-healing anticorrosive coatings: Capsule size, coating formulation, and exposure testing. Progress in Organic Coatings. 2012;75(4):309-318. doi:10.1016/j.porgcoat.2012.08.002
- Li B, Xue S, Mu P, Li J. Robust Self-Healing Graphene Oxide-Based Superhydrophobic Coatings for Efficient Corrosion Protection of Magnesium Alloys. ACS Applied Materials & Interfaces. 2022;14(26):30192-30204. doi:10.1021/acsami.2c06447
- Fortunato G, Marroccoli V, Corsini F, Turri S, Griffini G. A facile approach to durable, transparent and self-healing coatings with enhanced hardness based on Diels-Alder polymer networks. Progress in Organic Coatings. 2020;147:105840. doi:10.1016/j.porgcoat.2020.105840
- Habib S, Khan A, Nawaz M, Sliem M, Shakoor R, Kahraman R, et al. Self-Healing Performance of Multifunctional Polymeric Smart Coatings. Polymers. 2019;11(9):1519. doi:10.3390/polym11091519
- Makhlouf ASH, Daniels KE. Advanced Coatings for Corrosion Protection. Woodhead Publishing Series in Metals and Surface Engineering. 2015. doi:10.1016/C2013-0-19310-3.
- Yimyai T, Crespy D, Rohwerder M. Corrosion‐Responsive Self‐Healing Coatings. Advanced Materials. 2023;35(47). doi:10.1002/adma.202300101
- Wang H, Xu J, Du X, Du Z, Cheng X, Wang H. A self-healing polyurethane-based composite coating with high strength and anti-corrosion properties for metal protection. Composites Part B: Engineering. 2021;225:109273. doi:10.1016/j.compositesb.2021.109273
- Jones A, Ye M, Richards C, Hale T. Self-healing corrosion-resistant coatings. Smart Mater Struct. 2014;23(4):445-460. doi:10.1088/0964-1726/25/8/084013
- Stankiewicz A, Barker MB. Development of self-healing coatings for corrosion protection on metallic structures. Smart Materials and Structures. 2016;25(8):084013. doi:10.1088/0964-1726/25/8/084013
- Zhang J, Wei J, Li B, Zhao X, Zhang J. Long-term corrosion protection for magnesium alloy by two-layer self-healing superamphiphobic coatings based on shape memory polymers and attapulgite. Journal of Colloid and Interface Science. 2021;594:836-847. doi:10.1016/j.jcis.2021.03.005
- Lutz A, van den Berg O, Van Damme J, Verheyen K, Bauters E, De Graeve I, et al. A Shape-Recovery Polymer Coating for the Corrosion Protection of Metallic Surfaces. ACS Applied Materials & Interfaces. 2014;7(1):175-183. doi:10.1021/am505621x
- Muresan LM. Self-Healing Coatings for Corrosion Protection of Steel. Industrial Applications for Intelligent Polymers and Coatings. 2016:479-492. doi:10.1007/978-3-319-26893-4_22
- Dello Iacono S, Martone A, Amendola E. Corrosion-resistant self-healing coatings. AIP Conference Proceedings. 2018;1989:020010. doi:10.1063/1.5047764
- Zhang F, Ju P, Pan M, Zhang D, Huang Y, Li G, et al. Self-healing mechanisms in smart protective coatings: A review. Corrosion Science. 2018;144:74-88. doi:10.1016/j.corsci.2018.08.005
- Cui J, Li H, Wang Q, Yu C. A long-term stable and environmentally friendly self-healing coating. Chem Eng J. 2019;372(4):195-204. doi:10.1016/j.cej.2018.10.062
- Park BK. Self-healing Coatings for Corrosion Protection: A Review of Recent Advances. Journal of the Korean institute of surface engineering. 2014;47(5):244-251. doi:10.5695/jkise.2014.47.5.244
- Liu C, Wu H, Qiang Y, Zhao H, Wang L. Design of smart protective coatings with autonomous self-healing and early corrosion reporting properties. Corrosion Science. 2021;184:109355. doi:10.1016/j.corsci.2021.109355
- Ma J, Zhang Y, Zhao X, Wang T. Intrinsic self-healing corrosion-resistant silicone coating. ACS Appl Mater Interfaces. 2024;16(1):133-142. doi:10.1021/acsami.4c05347
- Zhang J, Zhao X, Wei J, Li B. Superhydrophobic coatings with photothermal self-healing chemical composition. Langmuir. 2021;37(24):7456-7468. doi:10.1021/acs.langmuir.1c02355
- Hao Z, Chen J, Lin M, Wang Y. Water-triggered self-healing composite coating. Polymers. 2022;14(9):Article 1847. doi:10.3390/polym14091847
- Zhao X, Wei J, Li B, Li S, Tian N, Jing L, et al. A self-healing superamphiphobic coating for efficient corrosion protection of magnesium alloy. Journal of Colloid and Interface Science. 2020;575:140-149. doi:10.1016/j.jcis.2020.04.097
- Kumar A, Stephenson LD, Murray JN. Self-healing coatings for steel. Progress in Organic Coatings. 2006;55(3):244-253. doi:10.1016/j.porgcoat.2005.11.010
- Yabuki A. Self-Healing Coatings for Corrosion Inhibition of Metals. Modern Applied Science. 2015;9(7):214. doi:10.5539/mas.v9n7p214
- Wang J, Tang L, Liu R, Zhou J. Corrosion-resistant polymeric coatings with self-healing properties. Surf Eng. 2021;37(6):563-572. doi:10.1080/02670844.2020.1877691
- Stankiewicz A, Szczygieł B. Advances in the development of self-healing anticorrosive coatings. Mater Perform. 2019;58(12):38-44. doi:10.1016/j.materperf.2019.03.008