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International Journal of Advance in Molecular Engineering Review Article

Applications of Nanomaterials in Membrane Separation for Effluent Treatment in the Textile Industry

  1. Keka Rana Department of Chemical Engineering, Haldia Institute of Technology, Haldia, Purba Medinipur

Abstract

The textile industry makes a significant contribution to economic growth. As the global population continues to increase exponentially, production rates are also on the rise to meet this growing demand. Unfortunately, this surge in production often leads to noncompliance with environmental regulations. While the textile industry supports economic development, it also contributes to serious pollution. Various dyes, such as azo dyes, Congo Red (CR), Crystal Violet, methylene blue, and methyl orange, are commonly used in textile manufacturing. These unused dyes frequently end up in effluents, polluting water bodies and soil. Furthermore, some of these dyes have carcinogenic effects, raising significant concerns among researchers. To address these issues, efforts are being made not only to remove these dyes but also to degrade them in order to mitigate the environmental problems they cause. Traditional methods such as adsorption and membrane separation have been widely used to address these serious environmental challenges, yielding notable results. However, the severity of these problems drives researchers to develop more advanced techniques aimed at improving removal efficiency. Nanomaterials play a significant role in this effort. Additionally, combining nanomaterials with membrane-based separation often enhance the effectiveness of the process. For example, titanium dioxide and graphene oxide nanocomposites integrated into polyethersulfone membranes demonstrate exceptional performance in treating raw textile wastewater. These composites exhibit better antifouling properties compared to standard virgin polyethersulfone membranes. Graphene oxide-silver nanocomposites also show remarkable outcomes in treating textile effluent. Furthermore, ceramic nanocomposite membranes are displaying promising performance in textile effluent treatment. Reports indicate that the removal efficiency is 95% for nano TiO2-bentonite ultrafiltration (UF) and nearly 100% for tight TiO2 UF. Ceramic hybrid hollow fiber membranes also show a removal efficiency of 99.3%. Therefore, nanomaterials play a decisive role in achieving remarkable treatment efficiency of textile effluent, ultimately benefiting the environment and the ecosystem, making it safer for living organisms.

Keywords

References (35)

  1. Khan M, Nizami AS, Yasar A, Musharavati F. Advancing vertical integration and circularity in the textile industry by developing a novel framework of textile sustainability index. Sustainable Futures. 2025;10:101496. doi:10.1016/j.sftr.2025.101496
  2. Marques DG, de Melo Franco Domingos J, Nolasco MA, Campos V. Textile effluent treatment using coagulation-flocculation and a hydrodynamic cavitation reactor associated with ozonation. Chemical Engineering Science. 2025;304:121094. doi:10.1016/j.ces.2024.121094
  3. Goudjil S, Guergazi S, Masmoudi T, Achour S. Effect of reactional parameters on the elimination of Congo Red by the combination of coagulation–floculation with aluminum sulfate. Desalination and Water Treatment. 2021;209:429-436. doi:10.5004/dwt.2021.26474
  4. Tang F, Wang C, Zhang L, He Z, Huang F. Sustainable transformation of waste cotton into quaternized carboxy cellulose nanocrystals enables chain-enhanced adsorption for industrial textile wastewater purification. Carbohydrate Polymers. 2026;372:124580. doi:10.1016/j.carbpol.2025.124580
  5. Khan NA, Jahan Z, Iqbal N, Niazi MB, Mehek R. Synergistic electrochemical performance of textile sludge based activated carbon with reduced graphene oxide as electrode for supercapacitor application. Waste Management. 2025;191:274-283. doi:10.1016/j.wasman.2024.11.015
  6. Jorge Garcia, Carla di Luca, Lara Lopez, Zahara M․ de Pedro, Jose A. Casas, Macarena Munoz, “Removal of textile microplastic fibers from water by photo-Fenton oxidation”, Water Research, Volume 289, Part B, 15 January 2026, 124999.
  7. El Machtani Idrissi D, Elidrissi ZC, Achiou B, Ouammou M, Alami Younssi S. Fabrication of low-cost kaolinite/perlite membrane for microfiltration of dairy and textile wastewaters. Journal of Environmental Chemical Engineering. 2023;11(2):109281. doi:10.1016/j.jece.2023.109281
  8. Lopatina A, Anugwom I, Blot H, Sánchez Conde Á, Mänttäri M, Kallioinen M. Re-use of waste cotton textile as an ultrafiltration membrane. Journal of Environmental Chemical Engineering. 2021;9(4):105705. doi:10.1016/j.jece.2021.105705
  9. Chen Q, Yang Y, Zhou M, Liu M, Yu S, Gao C. Comparative study on the treatment of raw and biologically treated textile effluents through submerged nanofiltration. Journal of Hazardous Materials. 2015;284:121-129. doi:10.1016/j.jhazmat.2014.11.009
  10. Suksaroj C, Héran M, Allègre C, Persin F. Treatment of textile plant effluent by nanofiltration and/or reverse osmosis for water reuse. Desalination. 2005;178(1-3):333-341. doi:10.1016/j.desal.2004.11.043
  11. Pla R, Baeza JA, Fernández-Marquez M, Live Lozada GS, Villa-Manso AM, Revenga-Parra M, et al. Graphene oxide membranes with amine intercalation for dye recovery from textile effluents. Journal of Industrial and Engineering Chemistry. 2025;152:766-776. doi:10.1016/j.jiec.2025.05.050
  12. Moustansiri HE, Abbadi SE, Douma M, Bouazizi A, Machtani Idrissi DE, Bechelany M, et al. Development of low-cost wollastonite based-membrane from clay for efficient microfiltration of textile and tannery wastewaters. Separation and Purification Technology. 2025;359:130770. doi:10.1016/j.seppur.2024.130770
  13. Pallot H, Isloor AM, Ismail AF. Effective separation of agrochemicals and textile dyes from polluted aqueous solution employing ternary ZnCoFe layered double hydroxide incorporated polyethersulfone hollow fiber ultrafiltration membrane. Chemical Engineering Journal. 2025;520:165254. doi:10.1016/j.cej.2025.165254
  14. Panda SR, De S. Performance evaluation of two stage nanofiltration for treatment of textile effluent containing reactive dyes. Journal of Environmental Chemical Engineering. 2015;3(3):1678-1690. doi:10.1016/j.jece.2015.06.004
  15. Liu M, Yu C, Dong Z, Jiang P, Lü Z, Yu S, et al. Improved separation performance and durability of polyamide reverse osmosis membrane in tertiary treatment of textile effluent through grafting monomethoxy-poly(ethylene glycol) brushes. Separation and Purification Technology. 2019;209:443-451. doi:10.1016/j.seppur.2018.07.072
  16. Ibrahim HA, Rashid KT, AbdulRazak AA, Shehab MA, Salih MA, Al-lami M, et al. A novel poly(ether-Sulfone) mixed matrix membranes infused with TiO2-BiFeO3 nanomaterials for the removal of toxic Congo red dye from textile wastewater. Chemical Engineering Journal Advances. 2025;24:100867. doi:10.1016/j.ceja.2025.100867
  17. Desa AL, Hairom NHH, Ng LY, Ng CY, Ahmad MK, Mohammad AW. Industrial textile wastewater treatment via membrane photocatalytic reactor (MPR) in the presence of ZnO-PEG nanoparticles and tight ultrafiltration. Journal of Water Process Engineering. 2019;31:100872. doi:10.1016/j.jwpe.2019.100872
  18. Wu X, Ma S, Ng D, Acharya D, Fan L, Xie Z. Enhancing water recovery through integrated graphene oxide-modified forward osmosis and membrane distillation for real textile wastewater treatment. Journal of Environmental Chemical Engineering. 2024;12(3):112512. doi:10.1016/j.jece.2024.112512
  19. Egbosiuba TC, Chukwuemeka C, Umeuzuegbu JC, Mmonwuba NC, Ewuzie U, Okoronkwo MU, et al. Performance evaluation of aminated multi-walled carbon nanotubes incorporated with green synthesized iron nanoparticles for toxic dyes sequestration from textile wastewater. Water Resources and Industry. 2025;33:100291. doi:10.1016/j.wri.2025.100291
  20. Gattucci F, Rossi M, Sarchini L, Bertarelli C, Castagna R, Balagna C. Silver-functionalized polyvinyl alcohol nanofiber membranes: A comparative study of nanoparticle incorporation and coating deposition. Surface and Coatings Technology. 2026;520:133038. doi:10.1016/j.surfcoat.2025.133038
  21. Kusworo TD, Purwanto P, Jos B, Budiyono B, Astuti DAP, Inamullah AMA, et al. Photocatalytic nanohybrid UV-light-driven PVDF/GO-NiFe@SiO2 membrane coupled with bentonite adsorption and ozonation process for a sustainable textile wastewater treatment. Process Safety and Environmental Protection. 2024;190:438-457. doi:10.1016/j.psep.2024.08.048
  22. Liang S, Ma Z, Fan Z, Gu M, Ding H, Wu D, et al. Tuning membrane surface wetting behavior via dual-nanomaterial functionalization for efficient water purification. Journal of Membrane Science. 2025;724:123970. doi:10.1016/j.memsci.2025.123970
  23. Wu S, Wells G, Gray KA. Engineered nanomaterials exert sublethal bacterial stress at very low doses: Effects of concentration, light, and media on cell membrane permeability. Science of The Total Environment. 2024;948:174861. doi:10.1016/j.scitotenv.2024.174861
  24. Nayeri S, Parsa JB. Fabrication of PES membrane loaded with Fe, Ni-BMOF/g-C3N4 nanomaterials and investigation of photocatalytic removal, antifouling and permeability properties in cephalexin aqueous solution. Chemical Engineering Journal Advances. 2025;24:100872. doi:10.1016/j.ceja.2025.100872
  25. Ahmad NA, Goh PS, Ismail AF, Ting TM, Hashim N, Kerisnan@Kerishnan NDAP, et al. Optimizing the boron rejection and chlorine-resistant performance of reverse osmosis thin film nanocomposite membrane through the positioning of sheet-like nanomaterials. Journal of Water Process Engineering. 2024;68:106277. doi:10.1016/j.jwpe.2024.106277
  26. Vasiraja N, Saravana Sathiya Prabhahar R, Joshua A. Preparation and Physio–Chemical characterisation of activated carbon derived from prosopis juliflora stem for the removal of methylene blue dye and heavy metal containing textile industry effluent. Journal of Cleaner Production. 2023;397:136579. doi:10.1016/j.jclepro.2023.136579
  27. Swarnkumar Reddy, Osborne WJ. Heavy metal determination and aquatic toxicity evaluation of textile dyes and effluents using Artemia salina. Biocatalysis and Agricultural Biotechnology. 2020;25:101574. doi:10.1016/j.bcab.2020.101574
  28. Le AT, Koe CM, Hanh Le TD, Tan WK, Tuan Huynh NA, Pung SY. Rapid immobilization of Ag/ZnO nanocomposite on Kanthal mesh for efficient removal of organic dye and heavy metal ions. Materials Chemistry and Physics. 2025;339:130692. doi:10.1016/j.matchemphys.2025.130692
  29. Arshad F, Al Momani DE, de Vos WM, Zou L. Nanocomposite membrane for simultaneous removal of dye and heavy metal ions from wastewater. Journal of Environmental Management. 2024;371:123242. doi:10.1016/j.jenvman.2024.123242
  30. Bopape DA. Exploring the synthesis and application of ZnO-, TiO₂-, CuO-ZnO- and CuO-TiO₂‑carbon sphere (CSs) nanocomposites for the photocatalytic degradation of methylene blue (MB) dye and ciprofloxacin (CIP) antibiotic under ultraviolet (UV) irradiation. Journal of Water Process Engineering. 2026;81:109392. doi:10.1016/j.jwpe.2025.109392
  31. Padmanabhan NT, Gayathri K, Thomas RM, John H. ZnO/Mo2TiC2 MXene nanohybrids for enhanced solar-driven photocatalytic degradation of tetracycline and organic pollutants in contaminated water. Energy & Environmental Sustainability. 2025;1(3):100042. doi:10.1016/j.eesus.2025.100042
  32. Korkut S, Esenli B, Yuksekdag A, Salmanzadeh-Jamadi Z, Habibi-Yangjeh A, Vatanpour V, et al. Enhanced anti-fouling properties and chlorine resistance in TiO2-QDs/C-dots modified thin-film nanocomposite reverse osmosis membranes. Journal of Environmental Chemical Engineering. 2025;13(6):120143. doi:10.1016/j.jece.2025.120143
  33. Mahlangu OT, Motsa MM, Richards H, Mamba BB, George MJ, Nthunya LN. The impact of nanoparticle leach on sustainable performance of the membranes – A critical review. Environmental Nanotechnology, Monitoring & Management. 2024;22:100984. doi:10.1016/j.enmm.2024.100984
  34. Zhao L, Ding Y, Li S, Song Y, Gong H, Zhang Y. Using nano-modifying sisal fibers with SiO2 NPs and graphene-based membranes to improve aging durability of sisal fiber-reinforced cement composites. Journal of Building Engineering. 2025;112:113874. doi:10.1016/j.jobe.2025.113874
  35. Mir TUG, Katoch V, Angurana R, Wani AK, Shukla S, El Messaoudi N, et al. Environmental and toxicological concerns associated with nanomaterials used in the industries. Nanomaterials for Bioreactors and Bioprocessing Applications. 2023:141-193. doi:10.1016/b978-0-323-91782-7.00010-2