Phosphin-imin-methandiides
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Synthesis, Crystal Structure and Reactivity Study of N-Pyrrolyl-P, P-Diphenylphosphino Sulfide/Selenide Ligand
Abstract: 800x600 We report the synthesis and solid state structures of the N-pyrrolyl-P,P-diphenylphosphino sulfide and selenide of molecular formulae [C4H4NP(S)Ph2] (1) and [C4H4NP(Se)Ph2] (2) respectively. Compounds 1 and 2 were prepared by one pot reaction of pyrrole and [Ph2P(E)Cl] (E = S and Se) in the presence of NaH as base at ambient temperature. In the solid state structure established by single crystal X-ray diffraction analysis, phosphorus atom adopts a distorted …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 5, Issue 3, 2014 · pp. 35–45 Read article