Organoheterotrimetallic-μ-oxoisopropoxide-μ-oxon-propoxide
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Synthesis and Characterization of Schiff Bases Derivatives of Heterotrimetallic [Al(III); Sn(II); Ti(IV)]-µ-oxoisopropoxide-µ-oxon-propoxide [SnO2TiAl(OPri )2(OPrn )3]
Abstract: Tin diacetate and aluminium isopropoxide in equimolar proportion in xylene affords the complex [(OAc)SnOAl(OPri )2] which on reaction with Ti(OPrn )4 in 1:1 molar ratio yielded a new organoheterotrimetallic-μ-oxoisopropoxide-μ-oxon-propoxide [SnO2TiAl(OPri )2(OPrn )3] with continuous liberation of isopropyl acetate and propyl acetate formed during the course of reaction. The preparation of Schiff base complexes of the compound [SnO2TiAl(OPri )2(OPrn )3] was carried out in refluxing benzene by the reaction of µ- …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 2, 2016 · pp. 27–37 Read article