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4 articles for “acetylacetone”
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Mono(acetylacetonato)zirconium(IV) Aryloxides: Synthesis, Reactivity and Thermoanalytical Investigation
Abstract: Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4 A series of novel zirconium(IV) complexes, formulated as ZrCl3−n(acac)(OArI–V)n (where n =− 3; –OArI = OC6H4Cl-2, –OArII = OC6H4Cl-4, –OArIII = –OC6H3Cl2-2,4, OArIV = –OC6H3Cl2-2,6 and OArV = –OC6H2Cl3-2,4,6) were synthesized by reacting ZrCl3(acac) with corresponding substituted chlorophenols in separate experiments. The complexes were characterized by elemental analysis, molar conductance measurements, molecular weight determination, spectroscopic techniques (1HNMR and IR) and thermal …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 1, 2012 · pp. 6–16 Read article
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Synthesis, Characterization of New Imidazolidin-4-One Containing Azo Compound Derived from Acetylacetone as Antibacterial and Antioxidant Agents
Abstract: In the present study, new derivatives of imidazolidine-4-one was prepared. Which involved reactions to diazonium salt of o-methoxy aniline with acetylacetone in the presence of sodium hydroxide, and isolating the azo compound as a brown precipitate. The azo diketone reacts efficiently with aromatic amine derivatives to produce Schiff bases as a light yellow and dark brown precipitates, and from this Schiff bases three derivatives of imidazolidine-4-one was prepared by reacting …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 17, Issue 1, 2026 · pp. 94–114 Read article
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Reactivity of Monochlorotetrakis2-Isopropylphenoxoniobium(V), [NbCl(OC6H4CH(CH3)2-2)4] towards Chelating Ligands
Abstract: The niobium(V) complexes with the formula [NbCl(OC₆H₄CH(CH₃)₂-2)₄] were successfully synthesized in high yields through the reaction of niobium pentachloride with four equivalent amounts of 2-isopropylphenol in carbon tetrachloride. The synthesized complexes were characterized and confirmed by elemental analysis, molar conductance measurements, infrared (IR) spectroscopy, ^1H and ^13C NMR spectroscopy, as well as mass spectrometric analysis. The spectroscopic studies have shown these to exhibit dimeric structures bridging through isopropylphenoxo groups. The …
Published in International Journal of Minerals · Vol. 3, Issue 1, 2026 · pp. 37–45 Read article
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Photoluminescent Reduced Graphene Oxide (rGO)–ZnO Nanocomposites Prepared Through one-pot Solvothermal Route
Abstract: In the present article, we report solvothermal synthesis of reduced graphene oxide (rGO)–ZnO nanocomposites through in situ exfoliations of graphite oxide with two different zinc-containing precursors viz. Zinc acetate dihydrate and zinc(II) acetylacetonate in water-diethylene glycol medium with hexamethylenetetramine as a reducing agent. The obtained rGO–ZnO nanocomposites were characterized by X-ray diffraction, and the ZnO lattice parameters were calculated. Raman spectroscopy indicated the presence of characteristic bands of graphene and …
Published in Journal of Polymer & Composites · Vol. 11, Issue 2, 2023 · pp. 70–80 Read article