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2 articles for “Os(VIII) catalysis”
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Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article
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Mechanistic and Catalytic Behavior of Os(VIII) for the Chlorpheniramine Maleate and Bromamine-B Redox System: A Kinetics Based Approach
Abstract: Chlorpheniramine maleate (CPM) is an important antihistamine agent. To the best of our knowledge there is no report in the literature about the oxidation of CPM with halogen + 1 oxidant from the stand point of its kinetics and mechanistic chemistry. Hence, a systematic kinetics and mechanistic study on the oxidation of CPM with bromamine-B (BAB) in the presence of NaOH and Os(VIII) catalyst has been carried out at 303 …
Published in Journal of Catalyst & Catalysis · Vol. 2, Issue 1, 2015 · pp. 18–31 Read article