Recent Trends in Civil Engineering & Technology Review Article

Review of Research on Pozzolanic Materials for Cement Blending and Concrete Applications

  1. Yogesh Tiwari
  2. Rakesh Kumar Rajak,

Abstract

The growing environmental concerns associated with cement production, particularly its high carbon footprint, have driven research into sustainable alternatives such as supplementary cementitious materials (SCMs) derived from agricultural and industrial waste. This study synthesizes findings from recent investigations into the pozzolanic potential of basil plant ash (BPA), rice husk ash (RHA), and stockpiled fly ash (FA), evaluating their processing methods, microstructural characteristics, and performance in concrete applications. BPA, being derived by controlled thermal processing, exhibited the best reactivity at 700°C and improved significantly the compressive as well as tensile strength of ultra-high-performance concrete and increased durability. RHA, treated by calibrated grinding and calcining, delivered high amorphous silica content and pozzolanic activity, resulting in significant early-age gain in strength and lowered porosity. FA, typically low-grade because of storage for extended periods, was rejuvenated via mechanical activation (milling), which enhanced surface area and reactivity and rendered it an effective SCM for typical mortar use. The three materials showed decreased permeability, enhanced microstructure, and hydration process compatibility, leading to long-term durability of concrete. Aside from technical advantages, application of these materials meets key environmental objectives by lowering CO₂ emissions, reducing industrial and agricultural waste, and saving natural resources. They also represent low-cost solutions to conventional cement components economically, supporting circular economy and sustainable development principles. However, consistent performance depends heavily on optimized processing, standardized treatment protocols, and further validation of long-term behavior. This study concludes that BPA, RHA, and FA hold strong promise as sustainable SCMs and encourages further interdisciplinary research to advance green concrete technologies through scalable, cost- effective, and environmentally responsible practices.

Keywords

References (67)

  1. Shilar, F. A., Ganachari, S. V., Patil, V. B., Khan, T. Y., & Khadar, S. D. A. (2022).
  2. Molarity activity effect on mechanical and microstructure properties of geopolymer
  3. concrete: A review. Case Studies in Construction Materials, 16, e01014.
  4. https://doi.org/10.1016/j.cscm.2022.e01014
  5. Thomas, M. (2013). Supplementary Cementing Materials in Concrete. CRC Press.
  6. https://doi.org/10.1201/b14493
  7. Bentz, D. P., Ferraris, C. F., & Galler, M. A. (2012). Influence of particle size
  8. distributions on the performance of cementitious materials. Cement and Concrete
  9. Research, 42(2), 404-409. https://doi.org/10.1016/j.cemconres.2011.11.006
  10. Saad, Siti & Nuruddin, Muhd & Shafiq, Nasir & Ali, Maisarah. (2015). Pozzolanic
  11. Reaction Mechanism of Rice Husk Ash in Concrete – A Review. Applied Mechanics and
  12. Materials. 773-774. 1143-1147. 10.4028/www.scientific.net/AMM.773-774.1143.
  13. http://dx.doi.org/10.4028/www.scientific.net/AMM.773-774.1143
  14. Bentz, D. P., Garboczi, E. J., Haecker, C. J., & Jensen, O. M. (1999). Effects of cement
  15. particle size distribution on performance properties of Portland cement-based materials.
  16. Cement and concrete research, 29(10), 1663-1671. https://doi.org/10.1016/S0008-
  17. 8846(99)00163-5
  18. Zeyad, A. M., Agwa, I. S., Abd-Elrahman, M. H., & Mostafa, S. A. (2024). Engineering
  19. characteristics of ultra-high performance concrete containing basil plant ash. Case
  20. Studies in Construction Materials, 21, e03422.
  21. https://doi.org/10.1016/j.cscm.2024.e03422
  22. Almutlaqah, A., Maddalena, R., & Kulasegaram, S. (2025). Optimising thermo-
  23. mechanical treatments of residual rice husk ash for cement blending. Case Studies in
  24. Construction Materials, 22, e04103. https://doi.org/10.1016/j.cscm.2024.e04103
  25. Šídlová, M., Šulc, R., Škvára, F., et al. (2023). Pozzolanic activity of stockpile ash:
  26. Comparison of test methods. Case Studies in Construction Materials, 19, e02396.
  27. https://doi.org/10.1016/j.cscm.2023.e02396
  28. Thiedeitz, M., Schmidt, W., Härder, M., & Kränkel, T. (2020). Performance of rice husk
  29. ash as supplementary cementitious material after production in the field and in the lab.
  30. Materials, 13(19), 4319. https://doi.org/10.3390/ma13194319
  31. Šídlová, M., Šulc, R., Rak, P., Formáček, P., Pulcová, K., & Snop, R. (2023, August).
  32. Comparison of different methods for assessing the pozzolanic activity of fly ash and
  33. bottom ash. In AIP Conference Proceedings (Vol. 2780, No. 1). AIP Publishing.
  34. https://doi.org/10.1063/5.0137066
  35. Hamada, H. M., Abed, F., Al-Sadoon, Z. A., & Alashkar, A. (2024). Enhancing
  36. pozzolanic activity of fly ash via dry and wet milling: A comparative study for
  37. sustainable construction material enhancement. Journal of CO2 Utilization, 83, 102811.
  38. https://doi.org/10.1016/j.jcou.2024.102811
  39. Akmalaiuly, Kenzhebek & Berdikul, Nazerke & Pundiene, Ina & Pranckeviciene,
  40. Jolanta. (2023). The Effect of Mechanical Activation of Fly Ash on Cement-Based
  41. Materials Hydration and Hardened State Properties. Materials. 16. 2959.
  42. 3390/ma16082959. http://dx.doi.org/10.3390/ma16082959
  43. Amran, M., Fediuk, R., Murali, G., Vatin, N., Karelina, M., Ozbakkaloglu, T., ... &
  44. Mishra, J. (2021). Rice husk ash-based concrete composites: A critical review of their
  45. properties and applications. Crystals, 11(2), 168. https://doi.org/10.3390/cryst11020168
  46. Yang, Y. P., Deng, Y. G., & Chen, L. S. (2025). Properties of high-volume rice husk ash
  47. UHPC with various fineness. Construction and Building Materials, 458, 139614.
  48. https://doi.org/10.1016/j.conbuildmat.2024.139614
  49. Akmalaiuly, K., Berdikul, N., Pundienė, I., & Pranckevičienė, J. (2023). The effect of
  50. mechanical activation of fly ash on cement-based materials hydration and hardened state
  51. properties. Materials, 16(8), 2959. https://doi.org/10.3390/ma16082959
  52. Salas Montoya, A., Chung, C. W., & Kim, J. H. (2023). High performance concretes with
  53. highly reactive rice husk ash and silica fume. Materials, 16(11), 3903.
  54. https://doi.org/10.3390/ma16113903
  55. Huang, T. Y., Chiueh, P. T., & Lo, S. L. (2017). Life-cycle environmental and cost
  56. impacts of reusing fly ash. Resources, Conservation and Recycling, 123, 255-260.
  57. https://doi.org/10.1016/j.resconrec.2016.07.001
  58. Ro, J., Cunningham, P.R., Miller, S.A. et al. Technical, economic, and environmental
  59. feasibility of rice hull ash from electricity generation as a mineral additive to concrete.
  60. Sci Rep 14, 9158 (2024). https://doi.org/10.1038/s41598-024-59615-1
  61. Singh, Neha & Sharma, R. & Yadav, Kundan. (2024). Sustainable Solutions: Exploring
  62. Supplementary Cementitious Materials in Construction. Iranian Journal of Science and
  63. Technology - Transactions of Civil Engineering. 10.1007/s40996-024-01585-5.
  64. http://dx.doi.org/10.1007/s40996-024-01585-5
  65. Indumathi, M., Nakkeeran, G., Roy, D. et al. Innovative approaches to sustainable
  66. construction: a detailed study of rice husk ash as an eco-friendly substitute in cement
  67. production. Discov Appl Sci 6, 597 (2024). https://doi.org/10.1007/s42452-024-06314-1
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