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    Organic Phase Speciation of 36% Tri-Iso Amyl Phosphate/N-Dodecane Solvent during Nitric Acid Extraction

    Abstract: Several solutions of 36% TiAP/n-dodecane solvent were equilibrated with different concentrations of aqueous nitric acid solutions at 298.15 K at a phase ratio of unity. The resultant equilibrated aqueous and organic solutions were analyzed for acidity. A three-solvate model with molecular HNO3 based mechanism was assumed for nitric acid extraction by TiAP. This model was analogous to the 3-solvate model for nitric acid extraction by TBP, recently reported by authors. …

    Published in Journal of Nuclear Engineering & Technology · Vol. 5, Issue 2, 2015 · pp. 28–34 Read article

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