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• Published Subscription 16 Apr 2019

  Ru(III)-Catalyzed Oxidative Cleavage of Ritodrine Hydrochloride: A Kinetic and Mechanistic Study

  By Putta swamy, S. Dakshayani, A. S. Manjunatha

  Abstract: A systematic kinetic and mechanistic study of the oxidation of ritodrine hydrochloride (RTH) with chloramine-T (CAT) in both HClO4 and NaOH media has been carried out at 303 K. In acid medium, the reaction rate is very sluggish to be measured kinetically. Ruthenium (III) chloride ([Ru(III)]) was found to be an efficient catalyst. The reaction rate exhibits a first-order dependence on [CAT]0 in both media. It shows a fractional-order on …

  Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 29–40 Read article →