Journal of Catalyst & Catalysis
Volume 4, Issue 3 (2017)
Published
Table of contents
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The Rheological Effect of SiO2 Nanoparticles Additives for NBR/CR Blends
Abstract: The rheological alteration of NBR/CR after adding various nano-quantities of silicon oxide (0–50) wt.% was studied. The rheological properties that were tested are viscosity, scorch time, cure time and max torque. Oscillating disk rheometer was used for measuring the above properties. The experimental results have shown that the silicon oxide additives have a good effect on viscosity and max torque during vulcanization, but at the same time the scorch and …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 1–4 Read article
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Green Synthesis of Biologically Active 2, 4, 5- Trisubstituted Imidazoles Catalyzed by Large Pore Zeolite H-BEA through Lophine MCRs
Abstract: 2, 4, 5-triphenyl-1(H)-imidazoles (popularly known as Lophine derivatives) are well known heterocyclic compounds and find significant diversified applications, not only in the area of medicinal chemistry as biologically active drug-like molecules, but also in the other advanced research areas, such as fluorescence labelling, biological imaging and chromospheres for non-linear optic system. In the present endeavour, a green synthesis of Lophine derivatives via multi-component reaction is carried out using benzil/benzoin, substituted …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 20–36 Read article
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Removal of AB 10B from Water by Copper Oxide Nano- Particles through Adsorption: A Kinetics and Thermodynamic Study
Abstract: Copper oxide nanoparticle was synthesized by a simple method. Consequently, adsorbent was characterized by using FTIR, XRD, and SEM techniques. The study of optimized parameter contains pH, initial dye concentration, adsorbent dose and contact time. Langmuir, Freundlich and Tempkin models were pragmatic for evaluating adsorption equilibrium data of AB 10B as the adsorbent but experiment show the Langmuir model is best for it. The adsorption kinetic model study was done …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 37–48 Read article
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Extraction and Characterization of Antioxidants from the Seeds of Ethiopian Avocado Variety, Pinkerton
Abstract: The objective of this study was to extract and characterize the antioxidants from the Ethiopian avocado seeds of the Pinkerton variety, using ethanol as a solvent. Response surface methodology (RSM) in combination with Box-Behnken experimental design with a three level, three-factor mixture design was used to optimize the extraction condition for assessing the maximum yield of antioxidant from the avocado seeds. Ethanol concentration (%, v/v), temperature (°C) and time (h) …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 49–56 Read article
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Catalytic Trends of OsO4 for the Taurine-Bromamine-T Redox System: Kinetic and Mechanistic Chemistry of Catalyzed and Uncatalyzed Reactions
Abstract: Taurine (2-ethane aminosulfonic acid) facilitates as a building block for protein synthesis, also possessing various other vital biological functions. Literature survey revealed that there was no report available on the oxidation of taurine with any oxidants from its kinetic, mechanistic and catalytic aspects. A detailed comparative mechanistic study of its Os(VIII) catalyzed and uncatalyzed oxidation kinetics by bromamine-T (BAT) in NaOH medium at 313 K revealed the rate law to …
Published in Journal of Catalyst & Catalysis · Vol. 4, Issue 3, 2017 · pp. 5–19 Read article