Journal of Catalyst & Catalysis
Volume 1, Issue 1 (2014)
Published
Table of contents
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A One-Step Selective Oxidation of Benzene to Phenol over CuCr2O4 Spinel Nanoparticles Catalyst with Air as Oxidant
Abstract: in presence of the cationic surfactant, cetyltrimethylammonium bromide and hydrazine. Detailed characterization of the material was carried out by XRD, BET, ICP-AES, SEM and TEM. XRD revealed the exclusive formation of CuCr2O4 spinel phase and TEM showed the formation of 30–50 nm particle size. The catalyst was highly active for selective oxidation of benzene to phenol with air as oxidant. Influence of reaction parameters were investigated in detail. The advantages …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 1–7 Read article
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Alcohol Oxidation in Ionic Liquids Catalysed by Recyclable Platinum Nanoparticles: A Green Approach
Abstract: The effect of particle size on the catalytic performance of materials in organic reactions is of scientific and industrial importance. In the present case we demonstrate the use of room temperature ionic liquids as effective agents of dispersion of platinum nanoparticles prepared from potassium tetrachloroplatinate. The platinum nanoparticles in the range 2.5±0.5 nm are recyclable catalysts for aerobic oxidation of alcohols under mild conditions. The particles suspended in ionic liquids …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 15–22 Read article
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H2 Production by Methanol Steam Reforming over Copper Impregnated Anodized Aluminum Oxide (AAO)
Abstract: Hydrogen production by methanol steam reforming (MSR) is easy and simple as compared to other reforming methods using fossil fuels such as methane steam reforming. The catalysts for MSR are well developed and available commercially. When constructing a small or micro reformer, the catalyst often needs to be coated on the wall of the metal substrate. In this case, the bonding between the metal surface and the catalyst layer must …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 23–28 Read article
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Ru(III)-Catalyzed Oxidative Cleavage of Ritodrine Hydrochloride: A Kinetic and Mechanistic Study
Abstract: A systematic kinetic and mechanistic study of the oxidation of ritodrine hydrochloride (RTH) with chloramine-T (CAT) in both HClO4 and NaOH media has been carried out at 303 K. In acid medium, the reaction rate is very sluggish to be measured kinetically. Ruthenium (III) chloride ([Ru(III)]) was found to be an efficient catalyst. The reaction rate exhibits a first-order dependence on [CAT]0 in both media. It shows a fractional-order on …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 29–40 Read article
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Synthesis of Zeolite Y-Encapsulated Copper(II) Complexes with Aminobenzonitriles and Carbonitriles by Flexible Ligand Method
Abstract: Zeolite Y encapsulated copper(II) sulphate complexes with 2-, 3- and 4- aminobenzonitrile and carbonitrile have been prepared by flexible ligand synthesis method. Complexes are characterized by magnetic susceptibility, infra-red and electronic spectral techniques. The data clearly suggests the presence of metal complexes in zeolite matrix.
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 41–52 Read article
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Synthesis, Structural Studies and Catalytic activity of Copper(II) Complex Supported by N, N′-bis (2-Hydroxy-3-Methoxybenzaldehyde) 4-Methylbenzene-1, 2-Diamine
Abstract: A novel robust method for synthesis of 3-MOBdMBn-Cu complex, supported by -ONNO-tetradentate Schiff-base ligand is presented. This copper complex is prepared by the reactions of metal solution with one molar equivalent of 3-MOBdMBn (N, N’-bis (2-hydroxy-3-methoxybenzaldehyde) 4-Methylbenzene-1, 2-diamine) Schiff-base ligand in methanol under nitrogen atmosphere. In contrast to other catalysts, the main advantage of this catalyst system was that the cost of the catalyst was remarkably low and it can …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 53–60 Read article
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In Situ Synthesized Cu(OH)2-Al2O3: A Novel and Highly Efficient Nano-Catalyst System for One pot Synthesis of N-Substituted Triazole at Room Temperature
Abstract: One pot room temperature synthesis of N- substituted Triazoles has been demonstrated using a novel catalyst system Cu(OH)2-Al2O3. The catalyst has been synthesized by a very simple one step chemical process. The catalyst is highly efficient and reusable with isolated yield as high as 87% even at the 4th reuse. The catalyst could also be used with water as a solvent with a little longer reaction time. Graphical Abstract: One …
Published in Journal of Catalyst & Catalysis · Vol. 1, Issue 1, 2014 · pp. 8–14 Read article