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Study of the Hammett equation for oxidation of 2 – Hydroxy – 1 - Naphthalidene Anil and para substituted chloroanils by potassium bromate in acid mediumBy Umesh N. Pol, Sharad Sankhe, Ramesh Yamgar
Abstract: The kinetics of oxidation of the Schiff base and its substituted anils by potassium bromate in aquo-acetic acid medium has been studied in this work. The study of thermodynamic parameters is done, and the rate constants for the reaction are determined. The plot of log{ks/k0} against the substituent constant (ï³ ) is plotted for para and meta substitution and the reaction constant (ï²) is calculated. The plot of ï„H against …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 7, Issue 2, 2016 · pp. 1–4 Read article →