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Copper(II) Catalyzed Oxidation of Hydrazine Hydrate by Hexacyanoferrate(III)By Vidyavati Shastry, S. Shashidhar, S. T. Nandibewoor, B. C. Sateesh
Abstract: The kinetics of Cu(II) catalyzed oxidation of hydrazine by hexacyanoferrate(III) is studied in acid medium. The stoichiometry of the reaction is 1:1. The first order condition [N2H5] > [Fe(CN)63−] is maintained. The order of the reaction is unity with respect to Fe(CN)63−, fractional orders with respect to hydrazine and copper. The reaction is independent of variation of sulphuric acid and ionic strength. A suitable mechanism is proposed for the reaction
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 1-3, 2012 · pp. 22–29 Read article →