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Mono(acetylacetonato)zirconium(IV) Aryloxides: Synthesis, Reactivity and Thermoanalytical InvestigationBy Raj Kaushal, S S Bhatt
Abstract: Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4 A series of novel zirconium(IV) complexes, formulated as ZrCl3−n(acac)(OArI–V)n (where n =− 3; –OArI = OC6H4Cl-2, –OArII = OC6H4Cl-4, –OArIII = –OC6H3Cl2-2,4, OArIV = –OC6H3Cl2-2,6 and OArV = –OC6H2Cl3-2,4,6) were synthesized by reacting ZrCl3(acac) with corresponding substituted chlorophenols in separate experiments. The complexes were characterized by elemental analysis, molar conductance measurements, molecular weight determination, spectroscopic techniques (1HNMR and IR) and thermal …
Published in Journal of Modern Chemistry & Chemical Technology · Vol. 3, Issue 1, 2012 · pp. 6–16 Read article →